Davyne
A valid IMA mineral species - grandfathered
This page is currently not sponsored. Click here to sponsor this page.
About Davyne
Formula:
(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2
Colour:
Colourless, white
Lustre:
Vitreous
Hardness:
5½ - 6
Specific Gravity:
2.42 - 2.53
Crystal System:
Hexagonal
Member of:
Name:
Named by T. Monticelli and N. Covelli in 1825 in honor of Sir Humphry Davy (17 December 1778, Penzance, Cornwall, England - 29 May 1829, Geneva, Switzerland), chemist who first isolated potassium, sodium, calcium, strontium, barium, magnesium and boron.
Cancrinite Group.
In the structure there are large channels closed by 12-membered tetrahedra rings. The channels are surrounded by cages, that are set in columns. In the "davyne subgroup" the cages contain [CaCl]+ lusters.
In the structure there are large channels closed by 12-membered tetrahedra rings. The channels are surrounded by cages, that are set in columns. In the "davyne subgroup" the cages contain [CaCl]+ lusters.
Unique Identifiers
Mindat ID:
1238
Long-form identifier:
mindat:1:1:1238:2
GUID
(UUID V4):
(UUID V4):
36b6fa0c-77eb-4309-b09a-7a10fd73fe5a
IMA Classification of Davyne
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
[(Na,K)6(SO4)0.5Cl][Ca2Cl2][(Si6Al6O24)]
First published:
1825
Classification of Davyne
9.FB.05
9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.5.5
76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
17.10.11
17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate
17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Dvy | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Davyne
Vitreous
Transparency:
Transparent, Translucent
Colour:
Colourless, white
Streak:
white
Hardness:
5½ - 6 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
on (10_10)
perfect to indistinct on {0001}
on (10_10)
perfect to indistinct on {0001}
Fracture:
Irregular/Uneven, Conchoidal
Density:
2.42 - 2.53 g/cm3 (Measured) 2.50 g/cm3 (Calculated)
Optical Data of Davyne
Type:
Uniaxial (+)
RI values:
nω = 1.515 - 1.519 nε = 1.519 - 1.522
Max Birefringence:
δ = 0.004
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Low
Chemistry of Davyne
Mindat Formula:
(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2
Crystallography of Davyne
Crystal System:
Hexagonal
Class (H-M):
6/m - Dipyramidal
Space Group:
P63/m
Cell Parameters:
a = 12.705(4) Å, c = 5.368(3) Å
Ratio:
a:c = 1 : 0.423
Unit Cell V:
750.40 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Prismatic crystals to 4 cm.
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File Best | x | y | z | a | b | c
CIF File Best | x | y | z | a | b | c
Rotation
Stop | Start
Stop | Start
Labels
Console Off | On | Grey | Yellow
Console Off | On | Grey | Yellow
Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0005240 | Davyne | Hassan I, Grundy H D (1990) Structure of davyne and implications for stacking faults Sample BM1907,210 The Canadian Mineralogist 28 341-349 | 1990 | 0 | 293 | ||
0005241 | Davyne | Hassan I, Grundy H D (1990) Structure of davyne and implications for stacking faults Sample 1469 The Canadian Mineralogist 28 341-349 | 1990 | 0 | 293 | ||
0012420 | Davyne | Rozenberg K A, Rastsvetaeva R K, Chukanov N V (2009) Crystal structures of oxalate-bearing cancrinite with an unusual arrangement of CO3 groups and sulfate-rich davyne Crystallography Reports 54 793-799 | 2009 | Sar-e Sang mine, Badakhshan, Afghanistan | 0 | 293 | |
0014841 | Davyne | Bonaccorsi E, Merlino S, Pasero M (1990) Davyne: its structural relationships with cancrinite and vishnevite Neues Jahrbuch fur Mineralogie, Monatshefte 1990 97-112 | 1990 | Monte Somma, Vesuvius, Italy | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.658 Å | (100) |
4.790 Å | (73) |
3.272 Å | (70) |
2.112 Å | (48) |
2.438 Å | (22) |
2.663 Å | (19) |
1.781 Å | (19) |
4.147 Å | (17) |
Comments:
M. Somma-Vesuvius, Italy. Data from Ballirano et al. (1997). Davyne can be distinguished from quadridavyne only by single-crystal diffraction.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-𝑇 alteration and/or metamorphism | |
31 : Thermally altered carbonate, phosphate, and iron formations | |
Stage 4b: Highly evolved igneous rocks | >3.0 |
35 : Ultra-alkali and agpaitic igneous rocks |
Geological Setting:
Volcanic ejecta and leucite rich lavas.
Type Occurrence of Davyne
Place of Conservation of Type Material:
No defined type material.
Other Language Names for Davyne
Varieties of Davyne
Acarbodavyne | Variety of Davyne free of Carbon Dioxide. A member of the Cancrinite group. |
Relationship of Davyne to other Species
Member of:
Other Members of this group:
Afghanite | (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 | Trig. 3m : P3 1c |
Alloriite | (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 | Trig. 3m : P3 1c |
Balliranoite | (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) | Hex. 6 : P63 |
Betzite | Na6Ca2(Al6Si6O24)Cl4 | Hex. 6 : P63 |
Biachellaite | (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O | Trig. 3 : P3 |
Bystrite | (Na,K)7Ca(Al6Si6O24)(S5)Cl | Trig. 3m : P3 1c |
Cancrinite | (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O | Hex. 6 : P63 |
Cancrisilite | Na7(Al5Si7O24)(CO3) · 3H2O | Hex. 6mm : P63mc |
Carbobystrite | Na8(Al6Si6O24)(CO3) · 3.5H2O | Trig. 3m : P3 1c |
Depmeierite | Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x | Hex. 6 : P63 |
Fantappièite | [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O | Trig. 3 : R3 |
Farneseite | (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O | Hex. 6/m : P63/m |
Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O | Hex. |
Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 | Trig. 3m : P3 1c |
Hydroxycancrinite | Na8(Al6Si6O24)(OH)2 · 2H2O | Hex. 6 : P63 |
Kircherite | Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O | Trig. 3 2 : R3 2 |
Kyanoxalite | Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) | Hex. 6 : P63 |
Liottite | (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 | Hex. 6 : P6 |
Marinellite | (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O | Trig. 3m : P3 1c |
Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 | Hex. 6 2 2 : P63 2 2 |
Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O | Hex. 6 : P63 |
Quadridavyne | (Na,K)6Ca2(Al6Si6O24)Cl4 | Hex. 6/m : P63/m |
Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O | Hex. |
Slyudyankaite | Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O | Tric. 1 : P1 |
Steudelite | Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O | Hex. 6 m2 : P62c |
Sulfhydrylbystrite | Na5K2Ca[Al6Si6O24](S5)2(SH) | Trig. 3m : P3 1c |
Tounkite | (Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2O | Hex. 6 2 2 : P62 2 2 |
UM2004-48-SiO:AlClCaNaS | (Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3 | |
UM2009-23-SiO:AlCCaClHKNaS | (Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2O | Trig. 3 : P3 |
Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O | Hex. 6 : P63 |
Common Associates
Associated Minerals Based on Photo Data:
3 photos of Davyne associated with Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
2 photos of Davyne associated with Kaliophilite | KAlSiO4 |
2 photos of Davyne associated with Augite | (CaxMgyFez)(Mgy1Fez1)Si2O6 |
2 photos of Davyne associated with Sodalite | Na4(Si3Al3)O12Cl |
2 photos of Davyne associated with Cancrinite Group | |
2 photos of Davyne associated with Hornblende Root Name Group | ◻Ca2(Z2+4Z3+)(AlSi7O22)(OH,F,Cl)2 |
2 photos of Davyne associated with Humite Group | |
1 photo of Davyne associated with Spinel | MgAl2O4 |
1 photo of Davyne associated with Fayalite-Forsterite Series | |
1 photo of Davyne associated with Pyroxene Group | ADSi2O6 |
Related Minerals - Strunz-mindat Grouping
9.FB. | Steudelite | Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O |
9.FB. | Sapozhnikovite | Na8(Al6Si6O24)(HS)2 |
9.FB. | Betzite | Na6Ca2(Al6Si6O24)Cl4 |
9.FB. | Slyudyankaite | Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O |
9.FB. | Bolotinaite | (Na7◻)(Al6Si6O24)F · 4H2O |
9.FB. | Wenlanzhangite-(Y) | Y2V3+2V4+2(SiO4)2O4(OH)4 |
9.FB.05 | Afghanite | (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 |
9.FB.05 | Bystrite | (Na,K)7Ca(Al6Si6O24)(S5)Cl |
9.FB.05 | Cancrinite | (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O |
9.FB.05 | Cancrisilite | Na7(Al5Si7O24)(CO3) · 3H2O |
9.FB.05 | Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O |
9.FB.05 | Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 |
9.FB.05 | Hydroxycancrinite | Na8(Al6Si6O24)(OH)2 · 2H2O |
9.FB.05 | Liottite | (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 |
9.FB.05 | Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 |
9.FB.05 | Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O |
9.FB.05 | Quadridavyne | (Na,K)6Ca2(Al6Si6O24)Cl4 |
9.FB.05 | Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O |
9.FB.05 | Tounkite | (Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2O |
9.FB.05 | Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O |
9.FB.05 | Marinellite | (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O |
9.FB.05 | Farneseite | (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O |
9.FB.05 | Alloriite | (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 |
9.FB.05 | Biachellaite | (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O |
9.FB.05 | Fantappièite | [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O |
9.FB.05 | Kyanoxalite | Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) |
9.FB.05 | Balliranoite | (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) |
9.FB.05 | Carbobystrite | Na8(Al6Si6O24)(CO3) · 3.5H2O |
9.FB.05 | Depmeierite | Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x |
9.FB.05 | Kircherite | Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O |
9.FB.05 | Sulfhydrylbystrite | Na5K2Ca[Al6Si6O24](S5)2(SH) |
9.FB.10 | Bicchulite | Ca2(Al2SiO6)(OH)2 |
9.FB.10 | Danalite | Be3Fe2+4(SiO4)3S |
9.FB.10 | Genthelvite | Be3Zn4(SiO4)3S |
9.FB.10 va | Hackmanite | Na8Al6Si6O24(Cl2,S) |
9.FB.10 | Haüyne | Na3Ca(Si3Al3)O12(SO4) |
9.FB.10 | Helvine | Be3Mn2+4(SiO4)3S |
9.FB.10 | Kamaishilite | Ca2(Al2SiO6)(OH)2 |
9.FB.10 | Lazurite | Na7Ca(Al6Si6O24)(SO4)(S3) · H2O |
9.FB.10 | Nosean | Na8(Al6Si6O24)(SO4) · H2O |
9.FB.10 | Sodalite | Na4(Si3Al3)O12Cl |
9.FB.10 | Tsaregorodtsevite | (N(CH3)4)(AlSi5O12) |
9.FB.10 | Tugtupite | Na4BeAlSi4O12Cl |
9.FB.10 | Vladimirivanovite | Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O |
9.FB.15 | Marialite | Na4Al3Si9O24Cl |
9.FB.15 | Meionite | Ca4Al6Si6O24CO3 |
9.FB.15 | Silvialite | (Ca,Na)4(Al6Si6O24)(SO4,CO3) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Davyne
mindat.org URL:
https://www.mindat.org/min-1238.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
References for Davyne
Reference List:
Hassan, I., Grundy, H. D. (1984) The crystal structures of sodalite-group minerals. Acta Crystallographica Section B Structural Science, 40 (1) 6-13 doi:10.1107/s0108768184001683
Jambor, John L., Burke, Ernst A. J. (1990) New Mineral Names. American Mineralogist, 75 (11-12) 1431-1437
Pekov, I. V., Olysych, L. V., Chukanov, N. V., Zubkova, N. V., Pushcharovsky, D. Y., Van, K. V., Giester, G., Tillmanns, E. (2011) Crystal chemistry of cancrinite-group minerals with an AB-type framework: A review and new data. I. Chemical and structural variations. The Canadian Mineralogist, 49 (5) 1129-1150 doi:10.3749/canmin.49.5.1129
Chukanov, N. V., Pekov, I. V., Olysych, L. V., Zubkova, N. V., Vigasina, M. F. (2011) Crystal chemistry of cancrinite-group minerals with an AB-type framework: A review and new data. II. IR spectroscopy and its crystal-chemical implications. The Canadian Mineralogist, 49 (5) 1151-1164 doi:10.3749/canmin.49.5.1151
Localities for Davyne
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Quick NavTopAbout DavyneUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence Other LanguagesVarietiesRelationshipsCommon AssociatesStrunz-MindatOther InformationInternet Links References Localities Locality List
Mount Somma, Somma-Vesuvius Complex, Naples, Campania, Italy