Known synthetic nesosilicate.

The K-F-analogue of dargaite.

The modular-layered structure, broken antiperovskite type, is derived from that of hatrurite. It characterizes in the presence of triple {[W₃B₁₂](TO₄)₄} layers of arctite-nabimusaite type.

Unique IdentifiersHide

Mindat ID:

43580

Long-form identifier:

mindat:1:1:43580:4

GUID
(UUID V4):

8b2ad50c-c17c-4327-aec3-81c55b523556

IMA Classification of NabimusaiteHide

IMA status:

Approved

IMA Formula:

KCa₁₂(SiO₄)₄(SO₄)₂O₂F

First published:

2015

Type description reference:

Galuskin, E. V., Gfeller, F., Armbruster, T., Galuskina, I. O., Vapnik, Y., Murashko, M., Włodyka, R., Dzierżanowski, P. (2015) New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part I. Nabimusaite, KCa₁₂(SiO₄)₄(SO₄)₂O₂F, from larnite rocks of Jabel Harmun, Palestinian Autonomy, Israel. Mineralogical Magazine, 79 (5) 1061-1072 doi:10.1180/minmag.2015.079.5.03

Classification of NabimusaiteHide

Strunz-mindat (2023):

9.AH.35

9 : SILICATES (Germanates)
A : Nesosilicates
H : Nesosilicates with CO₃, SO₄, PO₄, etc.

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Nbm	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NabimusaiteHide

Lustre:

Vitreous

Transparency:

Transparent

Colour:

Colorless

Streak:

White

Hardness:

5 on Mohs scale

Hardness:

VHN₅₀=370 - 500 kg/mm² - Vickers

Comment:

∼5

Tenacity:

Brittle

Cleavage:

Imperfect/Fair
imperfect along (001).

Parting:

Shows pronounced parting {001}.

Density:

3.119 g/cm³ (Calculated)

Comment:

Could not be measured due to incluclions

Optical Data of NabimusaiteHide

Type:

Uniaxial (-)

RI values:

n_ω = 1.644(2) n_ε = 1.640(2)

Max Birefringence:

δ = 0.004

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

Moderate

Pleochroism:

Non-pleochroic

Chemistry of NabimusaiteHide

Mindat Formula:

KCa₁₂(SiO₄)₄(SO₄)₂O₂F

Elements listed:

Ca, F, K, O, S, Si - search for minerals with similar chemistry

Crystallography of NabimusaiteHide

Crystal System:

Trigonal

Class (H-M):

3m (3 2/m) - Hexagonal Scalenohedral

Space Group:

R3m

Setting:

R3m

Cell Parameters:

a = 7.1905(4) Å, c = 41.251(3) Å

Ratio:

a:c = 1 : 5.737

Unit Cell V:

1847.1 Å³

Morphology:

irregular grains to 0.5 mm.

Crystal StructureHide

Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4

View
CIF File Best | x | y | z | a | b | c

Rotation
Stop | Start

Labels
Console Off | On | Grey | Yellow

Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0019773	Nabimusaite	Fayos J, Glasser F P, Howie R A,Lachowski E, Perez-Mendez M (1985) Structure of dodecacalcium potassium fluoride dioxide tetrasilicate bis(sulphate), KF.2[Ca6(SO4)(SiO4)20]: a fluorine-containing phase encountered in cement clinker production process Acta Crystallographica C41 814-816		1985	synthetic	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Nabimusaite'
loop_
_publ_author_name
'Fayos J'
'Glasser F P'
'Howie R A'
'Lachowski E'
'Perez-Mendez M'
_journal_name_full 'Acta Crystallographica, Section C'
_journal_volume 41 
_journal_year 1985
_journal_page_first 814
_journal_page_last 816
_publ_section_title
;
 Structure of dodecacalcium potassium fluoride dioxide tetrasilicate bis(sulphate),
 KF.2[Ca6(SO4)(SiO4)20]: a fluorine-containing phase encountered in cement clinker
 production process
;
_database_code_amcsd 0019773
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'K Ca12 Si4 S2 O26 F'
_cell_length_a 7.197
_cell_length_b 7.197
_cell_length_c 41.224
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 1849.199
_exptl_crystal_density_diffrn      3.048
_symmetry_space_group_name_H-M 'R -3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'x,x-y,z'
  '2/3+x,1/3+x-y,1/3+z'
  '1/3+x,2/3+x-y,2/3+z'
  'y,x,-z'
  '2/3+y,1/3+x,1/3-z'
  '1/3+y,2/3+x,2/3-z'
  '-x+y,y,z'
  '2/3-x+y,1/3+y,1/3+z'
  '1/3-x+y,2/3+y,2/3+z'
  '-x,-x+y,-z'
  '2/3-x,1/3-x+y,1/3-z'
  '1/3-x,2/3-x+y,2/3-z'
  '-y,-x,z'
  '2/3-y,1/3-x,1/3+z'
  '1/3-y,2/3-x,2/3+z'
  'x-y,-y,-z'
  '2/3+x-y,1/3-y,1/3-z'
  '1/3+x-y,2/3-y,2/3-z'
  'y,-x+y,-z'
  '2/3+y,1/3-x+y,1/3-z'
  '1/3+y,2/3-x+y,2/3-z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
  '-x,-y,-z'
  '2/3-x,1/3-y,1/3-z'
  '1/3-x,2/3-y,2/3-z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  'x-y,x,-z'
  '2/3+x-y,1/3+x,1/3-z'
  '1/3+x-y,2/3+x,2/3-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
K   0.00000   0.00000   0.00000   0.02698
Ca1   0.15930   0.84070   0.39790   0.01127
Ca2   0.15330   0.84670   0.53240   0.01013
Si1   0.00000   0.00000   0.20640   0.00899
Si2   0.00000   0.00000   0.08320   0.00988
S   0.00000   0.00000  -0.32430   0.00925
O1   0.55640   0.44360  -0.35480   0.01900
O2   0.12350   0.87650   0.19460   0.01646
O3   0.12610   0.87390   0.07280   0.01393
O4   0.00000   0.00000   0.36040   0.01267
O5   0.00000   0.00000  -0.24640   0.01520
O6   0.00000   0.00000   0.12330   0.01013
O7   0.00000   0.00000   0.43030   0.00633
F   0.00000   0.00000   0.50000   0.01773

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
3.595 Å	(52)
3.105 Å	(97)
2.829 Å	(71)
2.753 Å	(97)
2.750 Å	(89)
2.140 Å	(50)
1.986 Å	(46)
1.798 Å	(100)

Comments:

From Type Description.

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere	<0.6
51 : Pyrometamorphic minerals (see also #54 and #56)	<0.36

Type Occurrence of NabimusaiteHide

Type Locality:

ⓘ Jebel Harmun (Jabel Harum), Quds Governorate, West Bank, Palestine

General Appearance of Type Material:

Xenomorphic, poikilitic crystals 0.1–0.2 mm in size, filled with inclusions of larnite and ye’elmite. Very rarely nabimusaite grains reach 0.5 mm in size.

Place of Conservation of Type Material:

Museum of Natural History in Bern, Bern, Switzerland, catalogue number NMBE 41598

Geological Setting of Type Material:

In larnite-ye'elimite nodules of pyrometamorphic rocks.

Associated Minerals at Type Locality:

Ye'elimite	Spinel	Shulamitite	Periclase	Oldhamite
Magnesioferrite	Larnite	Gehlenite	Fluorellestadite	Fluorellestadite
Dzierżanowskite	Covellite	Brownmillerite

Reference:

Galuskin, E.V., Gfeller, F., Armbruster, T., Galuskina, I.O., Vapnik, Y., Murashko, M., Włodyka, R., Dzierżanowski, P. (2015) New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part I. Nabimusaite, KCa12(SiO4)4(SO4)2O2F, from larnite rocks of Jabel Harmun, Palestinian Autonomy, Israel. Mineralogical Magazine: 79: 1061-1072.

Download:

https://rruff.info/rruff_1.0/uploads/MM79_1061.pdf

Synonyms of NabimusaiteHide

IMA2012-057

Relationship of Nabimusaite to other SpeciesHide

Member of:

Arctite Group > Arctite Supergroup

Other Members of this group:

Arctite	Na₂Ca₄(PO₄)₃F	Trig. 3m (3 2/m) : R3m
Ariegilatite	BaCa₁₂(SiO₄)₄(PO₄)₂F₂O	Trig. 3m (3 2/m) : R3m
Dargaite	BaCa₁₂(SiO₄)₄(SO₄)₂O₃	Trig. 3m : R3m

Forms a series with:

Dargaite

Nabimusaite-Dargaite Series

Common AssociatesHide

Associated Minerals Based on Photo Data:

1 photo of Nabimusaite associated with Gazeevite	BaCa₆(SiO₄)₂(SO₄)₂O
1 photo of Nabimusaite associated with Larnite	Ca₂SiO₄

Related Minerals - Strunz-mindat Grouping Hide

9.AH.	Fluorbritholite-(Nd)	Ca₂Nd₃(SiO₄)₃F	Hex. 6/m : P6₃/m
9.AH.05	Iimoriite-(Y)	Y₂[SiO₄][CO₃]	Tric. 1 : P1
9.AH.10	Tundrite-(Ce)	Na₂Ce₂Ti(SiO₄)(CO₃)₂O₂	Tric. 1 : P1
9.AH.10	Tundrite-(Nd)	Na₂(Nd,Ce)₂Ti(SiO₄)(CO₃)₂O₂
9.AH.15	Spurrite	Ca₅(SiO₄)₂(CO₃)	Mon. 2/m : P2₁/b
9.AH.15	Galuskinite	Ca₇(SiO₄)₃(CO₃)	Mon. 2/m : P2₁/b
9.AH.20	Ternesite	Ca₅(SiO₄)₂(SO₄)	Orth. mmm (2/m 2/m 2/m) : Pnma
9.AH.20	Silicocarnotite	Ca₅[(SiO₄)(PO₄)](PO₄)	Orth. mmm (2/m 2/m 2/m) : Pnma
9.AH.25	Britholite-(Ce)	(Ce,Ca)₅(SiO₄)₃OH	Hex. 6/m : P6₃/m
9.AH.25	Britholite-(Y)	(Y,Ca)₅(SiO₄)₃OH	Hex. 6/m : P6₃/m
9.AH.25	Chlorellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5Cl	Hex. 6/m : P6₃/m
9.AH.25	Fluorbritholite-(Ce)	(Ce,Ca)₅(SiO₄)₃F	Hex. 6/m : P6₃/m
9.AH.25	Fluorellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5F	Hex. 6/m : P6₃/m
9.AH.25	Hydroxylellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5(OH)	Hex. 6/mmm (6/m 2/m 2/m) : P6₃/mcm
9.AH.25	Mattheddleite	Pb₅(SiO₄)_1.5(SO₄)_1.5(Cl,OH)	Hex. 6/m : P6₃/m
9.AH.25	Tritomite-(Ce)	Ce₅(SiO₄,BO₄)₃(OH,O)
9.AH.25	Tritomite-(Y)	Y₅(SiO₄,BO₄)₃(O,OH,F)
9.AH.25	Fluorcalciobritholite	(Ca,REE)₅(SiO₄,PO₄)₃F	Hex. 6/m : P6₃/m
9.AH.25	Fluorbritholite-(Y)	(Y,Ca)₅(SiO₄)₃F	Hex. 6/m : P6₃/m
9.AH.25	Britholite-(La)	Ca₂(La,Ce,Ca)₃(SiO₄,PO₄)₃(OH,F)
9.AH.25	Calciobritholite	(Ca,Y)₅(SiO₄,PO₄)₃(OH)
9.AH.35	Dargaite	BaCa₁₂(SiO₄)₄(SO₄)₂O₃	Trig. 3m : R3m
9.AH.40	Zadovite	BaCa₆[(SiO₄)(PO₄)](PO₄)₂F	Trig. 3m : R3m
9.AH.40	Gazeevite	BaCa₆(SiO₄)₂(SO₄)₂O	Trig. 3m (3 2/m) : R3m
9.AH.40	Stracherite	BaCa₆(SiO₄)₂[(PO₄)(CO₃)]₂F	Trig. 3m (3 2/m) : R3m
9.AH.45	Flamite	Ca_8-x(Na,K)_x(SiO₄)_4-x(PO₄)_x	Orth. mm2
9.AH.50	Byzantievite	Ba₅(Ca,REE,Y)₂₂(Ti,Nb)₁₈(SiO₄)₄[(PO₄),(SiO₄)]₄(BO₃)₉O₂₂[(OH),F]₄₃(H₂O)_1.5	Trig. 3 : R3
9.AH.55	Greenwoodite	(Ba,V³⁺O)₂V³⁺₉(Fe³⁺,Fe²⁺)₂Si₂O₂₂	Trig. 3m (3 2/m) : P3m1
9.AH.60	Kihlmanite-(Ce)	Ce₂TiO₂(SiO₄)(HCO₃)₂(H₂O)	Tric. 1 : P1
9.AH.65	Tsangpoite	Ca₅(PO₄)₂(SiO₄)	Hex.
9.AH.70	Enalite	(Th,REE,Al) [(PO₄),(SiO₄),(OH)]	Tet.

Fluorescence of NabimusaiteHide

In UV light:

Does not show luminescence.

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for NabimusaiteHide

mindat.org URL:

https://www.mindat.org/min-43580.html
Please feel free to link to this page.

Search Engines:

Look for Nabimusaite on Google

Look for Nabimusaite images on Google

Look for Nabimusaite on Bing

Look for Nabimusaite images on Bing

Look for Nabimusaite on DuckDuckGo

Look for Nabimusaite images on DuckDuckGo

Look for Nabimusaite in the Rock H. Currier Digital Library

External Links:

Look for Nabimusaite on Webmineral

Look for Nabimusaite on Wikipedia

Look for Nabimusaite on Mineralien Atlas

Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

Mineral Dealers:

Buy from David K Joyce minerals

The Arkenstone - Fine Minerals

Wilensky Exquisite Minerals

Blue Gems Australian & International

High-end worldwide specimens & outstanding customer service

Buy from McDougall Minerals

Buy rare minerals from Excalibur Minerals

References for NabimusaiteHide

Reference List:

Galuskin, E.V., Gfeller, F., Armbruster, T., Galuskina, I.O., Vapnik, Y., Murashko, M., Włodyka, R. and Dzierżanowski, P. (2013) Nabimusaite, IMA 2012-057. CNMNC Newsletter No. 15, February 2013, page 5. Mineralogical Magazine: 77: 1-12.

Vapnik, Y., Novikov, I. (2013) Reply to Comment of Y. Kolodny, A. Burg and A. Sneh on “Combustion metamorphism in the Nabi Musa dome: new implications for a mud volcano origin of the Mottled Zone, Dead Sea area”, by E. Sokol, I. Novikov, S. Zateeva, Ye. Vapnik, R. Shagam and O. Kozmenko, Basin Research (2010), 22, 414‐438. Basin Research: 25(1): 115-120.

Localities for NabimusaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Germany
Rhineland-Palatinate Mayen-Koblenz Vordereifel Ettringen ⓘ Caspar quarry	www.mineralienatlas.de (2014) http://www.mineralienatlas.de/lexikon/index.php/Deutschland/Rheinland-Pfalz/Mayen-Koblenz-Kreis/Mayen/Ettringen/Bellerberg/Ettringer%20Bellerberg%20%28Stbr.%20Caspar%29
ⓘ Xenolith CS-050	in the collection of Christof SchäferIdentification: SEM-EDS

Israel
Southern District (HaDarom District) Tamar Regional Council Hatrurim Basin ⓘ Har Parsa (Mt. Parsa)	Galuskin, E. V., Gfeller, F., Armbruster, T., Galuskina, I. O., Vapnik, Y., Murashko, M., Włodyka, R., Dzierżanowski, P. (2015) New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part I. Nabimusaite, KCa₁₂(SiO₄)₄(SO₄)₂O₂F, from larnite rocks of Jabel Harmun, Palestinian Autonomy, Israel. Mineralogical Magazine, 79 (5) 1061-1072 doi:10.1180/minmag.2015.079.5.03

Jordan
Amman Governorate Transjordan Plateau Daba-Siwaqa complex Hashem region Lisdan-Siwaga Fault Siwaga Tulul al Hammam ⓘ Unnamed marble quarries	Sokol, E.V. Kokh, S.N. Seryotkin, Y.V. Deviatiiarova, A.S. Goryainov, S.V. Sharygin, V.V. Khoury, H.N. Karmanov, N.S. Danilovsky, V.A. Artemyev, D.A. (2020) Ultrahigh-Temperature Sphalerite from Zn-Cd-Se-Rich Combustion Metamorphic Marbles, Daba Complex, Central Jordan: Paragenesis, Chemistry, and Structure. Minerals: 10(9): 822.

Middle East
ⓘ Hatrurim Formation	Vapnik, Y., Galuskina, I., Murashko, M., Britvin, S., & Galuskin, E. (2014). The Hatrurim Complex-the New Unique Locality on World Mineral Map: the Review of Mineral Discoveries. In Israel Geological Society 2014, Annual Meeting, En Boqeq (pp. 143-144).

Palestine
West Bank Bethlehem Governorate ⓘ Nahal Darga	Galuskin, E. V., Gfeller, F., Armbruster, T., Galuskina, I. O., Vapnik, Y., Murashko, M., Włodyka, R., Dzierżanowski, P. (2015) New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part I. Nabimusaite, KCa₁₂(SiO₄)₄(SO₄)₂O₂F, from larnite rocks of Jabel Harmun, Palestinian Autonomy, Israel. Mineralogical Magazine, 79 (5) 1061-1072 doi:10.1180/minmag.2015.079.5.03 Galuskina, Irina O., Gfeller, Frank, Galuskin, Evgeny V., Armbruster, Thomas, Vapnik, Yevgeny, Dulski, Mateusz, Gardocki, Mariusz, Jeżak, Lidia, Murashko, Mikhail (2019) New minerals with modular structure derived from hatrurite from the pyrometamorphic rocks. Part IV: Dargaite, BaCa₁₂(SiO₄)₄(SO₄)₂O₃, from Nahal Darga, Palestinian Autonomy. Mineralogical Magazine, 83 (1) 81-88 doi:10.1180/minmag.2017.081.095
Jericho Governorate ⓘ Nabi Musa	Galuskin, E. V., Gfeller, F., Armbruster, T., Galuskina, I. O., Vapnik, Y., Murashko, M., Włodyka, R., Dzierżanowski, P. (2015) New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part I. Nabimusaite, KCa₁₂(SiO₄)₄(SO₄)₂O₂F, from larnite rocks of Jabel Harmun, Palestinian Autonomy, Israel. Mineralogical Magazine, 79 (5) 1061-1072 doi:10.1180/minmag.2015.079.5.03
Quds Governorate ⓘ Jebel Harmun (Jabel Harum) (TL)	Mineralogical Magazine, 77, 1-12. Galuskin, E.V., Gfeller, F., Armbruster, T., Galuskina, I.O., Vapnik, Y., Murashko, M., Włodyka, R. and Dzierz˙anowski, P. (2013) Nabimusaite, IMA 2012-057. CNMNC Newsletter No. 15, February 2013, page 5 Galuskin, E. V., Gfeller, F., Armbruster, T., Galuskina, I. O., Vapnik, Y., Murashko, M., Włodyka, R., Dzierżanowski, P. (2015) New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part I. Nabimusaite, KCa₁₂(SiO₄)₄(SO₄)₂O₂F, from larnite rocks of Jabel Harmun, Palestinian Autonomy, Israel. Mineralogical Magazine, 79 (5) 1061-1072 doi:10.1180/minmag.2015.079.5.03
ⓘ Ma'ale Adumim	Galuskin, E. V., Gfeller, F., Armbruster, T., Galuskina, I. O., Vapnik, Y., Murashko, M., Włodyka, R., Dzierżanowski, P. (2015) New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part I. Nabimusaite, KCa₁₂(SiO₄)₄(SO₄)₂O₂F, from larnite rocks of Jabel Harmun, Palestinian Autonomy, Israel. Mineralogical Magazine, 79 (5) 1061-1072 doi:10.1180/minmag.2015.079.5.03

Mindat.org is an outreach project of the Hudson Institute of Mineralogy, a 501(c)(3) not-for-profit organization.
Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2024, except where stated. Most political location boundaries are © OpenStreetMap contributors. Mindat.org relies on the contributions of thousands of members and supporters. Founded in 2000 by Jolyon Ralph.
Privacy Policy - Terms & Conditions - Contact Us / DMCA issues - Report a bug/vulnerability Current server date and time: April 28, 2024 03:35:49 Page updated: November 12, 2023 21:32:58

Go to top of page

Nabimusaite

About NabimusaiteHide