Tweddillite
A valid IMA mineral species
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About Tweddillite
Formula:
(CaSr)(Mn3+AlMn3+)O[Si2O7][SiO4](OH)
Colour:
Deep red
Lustre:
Vitreous
Hardness:
6 - 7
Specific Gravity:
3.84 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
Named by T. Armbruster et al. in 2002 in honor of Samuel Milbourn Tweddill (3 April 1852, Scarborough, Yorkshire, England - 4 July 1917, Groenvlei Tin Mine, Limpopo, South Africa), the first curator of the Pretoria Geological Museum from 1897 to 1916. It was renamed manganipiemontite-(Sr) by the Epidote Subcommittee of the CNMMN in 2006 and reverted to tweddillite in 2015.
Clinozoisite Subgroup of Epidote Group.
The (Mn3+AlMn3+)-analogue of Unnamed (Fe3+-analogue of Piemontite-(Sr)).
The (Mn3+AlMn3+)-analogue of Unnamed (Fe3+-analogue of Piemontite-(Sr)).
Unique Identifiers
Mindat ID:
11118
Long-form identifier:
mindat:1:1:11118:0
GUID
(UUID V4):
(UUID V4):
6cdccbe6-1729-4d8d-bd33-5583ecd1ddba
IMA Classification of Tweddillite
Approved
IMA Formula:
CaSr(Mn3+2Al)[Si2O7][SiO4]O(OH)
First published:
2002
Approval history:
Originally called tweddillite; renamed manganipiemontite-(Sr) by the Epidote Subcommittee of the CNMMN in 2006; reverted to tweddillite in 2015.
Type description reference:
Classification of Tweddillite
9.BG.05
9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Twe | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Tweddillite
Vitreous
Colour:
Deep red
Streak:
Brownish red
Hardness:
6 - 7 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
perfect after {001}
perfect after {001}
Fracture:
Sub-Conchoidal
Density:
3.84(3) g/cm3 (Calculated)
Optical Data of Tweddillite
Type:
Biaxial (+)
Pleochroism:
Strong
Comments:
Within the (001) blades, the crystals appear dark red parallel to b and orange-yellow parallel to a. Perpendicular to (001) the blades appear magenta to red.
Comments:
Average RI = 1.825.
Chemistry of Tweddillite
Mindat Formula:
(CaSr)(Mn3+AlMn3+)O[Si2O7][SiO4](OH)
Common Impurities:
Fe
Chemical Analysis
Oxide wt%:
1 | 2 | |
---|---|---|
SiO2 | 32.6 % | 33.0 % |
ThO2 | 0.2 % | 0.2 % |
Al2O3 | 12.9 % | 13.6 % |
Ga2O3 | 0.1 % | % |
Cr2O3 | 0.1 % | % |
La2O3 | 9.2 % | 3.1 % |
Ce2O3 | 0.2 % | 0.3 % |
Pr2O3 | 1.5 % | 0.8 % |
Nd2O3 | 2.6 % | 1.9 % |
Sm2O3 | 0.1 % | 0.1 % |
Mn2O3 | 15.0 % | 19.4 % |
Fe2O3 | 1.5 % | 1.2 % |
MnO | 1.4 % | 0.9 % |
MgO | 2.2 % | 0.6 % |
CaO | 10.6 % | 13.7 % |
SrO | 7.2 % | 8.6 % |
Na2O | 0.5 % | 0.2 % |
H2O | 1.6 % | 1.7 % |
Total: | 99.5 % | 99.3 % |
Sample references:
ID | Locality | Reference | Notes |
---|---|---|---|
1 | Praborna Mine, Saint-Marcel, Aosta Valley, Italy | EPMA data for zoned composite tweddellite-piemontite grains in Mn-rich schist. analysis spot #23 | |
2 | " " | EPMA data for zoned composite tweddellite-piemontite grains in Mn-rich schist. analysis spot #34 |
Crystallography of Tweddillite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Setting:
P21/m
Cell Parameters:
a = 8.932(5) Å, b = 5.698(4) Å, c = 10.310(5) Å
β = 114.56(4)°
β = 114.56(4)°
Ratio:
a:b:c = 1.568 : 1 : 1.809
Unit Cell V:
477.25 ų (Calculated from Unit Cell)
Twinning:
All crystals are (100) twinned.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0014561 | Tweddillite | Armbruster T, Gnos E, Dixon R, Gutzmer J, Hejny C, Dobelin N, Medenbach O (2002) Manganvesuvianite and tweddillite, two new Mn3+-silicate minerals from the Kalahari manganese fields, South Africa Mineralogical Magazine 66 137-150 | 2002 | Kalahari manganese fields, South Africa | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
2.936 Å | (100) |
2.703 Å | (80) |
2.586 Å | (80) |
2.182 Å | (80) |
3.515 Å | (50) |
2.149 Å | (40) |
2.415 Å | (30) |
2.320 Å | (30) |
2.126 Å | (30) |
1.8957 Å | (30) |
1.7178 Å | (30) |
1.6695 Å | (30) |
Type Occurrence of Tweddillite
General Appearance of Type Material:
Dark-red ‘suns’ of very thin (~0.02 mm) radiating (001) blades, elongated parallel to [010] (up to 0.5 mm).
Place of Conservation of Type Material:
(NMBE 35475) at the Natural History Museum, Bern, Switzerland.
Geological Setting of Type Material:
In calcsilicate rocks formed as hydrothermal alteration of primary sedimentary manganese ore.
Associated Minerals at Type Locality:
Reference:
Armbruster, T., Gnos, E., Dixon, R., Gutzmer, J., Hejny, C., Döbelin, N., Medenbach, O. (2002) Manganvesuvianite and tweddillite, two new Mn3+-silicate minerals from the Kalahari Manganese fields, South Africa. Mineralogical Magazine: 66: 137-150.
Synonyms of Tweddillite
Other Language Names for Tweddillite
German:Tweddillit
Twedillit
Twedillit
Russian:Манганипьемонтит-(Sr)
Тведдилит
Тведдилит
Simplified Chinese:特威迪尔石
Spanish:Tweddillita
Twedillita
Twedillita
Traditional Chinese:特威迪爾石
Relationship of Tweddillite to other Species
Member of:
Other Members of this group:
Clinozoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) | Mon. 2/m : P21/m |
Epidote | (CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH) | Mon. 2/m : P21/m |
Epidote-(Sr) | (CaSr)(AlAlFe3+)O[Si2O7][SiO4](OH) | Mon. 2/m : P21/m |
Hancockite | (CaPb)(AlAlFe3+)O[Si2O7][SiO4](OH) | Mon. 2/m : P21/m |
Heflikite | (CaCa)(AlAlSc)O[Si2O7][SiO4](OH) | Mon. 2/m : P21/m |
Mukhinite | (CaCa)(AlAlV3+)O[Si2O7][SiO4](OH) | Mon. |
Niigataite | (CaSr)(AlAlAl)O[Si2O7][SiO4](OH) | Mon. 2/m : P21/m |
Piemontite | (CaCa)(AlAlMn3+)O[Si2O7][SiO4](OH) | Mon. 2/m : P21/m |
Piemontite-(Pb) | (CaPb)(AlAlMn3+)O[Si2O7][SiO4](OH) | Mon. 2/m : P21/m |
Piemontite-(Sr) | (CaSr)(AlAlMn3+)O[Si2O7][SiO4](OH) | Mon. 2/m : P21/m |
Unnamed (Fe3+ analogue of Piemontite-(Pb)) | (CaPb)(Fe3+AlMn3+)O[Si2O7][SiO4](OH) | |
Unnamed (Fe3+-analogue of Piemontite) | (CaCa)(Fe3+AlMn3+)O[Si2O7][SiO4](OH) | |
Unnamed (Fe3+-analogue of Piemontite-(Sr)) | (CaSr)(Fe3+AlMn3+)O[Si2O7][SiO4](OH) | |
Unnamed (Ga-analogue of Epidote) | (CaCa)(AlAlGa3+)O[Si2O7][SiO4](OH) |
Common Associates
Associated Minerals Based on Photo Data:
1 photo of Tweddillite associated with Strontium-bearing Piemontite | {(Ca,Sr)2}{Al2Mn3+}(Si2O7)(SiO4)O(OH) |
1 photo of Tweddillite associated with Braunite | Mn2+Mn3+6(SiO4)O8 |
1 photo of Tweddillite associated with Cryptomelane | K(Mn4+7Mn3+)O16 |
1 photo of Tweddillite associated with Aegirine | NaFe3+Si2O6 |
1 photo of Tweddillite associated with Alurgite | K(Al,Mn3+)2(AlSi3O10)(OH)2 |
1 photo of Tweddillite associated with Hennomartinite | SrMn3+2(Si2O7)(OH)2 · H2O |
1 photo of Tweddillite associated with Sugilite | KNa2Fe3+2Li3[Si12O30] |
Related Minerals - Strunz-mindat Grouping
9.BG. | Shuiskite-(Cr) | Ca2Cr3+Cr3+2[Si2O6OH][SiO4](OH)2O |
9.BG. | Alnaperbøeite-(Ce) | Ca(Ce2.5Na0.5)(AlAl2Al)[Si2O7][SiO4]3O(OH)2 |
9.BG. | Magnesiovesuvianite | Ca19MgAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
9.BG. | Alumovesuvianite | Ca19AlAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
9.BG. | Zoisite-(Pb) | (CaPb)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG. | Vielleaureite-(Ce) | (Mn2+Ce)(MgAlMn2+)F[Si2O7][SiO4](OH) |
9.BG. | Heflikite | (CaCa)(AlAlSc)O[Si2O7][SiO4](OH) |
9.BG. | Zilbermintsite-(La) | (CaLa5)(Fe3+Al3Fe2+)[Si2O7][SiO4]5O(OH)3 |
9.BG.05b | Allanite-(Ce) | (CaCe)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Allanite-(La) | (CaLa)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Allanite-(Y) | (CaY)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05a | Clinozoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG.05b | Dissakisite-(Ce) | (CaCe)(AlAlMg)O[Si2O7][SiO4](OH) |
9.BG.05 | Dollaseite-(Ce) | (CaCe)(MgAlMg)F[Si2O7][SiO4](OH) |
9.BG.05a | Epidote | (CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05a | Hancockite | (CaPb)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05 | Khristovite-(Ce) | (CaCe)(MgAlMn2+)F[Si2O7][SiO4](OH) |
9.BG.05a | Mukhinite | (CaCa)(AlAlV3+)O[Si2O7][SiO4](OH) |
9.BG.05a | Piemontite | (CaCa)(AlAlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05 | Piemontite-(Sr) | (CaSr)(AlAlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Manganiandrosite-(La) | (Mn2+La)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Ferriallanite-(Ce) | (CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Niigataite | (CaSr)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG.05 | Manganiandrosite-(Ce) | (Mn2+Ce)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Dissakisite-(La) | (CaLa)(AlAlMg)O[Si2O7][SiO4](OH) |
9.BG.05 | Vanadoandrosite-(Ce) | (Mn2+Ce)(V3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Uedaite-(Ce) | (Mn2+Ce)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05a | Epidote-(Sr) | (CaSr)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Allanite-(Nd) | (CaNd)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Unnamed (Mg-analogue of Ferriallanite-(Ce)) | (CaCe)(Fe3+AlMg)O[Si2O7][SiO4](OH) |
9.BG.05b | Unnamed (Mn3+-analogue of Ferriakasakaite-(Ce)) | (CaCe)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Ferriallanite-(La) | (CaLa)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Åskagenite-(Nd) | (Mn2+Nd)(AlAlFe3+)O[Si2O7][SiO4]O |
9.BG.05 | Piemontite-(Pb) | (CaPb)(AlAlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Vanadoallanite-(La) | (CaLa)(V3+AlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Ferriakasakaite-(La) | (CaLa)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Ferriandrosite-(La) | (Mn2+La)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Androsite-(Ce) | (Mn2+Ce)(AlAlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Ferriandrosite-(Ce) | (Mn2+Ce)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05a v | Unnamed (Ga-analogue of Epidote) | (CaCa)(AlAlGa3+)O[Si2O7][SiO4](OH) |
9.BG.05b | UM1989-32-SiO:AlCaFeHREE | (Ca0.5◻0.5REE)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Manganiakasakaite-(La) | (CaLa)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Ferriakasakaite-(Ce) | (CaCe)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Allanite-(Sm) | (CaSm)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.10 | Zoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG.15 | Macfallite | Ca2Mn3+3(SiO4)(Si2O7)(OH)3 |
9.BG.15 | Sursassite | Mn2+2Al3(SiO4)(Si2O7)(OH)3 |
9.BG.20 | Julgoldite-(Fe2+) | Ca2Fe2+Fe3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.20 | Okhotskite | Ca2Mn2+Mn3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.20 | Pumpellyite-(Fe2+) | Ca2Fe2+Al2(Si2O7)(SiO4)(OH,O)2 · H2O |
9.BG.20 | Pumpellyite-(Fe3+) | Ca2Fe3+Al2(Si2O7)(SiO4)(OH,O)2 · H2O |
9.BG.20 | Pumpellyite-(Mg) | Ca2MgAl2(Si2O7)(SiO4)(OH)2 · H2O |
9.BG.20 | Pumpellyite-(Mn2+) | Ca2Mn2+Al2(Si2O7)(SiO4)(OH)2 · H2O |
9.BG.20 | Shuiskite-(Mg) | Ca2MgCr3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.20 | Julgoldite-(Fe3+) | Ca2Fe3+Fe3+2[Si2O6OH][SiO4](OH)2O |
9.BG.20 | Pumpellyite-(Al) | Ca2Al3(Si2O7)(SiO4)(OH,O)2 · H2O |
9.BG.20 | Poppiite | Ca2V3+V3+2[Si2O6OH][SiO4](OH)2O |
9.BG.20 | Julgoldite-(Mg) | Ca2MgFe3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.25 | Ganomalite | Pb9Ca5Mn(Si2O7)4(SiO4)O |
9.BG.25 | Wayneburnhamite | Pb9Ca6(Si2O7)3(SiO4)3 |
9.BG.30 | Rustumite | Ca10(Si2O7)2(SiO4)(OH)2Cl2 |
9.BG.35 | Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
9.BG.35 | Wiluite | Ca19MgAl4(Al,Mg)8(B,◻)4◻[Si2O7]4[(SiO4)10]O(O,OH)9 |
9.BG.35 | Manganvesuvianite | Ca19Mn3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
9.BG.35 | Fluorvesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(F,OH)9 |
9.BG.35 | Cyprine | Ca19Cu2+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
9.BG.35 | Hongheite | Ca19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9 |
9.BG.35 | Milanriederite | (Ca18[REE])Fe3+Al4(Mg4Al4)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
9.BG.35 | Manaevite-(Ce) | (Ca13Ce4[H2O]2)Mg(Al3Mg)(Mg3Ti3Fe3+2)(◻4)◻[Si2O7]4[(SiO4)8(H4O4)2]O(OH)9 |
9.BG.40 | Vyuntspakhkite-(Y) | (Y,Yb)4Al2.5-1.5(Si,Al)1.5-2.5(SiO4)4O(OH)7 |
9.BG.45 | Dellaite | Ca6Si3O11(OH)2 |
9.BG.50 | Gatelite-(Ce) | CaCe3(AlAl2Mg)[Si2O7][SiO4]3O(OH)2 |
9.BG.50 | Perbøeite-(Ce) | CaCe3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.50 | Ferriperbøeite-(Ce) | CaCe3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.50 | Ferriperbøeite-(La) | CaLa3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.50 | Perbøeite-(La) | CaLa3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.55 | Västmanlandite-(Ce) | CaCe3(MgAl2Mg)[Si2O7][SiO4]3F(OH)2 |
9.BG.60 | Radekškodaite-(La) | (CaLa5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3 |
9.BG.60 | Radekškodaite-(Ce) | (CaCe5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3 |
9.BG.60 | Radekškodaite Group | (CaM5)([Fe3+Al3]Fe2+)[Si2O7][SiO4]5O(OH)3 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Tweddillite
mindat.org URL:
https://www.mindat.org/min-11118.html
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External Links:
References for Tweddillite
Reference List:
Armbruster, T., Gnos, E., Dixon, R., Gutzmer, J., Hejny, C., Döbelin, N., Medenbach, O. (2002) Manganvesuvianite and tweddillite, two new Mn3+-silicate minerals from the Kalahari manganese fields, South Africa. Mineralogical Magazine, 66 (1) 137-150 doi:10.1180/0026461026610018
Armbruster, Thomas, Bonazzi, Paola, Akasaka, Masahide, Bermanec, Vladimir, Chopin, Christian, Gieré, Reto, Heuss-Assbichler, Soraya, Liebscher, Axel, Menchetti, Silvio, Pan, Yuanming, Pasero, Marco (2006) Recommended nomenclature of epidote-group minerals. European Journal of Mineralogy, 18 (5) 551-567 doi:10.1127/0935-1221/2006/0018-0551
Localities for Tweddillite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Italy | |
| Frank K. Mazdab collection (see https://www.rockptx.com/fkm-151-to-fkm-175/#FKM-171 for normalized analysis) |
Japan | |
| Fukushima et al. (2005) |
Lapis 2002 (11) +1 other reference | |
South Africa (TL) | |
| Lapis 2002 (11) +1 other reference |
Spain | |
| Dill et al. (2023) |
Dill et al. (2023) | |
Dill et al. (2023) |
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Wessels Mine, Joe Morolong Local Municipality, John Taolo Gaetsewe District Municipality, Northern Cape, South Africa