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Liottite

A valid IMA mineral species
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About LiottiteHide

02860760017059440594305.jpg
Luciano Liotti
Formula:
(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4
Colour:
Colourless
Hardness:
5
Specific Gravity:
2.56
Crystal System:
Hexagonal
Name:
Named in 1977 by S. Merlino and P. Orlandi in honor of Luciano Liotti (1932 - 2006), a mineral collector who donated the material in which liottite was first found.
This page provides mineralogical data about Liottite.


Unique IdentifiersHide

Mindat ID:
2411
Long-form identifier:
mindat:1:1:2411:8
GUID
(UUID V4):
15d76e50-9c9b-49be-8028-ce6b205df524

IMA Classification of LiottiteHide

Approved
IMA Formula:
Na16Ca8Si18Al18O72(SO4)5Cl4
Approval year:
1975
First published:
1977

Classification of LiottiteHide

9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.5.9

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
17.10.5

17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
LioIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LiottiteHide

Colour:
Colourless
Streak:
White
Hardness:
Density:
2.56(2) g/cm3 (Measured)    2.61 g/cm3 (Calculated)
Comment:
Measured in a mixture of bromoform and acetone.

Optical Data of LiottiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.530 nε = 1.528
Max Birefringence:
δ = 0.002
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemistry of LiottiteHide

Mindat Formula:
(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4
Common Impurities:
Fe

Crystallography of LiottiteHide

Crystal System:
Hexagonal
Class (H-M):
6 - Trigonal Dipyramidal
Space Group:
P6
Cell Parameters:
a = 12.870(1) Å, c = 16.096(2) Å
Ratio:
a:c = 1 : 1.251
Unit Cell V:
2,308.90 ų (Calculated from Unit Cell)
Morphology:
{001}, {100}, {110}, {101}, {102}, {103}, {104}, {203}, {111}, and minor forms {120}, {121}, {112}, {113}.
Comment:
Cell parameters from Ballirano et al. (1996).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005509LiottiteBallirano P, Merlino S, Bonaccorsi E, Maras A (1996) The crystal structure of liottite, a six-layer member of the cancrinite group The Canadian Mineralogist 34 1021-103019960293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.715 Å(100)
3.315 Å(75)
4.84 Å(36)
2.141 Å(24)
2.686 Å(10)
2.471 Å(10)
1.801 Å(10)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of LiottiteHide

General Appearance of Type Material:
Flattened hexagonal prisms up to 1 cm in diameter.
Place of Conservation of Type Material:
University of Pisa, Pisa, Italy, 3209.
University of Modena, Modena, Italy.
Geological Setting of Type Material:
In cavities of ejected blocks in a pumice deposit.
Associated Minerals at Type Locality:
Reference:
Merlino, S., Orlandi, P. (1977) Liottite, a new mineral in the cancrinite-davyne group. American Mineralogist: 62: 321-326.

Synonyms of LiottiteHide

Other Language Names for LiottiteHide

German:Liottit
Spanish:Liottita

Relationship of Liottite to other SpeciesHide

Other Members of this group:
Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P3 1c
Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 6 2 2 : P63 2 2
PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6 m2 : P62c
SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P3 1c
Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex. 6 2 2 : P62 2 2
UM2004-48-SiO:AlClCaNaS(Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3
UM2009-23-SiO:AlCCaClHKNaS(Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2OTrig. 3 : P3
Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63

Common AssociatesHide

Associated Minerals Based on Photo Data:
7 photos of Liottite associated with VesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9
5 photos of Liottite associated with AndraditeCa3Fe3+2(SiO4)3
4 photos of Liottite associated with MelaniteCa3(Fe3+,Ti)2(SiO4)3
4 photos of Liottite associated with SanidineK(AlSi3O8)
2 photos of Liottite associated with GrossularCa3Al2(SiO4)3
2 photos of Liottite associated with TitaniteCaTi(SiO4)O
1 photo of Liottite associated with Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2
1 photo of Liottite associated with MagnetiteFe2+Fe3+2O4
1 photo of Liottite associated with Augite(CaxMgyFez)(Mgy1Fez1)Si2O6
1 photo of Liottite associated with BiotiteK(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2

Related Minerals - Strunz-mindat GroupingHide

9.FB.SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6 m2 : P62c
9.FB.SapozhnikoviteNa8(Al6Si6O24)(HS)2Iso. 4 3m : P4 3n
9.FB.BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
9.FB.SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
9.FB.Bolotinaite(Na7◻)(Al6Si6O24)F · 4H2OIso. 4 3m : I4 3m
9.FB.Wenlanzhangite-(Y)Y2V3+2V4+2(SiO4)2O4(OH)4Tric. 1 : P1
9.FB.05Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P3 1c
9.FB.05Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
9.FB.05CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
9.FB.05Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
9.FB.05Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
9.FB.05Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
9.FB.05HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
9.FB.05MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 6 2 2 : P63 2 2
9.FB.05PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
9.FB.05Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
9.FB.05Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
9.FB.05Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex. 6 2 2 : P62 2 2
9.FB.05Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
9.FB.05Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
9.FB.05Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
9.FB.05Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
9.FB.05Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
9.FB.05KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
9.FB.05Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
9.FB.05CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
9.FB.05DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
9.FB.05KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
9.FB.05SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P3 1c
9.FB.10BicchuliteCa2(Al2SiO6)(OH)2Iso. 4 3m : I4 3m
9.FB.10DanaliteBe3Fe2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10GenthelviteBe3Zn4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10 vaHackmaniteNa8Al6Si6O24(Cl2,S)
9.FB.10HaüyneNa3Ca(Si3Al3)O12(SO4)Iso. 4 3m : P4 3n
9.FB.10HelvineBe3Mn2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10KamaishiliteCa2(Al2SiO6)(OH)2Tet.
9.FB.10LazuriteNa7Ca(Al6Si6O24)(SO4)(S3) · H2OIso. 4 3m : P4 3n
9.FB.10NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
9.FB.10SodaliteNa4(Si3Al3)O12ClIso. 4 3m : P4 3n
9.FB.10Tsaregorodtsevite(N(CH3)4)(AlSi5O12)Orth. 2 2 2 : I2 2 2
9.FB.10TugtupiteNa4BeAlSi4O12ClTet. 4 : I4
9.FB.10VladimirivanoviteNa6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2OOrth. mmm (2/m 2/m 2/m)
9.FB.15MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
9.FB.15MeioniteCa4Al6Si6O24CO3Tet. 4/m : I4/m
9.FB.15Silvialite(Ca,Na)4(Al6Si6O24)(SO4,CO3)Tet. 4/m : I4/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LiottiteHide

References for LiottiteHide

Localities for LiottiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy
 
  • Campania
    • Naples
      • Bacoli
www.geocities.com/gmgn/n1_96-4.htm +2 other references
Russo (2010)
in the collection of Luigi Mattei
  • Lazio
    • Metropolitan City of Rome Capital
      • Magliano Romano
Liotti L. and Tealdi E. (1983)
      • Sacrofano
Chukanov et al. (2022)
    • Viterbo Province
Stoppani et al. (1982)
      • Onano
Cresta et al. (2002)
      • Valentano
Collected & analyzed by Rossano Carlini
  • Tuscany
    • Grosseto Province
      • Pitigliano
Merlino et al. (1977)
 
Mineral and/or Locality  
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