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Quadridavyne

A valid IMA mineral species
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About QuadridavyneHide

Formula:
(Na,K)6Ca2(Al6Si6O24)Cl4
Colour:
Colourless
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
2.335
Crystal System:
Hexagonal
Name:
The name reflects its unit-cell volume, which is QUADRupled relative to that of Davyne.
Dimorph of:

Unique IdentifiersHide

Mindat ID:
3335
Long-form identifier:
mindat:1:1:3335:6
GUID
(UUID V4):
5a707a39-b7dc-4dd2-b3f9-05c1e1dcf674

IMA Classification of QuadridavyneHide

Approved
IMA Formula:
[(Na,K)6Cl2][Ca2Cl2][(Si6Al6O24)]
Approval year:
1990
First published:
1994

Classification of QuadridavyneHide

9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.5.12

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
QdvIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of QuadridavyneHide

Vitreous
Transparency:
Transparent
Colour:
Colourless
Streak:
White
Hardness:
Tenacity:
Brittle
Cleavage:
Perfect
{001} perfect, {110} distinct.
Density:
2.335(5) g/cm3 (Measured)    2.354 g/cm3 (Calculated)

Optical Data of QuadridavyneHide

Type:
Uniaxial (+)
RI values:
nω = 1.529 nε = 1.532
Max Birefringence:
δ = 0.003
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemistry of QuadridavyneHide

Mindat Formula:
(Na,K)6Ca2(Al6Si6O24)Cl4
Common Impurities:
S

Crystallography of QuadridavyneHide

Crystal System:
Hexagonal
Class (H-M):
6/m - Dipyramidal
Space Group:
P63/m
Cell Parameters:
a = 25.77 Å, c = 5.37 Å
Ratio:
a:c = 1 : 0.208
Unit Cell V:
3,088.40 ų (Calculated from Unit Cell)
Morphology:
Hexagonal prismatic. Dominant fonus are {0001} and {1010}.
Twinning:
Twinning (1100) has been frequently observed.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0006545QuadridavyneBonaccorsi E, Merlino S, Orlandi P, Pasero M, Vezzalini G (1994) Quadridavyne, [(Na,K)6Cl2][Ca2Cl2][Si6Al6O24], a new feldspathoid mineral from Vesuvius area European Journal of Mineralogy 6 481-4871994Vesuvius, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.71 Å(Very strong)
3.31 Å(Very strong)
4.80 Å(Strong)
2.788 Å(Strong)
2.677 Å(Medium)
2.474 Å(Medium)
2.147 Å(Medium)
Comments:
Can be distinguished from davyne only by single-crystal diffraction.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
9 : Lava/xenolith minerals (hornfels, sanidinite facies)
High-𝑇 alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of QuadridavyneHide

General Appearance of Type Material:
Transparent, colorless, prismatic crystals, elongated [001] with hexagonal outline, up to 2 mm in length and 0.5 mm in
diameter.
Place of Conservation of Type Material:
University of Pisa, Pisa, Italy, 10014.
Geological Setting of Type Material:
Volcanic ash samples that also contain lithic fragments composed of metasomatized and hydrothermally altered lavas and scoriae.

Synonyms of QuadridavyneHide

Other Language Names for QuadridavyneHide

Relationship of Quadridavyne to other SpeciesHide

Other Members of this group:
Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P3 1c
Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex. 6 : P6
Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 6 2 2 : P63 2 2
PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6 m2 : P62c
SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P3 1c
Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex. 6 2 2 : P62 2 2
UM2004-48-SiO:AlClCaNaS(Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3
UM2009-23-SiO:AlCCaClHKNaS(Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2OTrig. 3 : P3
Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63

Related Minerals - Strunz-mindat GroupingHide

9.FB.SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6 m2 : P62c
9.FB.SapozhnikoviteNa8(Al6Si6O24)(HS)2Iso. 4 3m : P4 3n
9.FB.BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
9.FB.SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
9.FB.Bolotinaite(Na7◻)(Al6Si6O24)F · 4H2OIso. 4 3m : I4 3m
9.FB.Wenlanzhangite-(Y)Y2V3+2V4+2(SiO4)2O4(OH)4Tric. 1 : P1
9.FB.05Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P3 1c
9.FB.05Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
9.FB.05CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
9.FB.05Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
9.FB.05Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
9.FB.05Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
9.FB.05HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
9.FB.05Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex. 6 : P6
9.FB.05MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 6 2 2 : P63 2 2
9.FB.05PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
9.FB.05Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
9.FB.05Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex. 6 2 2 : P62 2 2
9.FB.05Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
9.FB.05Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
9.FB.05Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
9.FB.05Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
9.FB.05Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
9.FB.05KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
9.FB.05Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
9.FB.05CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
9.FB.05DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
9.FB.05KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
9.FB.05SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P3 1c
9.FB.10BicchuliteCa2(Al2SiO6)(OH)2Iso. 4 3m : I4 3m
9.FB.10DanaliteBe3Fe2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10GenthelviteBe3Zn4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10 vaHackmaniteNa8Al6Si6O24(Cl2,S)
9.FB.10HaüyneNa3Ca(Si3Al3)O12(SO4)Iso. 4 3m : P4 3n
9.FB.10HelvineBe3Mn2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10KamaishiliteCa2(Al2SiO6)(OH)2Tet.
9.FB.10LazuriteNa7Ca(Al6Si6O24)(SO4)(S3) · H2OIso. 4 3m : P4 3n
9.FB.10NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
9.FB.10SodaliteNa4(Si3Al3)O12ClIso. 4 3m : P4 3n
9.FB.10Tsaregorodtsevite(N(CH3)4)(AlSi5O12)Orth. 2 2 2 : I2 2 2
9.FB.10TugtupiteNa4BeAlSi4O12ClTet. 4 : I4
9.FB.10VladimirivanoviteNa6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2OOrth. mmm (2/m 2/m 2/m)
9.FB.15MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
9.FB.15MeioniteCa4Al6Si6O24CO3Tet. 4/m : I4/m
9.FB.15Silvialite(Ca,Na)4(Al6Si6O24)(SO4,CO3)Tet. 4/m : I4/m

Fluorescence of QuadridavyneHide

Not fluorescent.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for QuadridavyneHide

References for QuadridavyneHide

Localities for QuadridavyneHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany
 
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Vordereifel
        • Ettringen
Blass
Italy
 
  • Campania
    • Naples
      • Somma-Vesuvius Complex
Russo et al. (2004)
Bonaccorsi et al. (1994)
 
Mineral and/or Locality  
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