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Davyne

A valid IMA mineral species - grandfathered
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About DavyneHide

05628150014947572517791.jpg
Sir Humphry Davy
Formula:
(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2
Colour:
Colourless, white
Lustre:
Vitreous
Hardness:
5½ - 6
Specific Gravity:
2.42 - 2.53
Crystal System:
Hexagonal
Name:
Named by T. Monticelli and N. Covelli in 1825 in honor of Sir Humphry Davy (17 December 1778, Penzance, Cornwall, England - 29 May 1829, Geneva, Switzerland), chemist who first isolated potassium, sodium, calcium, strontium, barium, magnesium and boron.

Cancrinite Group.

In the structure there are large channels closed by 12-membered tetrahedra rings. The channels are surrounded by cages, that are set in columns. In the "davyne subgroup" the cages contain [CaCl]+ lusters.


Unique IdentifiersHide

Mindat ID:
1238
Long-form identifier:
mindat:1:1:1238:2
GUID
(UUID V4):
36b6fa0c-77eb-4309-b09a-7a10fd73fe5a

IMA Classification of DavyneHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
[(Na,K)6(SO4)0.5Cl][Ca2Cl2][(Si6Al6O24)]
First published:
1825

Classification of DavyneHide

9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.5.5

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
17.10.11

17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
DvyIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of DavyneHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
Colourless, white
Streak:
white
Hardness:
5½ - 6 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
on (10_10)
perfect to indistinct on {0001}
Fracture:
Irregular/Uneven, Conchoidal
Density:
2.42 - 2.53 g/cm3 (Measured)    2.50 g/cm3 (Calculated)

Optical Data of DavyneHide

Type:
Uniaxial (+)
RI values:
nω = 1.515 - 1.519 nε = 1.519 - 1.522
Max Birefringence:
δ = 0.004
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemistry of DavyneHide

Mindat Formula:
(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2

Crystallography of DavyneHide

Crystal System:
Hexagonal
Class (H-M):
6/m - Dipyramidal
Space Group:
P63/m
Cell Parameters:
a = 12.705(4) Å, c = 5.368(3) Å
Ratio:
a:c = 1 : 0.423
Unit Cell V:
750.40 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Prismatic crystals to 4 cm.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005240DavyneHassan I, Grundy H D (1990) Structure of davyne and implications for stacking faults Sample BM1907,210 The Canadian Mineralogist 28 341-34919900293
0005241DavyneHassan I, Grundy H D (1990) Structure of davyne and implications for stacking faults Sample 1469 The Canadian Mineralogist 28 341-34919900293
0012420DavyneRozenberg K A, Rastsvetaeva R K, Chukanov N V (2009) Crystal structures of oxalate-bearing cancrinite with an unusual arrangement of CO3 groups and sulfate-rich davyne Crystallography Reports 54 793-7992009Sar-e Sang mine, Badakhshan, Afghanistan0293
0014841DavyneBonaccorsi E, Merlino S, Pasero M (1990) Davyne: its structural relationships with cancrinite and vishnevite Neues Jahrbuch fur Mineralogie, Monatshefte 1990 97-1121990Monte Somma, Vesuvius, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.658 Å(100)
4.790 Å(73)
3.272 Å(70)
2.112 Å(48)
2.438 Å(22)
2.663 Å(19)
1.781 Å(19)
4.147 Å(17)
Comments:
M. Somma-Vesuvius, Italy. Data from Ballirano et al. (1997). Davyne can be distinguished from quadridavyne only by single-crystal diffraction.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Geological Setting:
Volcanic ejecta and leucite rich lavas.

Type Occurrence of DavyneHide

Place of Conservation of Type Material:
No defined type material.

Other Language Names for DavyneHide

German:Davyn
Russian:Давин

Varieties of DavyneHide

AcarbodavyneVariety of Davyne free of Carbon Dioxide. A member of the Cancrinite group.

Relationship of Davyne to other SpeciesHide

Other Members of this group:
Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P3 1c
Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex. 6 : P6
Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 6 2 2 : P63 2 2
PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6 m2 : P62c
SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P3 1c
Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex. 6 2 2 : P62 2 2
UM2004-48-SiO:AlClCaNaS(Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3
UM2009-23-SiO:AlCCaClHKNaS(Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2OTrig. 3 : P3
Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Davyne associated with VesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9
2 photos of Davyne associated with KaliophiliteKAlSiO4
2 photos of Davyne associated with Augite(CaxMgyFez)(Mgy1Fez1)Si2O6
2 photos of Davyne associated with SodaliteNa4(Si3Al3)O12Cl
2 photos of Davyne associated with Cancrinite Group
2 photos of Davyne associated with Hornblende Root Name Group◻Ca2(Z2+4Z3+)(AlSi7O22)(OH,F,Cl)2
2 photos of Davyne associated with Humite Group
1 photo of Davyne associated with SpinelMgAl2O4
1 photo of Davyne associated with Fayalite-Forsterite Series
1 photo of Davyne associated with Pyroxene GroupADSi2O6

Related Minerals - Strunz-mindat GroupingHide

9.FB.SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6 m2 : P62c
9.FB.SapozhnikoviteNa8(Al6Si6O24)(HS)2Iso. 4 3m : P4 3n
9.FB.BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
9.FB.SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
9.FB.Bolotinaite(Na7◻)(Al6Si6O24)F · 4H2OIso. 4 3m : I4 3m
9.FB.Wenlanzhangite-(Y)Y2V3+2V4+2(SiO4)2O4(OH)4Tric. 1 : P1
9.FB.05Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P3 1c
9.FB.05Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
9.FB.05CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
9.FB.05Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
9.FB.05Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
9.FB.05HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
9.FB.05Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex. 6 : P6
9.FB.05MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 6 2 2 : P63 2 2
9.FB.05PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
9.FB.05Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
9.FB.05Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
9.FB.05Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex. 6 2 2 : P62 2 2
9.FB.05Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
9.FB.05Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
9.FB.05Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
9.FB.05Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
9.FB.05Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
9.FB.05KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
9.FB.05Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
9.FB.05CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
9.FB.05DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
9.FB.05KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
9.FB.05SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P3 1c
9.FB.10BicchuliteCa2(Al2SiO6)(OH)2Iso. 4 3m : I4 3m
9.FB.10DanaliteBe3Fe2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10GenthelviteBe3Zn4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10 vaHackmaniteNa8Al6Si6O24(Cl2,S)
9.FB.10HaüyneNa3Ca(Si3Al3)O12(SO4)Iso. 4 3m : P4 3n
9.FB.10HelvineBe3Mn2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10KamaishiliteCa2(Al2SiO6)(OH)2Tet.
9.FB.10LazuriteNa7Ca(Al6Si6O24)(SO4)(S3) · H2OIso. 4 3m : P4 3n
9.FB.10NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
9.FB.10SodaliteNa4(Si3Al3)O12ClIso. 4 3m : P4 3n
9.FB.10Tsaregorodtsevite(N(CH3)4)(AlSi5O12)Orth. 2 2 2 : I2 2 2
9.FB.10TugtupiteNa4BeAlSi4O12ClTet. 4 : I4
9.FB.10VladimirivanoviteNa6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2OOrth. mmm (2/m 2/m 2/m)
9.FB.15MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
9.FB.15MeioniteCa4Al6Si6O24CO3Tet. 4/m : I4/m
9.FB.15Silvialite(Ca,Na)4(Al6Si6O24)(SO4,CO3)Tet. 4/m : I4/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for DavyneHide

References for DavyneHide

Reference List:

Localities for DavyneHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Egypt
 
  • Red Sea Governorate
Bonaccorsi E. et al. (1991)
Germany
 
  • Rhineland-Palatinate
    • Ahrweiler
      • Brohltal
        • Brenk
Blass et al. (2001) +1 other reference
        • Burgbrohl
Blass et al. (VI)
        • Glees
Brauns +1 other reference
        • Spessart
          • Hannebach
Hentschel (1983)
    • Mayen-Koblenz
      • Mendig
        • Mendig
Brauns +1 other reference
Brauns +1 other reference
          • Wingertsberg
Brauns +1 other reference
      • Pellenz
        • Kruft
Brauns +1 other reference
        • Nickenich
Hentschel (1983)
      • Vordereifel
        • Ettringen
[Blass et al. (5)
Italy
 
  • Campania
    • Naples
Russo (2010)
Panikorovskii et al. (2017)
NJMM (1990)
          • Ercolano
            • San Vito
          • Pollena Trocchia
Carati M.
M. Carati - Guida alla mineralogia ...
[BINON J. et al. (2004)
          • Terzigno
Luigi Chiappino data
  • Lazio
    • Metropolitan City of Rome Capital
      • Campagnano di Roma
Liotti L. (1983)
      • Sacrofano
Stoppani F.S. (1982)
    • Viterbo Province
Stoppani et al. (1982)
www.mindat.org (n.d.)
      • Viterbo
Fantappiè L. (1896) +2 other references
  • Tuscany
    • Grosseto Province
      • Pitigliano
Liotti L. (Grosseto)
Russia
 
  • Sakhalin Oblast
    • Kuril Islands (Kurile Islands)
      • Kurilsky District
        • Iturup Island
Ganino et al. (2019)
 
Mineral and/or Locality  
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