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Alleghanyite

A valid IMA mineral species - grandfathered
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About AlleghanyiteHide

09717340017061282663800.jpg
Seal of Alleghany County
Formula:
Mn2+5(SiO4)2(OH)2
Colour:
Pinkish to reddish brown, deep pink, grayish pink
Lustre:
Sub-Vitreous, Resinous, Waxy, Dull
Hardness:
Specific Gravity:
3.93 - 4.02
Crystal System:
Monoclinic
Name:
Named in 1932 by Clarence S. Ross and Paul F. Kerr after the type locality occurrence in Alleghany County, North Carolina, USA.
Dimorph of:
Alleghanyite is a mineral in the humite group and is the manganese analogue of chondrodite. Alleghnyite is closely related to the other manganese-dominant humite-group minerals such as leucophoenicite, manganhumite and sonolite, and is often difficult to distinguish from these.

Alleghanyite most commonly occurs in hypogene and hydrothermal manganese deposits. It normally occurs as mm-sized grains together with other Mn silicates such as tephroite, but crystals on vein fractures are known from Franklin and Sterling Hill and the Bennalt mine in Wales.



Unique IdentifiersHide

Mindat ID:
129
Long-form identifier:
mindat:1:1:129:0
GUID
(UUID V4):
7882c480-3643-4805-8b96-b1ed9dd4d188

IMA Classification of AlleghanyiteHide

Approved, 'Grandfathered' (first described prior to 1959)

Classification of AlleghanyiteHide

9.AF.45

9 : SILICATES (Germanates)
A : Nesosilicates
F : Nesosilicates with additional anions; cations in [4], [5] and/or only [6] coordination
52.3.2b.1

52 : NESOSILICATES Insular SiO4 Groups and O,OH,F,H2O
3 : Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] coordination only
14.17.4

14 : Silicates not Containing Aluminum
17 : Silicates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
AlhIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AlleghanyiteHide

Sub-Vitreous, Resinous, Waxy, Dull
Transparency:
Transparent, Translucent
Colour:
Pinkish to reddish brown, deep pink, grayish pink
Comment:
in thin section, pink or buff in thick plates
Streak:
Very pale pink
Hardness:
5½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
Good to poor
Fracture:
Conchoidal, Sub-Conchoidal
Density:
3.93 - 4.02 g/cm3 (Measured)    3.96 g/cm3 (Calculated)

Optical Data of AlleghanyiteHide

Type:
Biaxial (-)
RI values:
nα = 1.756 nβ = 1.780 nγ = 1.792
2V:
Measured: 72° , Calculated: 68°
Birefringence:
0.036
Max Birefringence:
δ = 0.036
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
r > v
Optical Extinction:
X ^ a = 35°, Z = b (olivine setting). OAP perpendicular to {100}
Pleochroism:
Weak
Comments:
X brown, Y light brown, Z colorless

Chemistry of AlleghanyiteHide

Mindat Formula:
Mn2+5(SiO4)2(OH)2
Common Impurities:
Ti,Al,Fe,Mg,Ca,F

Crystallography of AlleghanyiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/b
Cell Parameters:
a = 8.27 Å, b = 4.85 Å, c = 10.72 Å
β = 104.64°
Ratio:
a:b:c = 1.705 : 1 : 2.21
Unit Cell V:
416.01 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals often rounded, slender; in stout plates, some longitudinally deeply striated. As fan-shaped aggregates; commonly irregular, massive.
Twinning:
On {001} , lamellar, common; also on {105} , {305} .
Comment:
Various settings reported

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000968AlleghanyiteFrancis C A (1985) Crystal structure refinement of magnesian alleghanyite American Mineralogist 70 182-1851985Sterling mine, Ogdensburg, New Jersey, USA0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.10 Å(100)
2.84 Å(70)
2.75 Å(40)
2.70 Å(40)
2.59 Å(40)
2.33 Å(50)
1.79 Å(60)
Comments:
ICDD 43-683; see also ICDD 39-1348. Older data sets show different strongest lines: ICDD 22-726 (d100 = 1.799) and ICDD 25-1184 (d100 = 3.616).

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)
High-𝑇 alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits
Geological Setting:
in veins crosscutting franklinite ore near pegmatites in a metamorphosed stratiform Zn-Mn deposit

Type Occurrence of AlleghanyiteHide

Geological Setting of Type Material:
Hydrothermally deposited, in lenses in a manganese-bearing vein
Associated Minerals at Type Locality:

Synonyms of AlleghanyiteHide

Other Language Names for AlleghanyiteHide

Simplified Chinese:粒硅锰矿
Spanish:Alleghanyita

Relationship of Alleghanyite to other SpeciesHide

Other Members of this group:
Manganhumite(Mn2+,Mg)7(SiO4)3(OH)2Orth. mmm (2/m 2/m 2/m)
SonoliteMn2+9(SiO4)4(OH)2Mon. 2/m : P21/b

Common AssociatesHide

Associated Minerals Based on Photo Data:
25 photos of Alleghanyite associated with FrankliniteZn2+Fe3+2O4
20 photos of Alleghanyite associated with CalciteCaCO3
20 photos of Alleghanyite associated with WillemiteZn2SiO4
9 photos of Alleghanyite associated with KellyiteMn2+2Al(AlSiO5)(OH)4
9 photos of Alleghanyite associated with KutnohoriteCaMn2+(CO3)2
7 photos of Alleghanyite associated with JacobsiteMn2+Fe3+2O4
7 photos of Alleghanyite associated with SussexiteMn2+BO2(OH)
5 photos of Alleghanyite associated with RhodoniteCaMn3Mn[Si5O15]
5 photos of Alleghanyite associated with PyrochroiteMn(OH)2
5 photos of Alleghanyite associated with Chlorophoenicite(Mn,Mg)3Zn2(AsO4)(OH,O)6

Related Minerals - Strunz-mindat GroupingHide

9.AF.ChegemiteCa7(SiO4)3(OH)2Orth. mmm (2/m 2/m 2/m)
9.AF.BarwooditeMn2+6Nb5+(SiO4)2O3(OH)3Trig. 3 : P3
9.AF.Jingwenite-(Y)YAlV4+(SiO4)O2(OH)2Mon. 2/m
9.AF.05SillimaniteAl2(SiO4)OOrth. mmm (2/m 2/m 2/m)
9.AF.05XenoliteAl10Si8O31
9.AF.10AndalusiteAl2(SiO4)OOrth. mmm (2/m 2/m 2/m) : Pnnm
9.AF.10KanonaiteMn3+Al(SiO4)OOrth. mmm (2/m 2/m 2/m) : Pnnm
9.AF.15KyaniteAl2(SiO4)OTric. 1 : P1
9.AF.20MulliteAl4+2xSi2-2xO10-xOrth. mmm (2/m 2/m 2/m) : Pbam
9.AF.20KrieseliteAl2(GeO4)F2Orth. mmm (2/m 2/m 2/m) : Pnma
9.AF.23BoromulliteAl9BSi2O19Orth. mm2 : Cmc21
9.AF.25YoderiteMg(Al,Fe3+)3(SiO4)2O(OH)Mon. 2/m : P21/m
9.AF.30MagnesiostauroliteMg(Mg,Li)3(Al,Mg)18Si8O44(OH)4Mon. 2/m : B2/m
9.AF.30StauroliteFe2+2Al9Si4O23(OH)Mon. 2/m : B2/m
9.AF.30ZincostauroliteZn2Al9Si4O23(OH)Mon. 2/m : B2/m
9.AF.35TopazAl2(SiO4)(F,OH)2Orth. mmm (2/m 2/m 2/m)
9.AF.40NorbergiteMg3(SiO4)F2Orth. mmm (2/m 2/m 2/m)
9.AF.45ChondroditeMg5(SiO4)2F2Mon. 2/m : P21/b
9.AF.45ReinhardbraunsiteCa5(SiO4)2(OH,F)2Mon. 2/m : P21/b
9.AF.45KumtyubeiteCa5(SiO4)2F2Mon. 2/m : P21/b
9.AF.45HydroxylchondroditeMg5(SiO4)2(OH)2Mon. 2/m : P21/b
9.AF.50HumiteMg7(SiO4)3F2Orth. mmm (2/m 2/m 2/m) : Pnma
9.AF.50Manganhumite(Mn2+,Mg)7(SiO4)3(OH)2Orth. mmm (2/m 2/m 2/m)
9.AF.50Unnamed (Ca-analogue of Humite)Ca7(SiO4)4F2Orth. mmm (2/m 2/m 2/m)
9.AF.50FluorchegemiteCa7(SiO4)3F2 Orth. mmm (2/m 2/m 2/m)
9.AF.50Unnamed (OH-analogue of humite)Mg7(SiO4)3(OH)2Orth.
9.AF.55ClinohumiteMg9(SiO4)4F2Mon. 2/m : P21/b
9.AF.55SonoliteMn2+9(SiO4)4(OH)2Mon. 2/m : P21/b
9.AF.55HydroxylclinohumiteMg9(SiO4)4(OH)2Mon. 2/m : P21/b
9.AF.60LeucophoeniciteMn2+7(SiO4)3(OH)2Mon. 2/m : P21/b
9.AF.65RibbeiteMn2+5(SiO4)2(OH)2Orth. mmm (2/m 2/m 2/m)
9.AF.70JerrygibbsiteMn2+9(SiO4)4(OH)2Orth. mmm (2/m 2/m 2/m) : Pbcn
9.AF.75FranciscaniteMn2+6(V5+,◻)2(SiO4)2(O,OH)6Trig. 3 : P3
9.AF.75ÖrebroiteMn2+3(Sb5+,Fe3+)(SiO4)(O,OH)3Trig. 3 : P3
9.AF.75WeliniteMn2+6(W6+,Mg)2(SiO4)2(O,OH)6Trig. 3 : P3
9.AF.75ScorticoiteMn6(Sb,◻)Σ2(SiO4)2O3(OH)3Trig. 3 : P3
9.AF.80EllenbergeriteMg6(Mg,Ti,Zr,◻)2(Al,Mg)6Si8O28(OH)10Hex. 6 : P63
9.AF.85Chloritoid(Fe2+,Mg,Mn2+)Al2(SiO4)O(OH)2Mon. 2/m : B2/b
9.AF.85MagnesiochloritoidMgAl2(SiO4)O(OH)2Mon. 2/m : B2/b
9.AF.85Ottrélite(Mn2+,Fe2+,Mg)Al2(SiO4)O(OH)2Mon.
9.AF.90PoldervaartiteCaCa[SiO3(OH)](OH)Orth. mmm (2/m 2/m 2/m) : Pbca
9.AF.90OlmiiteCaMn2+[SiO3(OH)](OH)Orth. mmm (2/m 2/m 2/m) : Pbca
9.AF.95Pilawite-(Y)Ca2Y2Al4(SiO4)4O2(OH)2Mon. 2/m : P21/b

Fluorescence of AlleghanyiteHide

Not fluorescent in UV

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for AlleghanyiteHide

References for AlleghanyiteHide

Reference List:

Localities for AlleghanyiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Tyrol
    • Innsbruck-Land District
      • Trins
Kolitsch et al. (2021)
    • Lienz District
      • Prägraten am Großvenediger
        • Timmelbach valley
Kolitsch et al. (2019)
China
 
  • Guangxi
    • Baise
      • Jingxi Co.
Yang Yuchun (1996)
  • Hunan
    • Xiangtan
Yang Yuchun (1996)
  • Shaanxi
    • Ankang
      • Ziyang County
Yang Yuchun (1996) +1 other reference
    • Hanzhong
      • Xixiang County
Pingyi Wan (2002)
      • Zhenba County
Pingyi Wan (2002)
  • Sichuan
    • Dazhou
      • Wanyuan Co.
Pingyi Wan (2002)
Pingyi Wan (2002)
    • Ya'an
      • Hanyuan County
Yang Yuchun (1996)
  • Yunnan
    • Dali
      • Heqing County
Yuchun Yang (1990)
Yang Yuchun (1996)
    • Wenshan
      • Yanshan County
Yang Yuchun (1996)
France
 
  • Auvergne-Rhône-Alpes
    • Savoie
      • Saint-Jean-de-Maurienne
        • Bessans
Chopin (1978)
        • Bonneval-sur-Arc
Chopin (1978)
  • Occitanie
    • Hautes-Pyrénées
Le Règne Minéral 47: 5-21
      • Bagnères-de-Bigorre
        • Vielle-Aure
Ragu (1994) +1 other reference
Italy
 
  • Liguria
    • Genoa
      • Ne
        • Reppia
Bracco (2012)
Japan
 
  • Aichi Prefecture
    • Kitashitara County
      • Shitara
Mayumi Yoshinaga (1963)
  • Fukuoka Prefecture
Dr. Yohachiro Okamoto collection (conserved by the Geological Survey of Japan)
  • Fukushima Prefecture
    • Iwaki City
Matsubara et al. (1996)
  • Gunma Prefecture
    • Kiryu City
Masutomi Museum specimen (Kyoto) +1 other reference
FUKUOKA et al. (1977)
    • Midori City
      • Seta
FUKUOKA et al. (1977) +1 other reference
Dr. Kameki Kinoshita collection (curated at Geological Survey of Japan) +1 other reference
University of Tokyo collection
FUKUOKA et al. (1977) +1 other reference
  • Ibaraki Prefecture
    • Takanomine mine
Mayumi Yoshinaga (1963)
  • Iwate Prefecture
    • Kunohe-gun
      • Noda
Katsu Kaneko (1956)
    • Miyako City
Dr. Matsuo Nambu ore collection (curated at Geological Survey of Japan)
    • Shimohei District
      • Yamada-machi
Dr. Matsuo Nambu ore collection (curated at Geological Survey of Japan)
  • Kagoshima Prefecture
    • Oshima District
      • Setouchi-cho
Toyofumi Yoshimura et al. (1969)
  • Kochi Prefecture
    • Kami City
Toyofumi Yoshimura et al. (1969) +1 other reference
    • Kochi City
Kaneko (1956)
    • Nankoku city
Minakawa et al. (2008)
  • Kyoto Prefecture
Mayumi Yoshinaga (1963)
    • Nantan City
Toyofumi Yoshimura et al. (1969)
    • Soraku District
      • Wazuka-cho
Yoshinaga (1963)
  • Mie Prefecture
    • Toba City
Yamada (2004)
  • Nagano Prefecture
    • Kamiina District
Katsu Kaneko (1956) +1 other reference
Akira Kato (2011)
Akira Kato (2011)
    • Matsumoto City
Fukuoka (1981)
  • Saga Prefecture
    • Karatsu City
      • Kyuuragi-machi
Okamoto collection (curated at the Geological Survey museum, Japan)
  • Shiga Prefecture
    • Ritto City
Symposium sobre yacimientos de manganeso et al. (1956) +1 other reference
  • Tochigi Prefecture
加藤昭 (1980) +1 other reference
Fukuoka (1981)
    • Kanuma City
Akira Kato (undated manuscript) +2 other references
Fukuoka (1981)
    • Sano City
Collection of NHM
  • Tokyo Metropolis
    • Nishitama district
      • Okutama-cho
加藤昭 (1980)
Dr. Kameki Kinoshita collection (curated at Geological Survey of Japan)
  • Wakayama Prefecture
    • Iwade city
      • Afuzu-mura
Yamada (2004)
  • Yamaguchi Prefecture
    • Iwakuni City
Fukuoka (1981)
Lee (1955) +2 other references
    • Kudamatsu City
Fumitoshi HIROWATARI (1961) +1 other reference
Mayumi Yoshinaga (1963)
Kazakhstan
 
  • Ulytau Region
    • Karazhal
      • Zhayrem (Zhairem)
Vereshchagin et al. (2019) +1 other reference
Kyrgyzstan
 
  • Issyk-Kul Region
    • Inyl'chek Range
      • Muzeinyi Valley
Pautov et al. (1989)
Namibia
 
  • Otjozondjupa Region
    • Otavi Constituency
      • Kombat
Dunn et al. (1988) +1 other reference
Romania
 
Hîrtopanu et al. (2003)
  • Maramureș County
    • Târgu Lăpuș
Udubasa et al. (1996) +2 other references
  • Suceava County
    • Iacobeni
minerals-of-the-carpathians.eu (2008)
Russia
 
  • Bashkortostan
    • Sibay
Brusnitsyn et al. (2002) +1 other reference
  • Komi Republic
Brusnitsyn +1 other reference
  • Nenets Autonomous Okrug
    • Yugorskii Peninsula
      • Pai-Khoi Range (Paikhoi; Pay Khoy)
Старикова (2011)
  • Sverdlovsk Oblast
    • Sysertsky District
Brusnitsyn (2000)
      • Sedel'nikovo
Brusnitsyn A.I. (2000)
South Africa
 
  • Northern Cape
    • John Taolo Gaetsewe District Municipality
      • Ga-Segonyana Local Municipality
XRD and SEM-EDS by Joy Desor and ...
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
Dill et al. (2023)
Dill et al. (2023)
Sweden
 
  • Dalarna County
    • Hedemora
      • Garpenberg
Nysten (2003) +1 other reference
  • Värmland County
    • Filipstad
      • Långban Ore District
Gatedal (n.d.) +1 other reference
Gatedal (n.d.) +1 other reference
Mineralogical Society of America - ...
      • Persberg ore district
        • Pajsberg
Nysten (2004)
Switzerland
 
  • Grisons
    • Maloja Region
      • Samedan
        • Piz Corvatsch
Stalder et al. (1998)
    • Plessur Region
      • Arosa
        • Langwies
          • Fondei Valley
Stalder et al. (1998) +1 other reference
  • St. Gallen
    • Sarganserland
      • Sargans
Stalder et al. (1998)
  • Valais
    • Leuk
      • Turtmann-Unterems
        • Turtmann Valley
          • Pipjitälli
Ansermet et al. (2021)
    • Visp
      • Täsch
        • Täsch Valley
Stalder et al. (1998)
UK
 
  • Wales
    • Gwynedd
      • Aberdaron
        • Rhiw
Bevins (1994) +1 other reference
      • Llanfair
Cotterell (2013)
USA
 
  • California
    • Amador County
      • Fiddletown Mining District (Oleta Mining District)
        • Fiddletown (Oleta)
Van Nostrand Reinholt Press: 410 +3 other references
Hewett et al. (1961) +2 other references
    • Santa Clara County
      • Black Wonder Mining District
        • East Foothills
Van Nostrand Reinholt Press: 413 +5 other references
  • Colorado
    • San Juan County
      • Eureka Mining District
        • Gladstone
          • Bonita Peak
Rocks & Min.: 63: 366-384. +1 other reference
  • Connecticut
    • Middlesex County
      • Haddam
Schooner (circa 1980s)
  • Massachusetts
    • Hampshire County
      • Cummington
Anthony (1997)
      • Plainfield
Quinn (1945)
  • New Jersey
    • Sussex County
      • Franklin
Palache (1928) +3 other references
      • Ogdensburg
        • Sterling Hill
Cook (1969) +3 other references
  • North Carolina
    • Alleghany County
      • Sparta
        • Bald Knob
Ross et al. (1932) +2 other references
  • Virginia
    • Carroll County
      • Southern Section-Blue Ridge Province
        • Gossan Lead Mining District
Dietrich (1990)
    • Pittsylvania County
      • James River-Roanoke River Mn-Fe-Ba Mining District
Tracy et al. (2003)
  • Washington
    • Jefferson County
Cannon (1975)
    • Mason County
      • North Fork of the Skokomish River Area
Cannon (1975)
 
Mineral and/or Locality  
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