Magnussonite
A valid IMA mineral species - grandfathered
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About Magnussonite
Formula:
Mn2+10(As3+O3)6(OH,Cl)2
Initial (Moore & Araki, 1979) structural formula: Mn2+18[As3+6Mn+O18]2Cl2 but it is not necessarily confirmed (or disproved) by further studies
Colour:
Emerald- or grass-green; bluish green; pale green, olive-green. greenish-tan
Lustre:
Sub-Vitreous, Resinous, Greasy
Hardness:
3½ - 4
Specific Gravity:
4.14 - 4.49
Crystal System:
Isometric
Name:
Named in 1956 by Olof Erik Gabrielson in honor of Professor Nils Harald Magnusson [January 15, 1890 Filipstad, Sweden - September 28, 1976 Stockholm, Sweden], Director of the Geological Survey of Sweden and professor of geology at the Royal Institute of Technology in Stockholm, Sweden for his contributions to the geology and mineralogy of LĂ„ngban.
Related to UM1984-09-AsO:ClHMn. Also said to be the OH analogue of brattforsite, although with a higher symmetry.
Fluorite structure derivative.
Magnussonite is / may be the only mineral with univalent manganese. Indeed, in its structure, octahedral [Mn+(AsO3)6] does exist (e.g., Bowell et al. 2015; Hawthorne et al., 2022).
Fluorite structure derivative.
Magnussonite is / may be the only mineral with univalent manganese. Indeed, in its structure, octahedral [Mn+(AsO3)6] does exist (e.g., Bowell et al. 2015; Hawthorne et al., 2022).
Unique Identifiers
Mindat ID:
2543
Long-form identifier:
mindat:1:1:2543:6
GUID
(UUID V4):
(UUID V4):
73e086c5-a7ff-4926-a222-a62afff2ec86
IMA Classification of Magnussonite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Mn2+10As3+6O18(OH,Cl)2
Classification of Magnussonite
4.JB.15
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
J : Arsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodates
B : Arsenites, antimonites, bismuthites; with additional anions, without H2O
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
J : Arsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodates
B : Arsenites, antimonites, bismuthites; with additional anions, without H2O
46.1.6.1
46 : ANTIMONITES AND ARSENITES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO3)pZq
46 : ANTIMONITES AND ARSENITES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO3)pZq
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Mnu | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Magnussonite
Sub-Vitreous, Resinous, Greasy
Transparency:
Translucent
Comment:
Made be earthy when fine-grained
Colour:
Emerald- or grass-green; bluish green; pale green, olive-green. greenish-tan
Streak:
White
Hardness:
3½ - 4 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Sub-Conchoidal
Density:
4.14 - 4.49 g/cm3 (Measured) 4.55 g/cm3 (Calculated)
Optical Data of Magnussonite
Type:
Isotropic
Pleochroism:
Non-pleochroic
Chemistry of Magnussonite
Mindat Formula:
Mn2+10(As3+O3)6(OH,Cl)2
Initial (Moore & Araki, 1979) structural formula: Mn2+18[As3+6Mn+O18]2Cl2 but it is not necessarily confirmed (or disproved) by further studies
Initial (Moore & Araki, 1979) structural formula: Mn2+18[As3+6Mn+O18]2Cl2 but it is not necessarily confirmed (or disproved) by further studies
Crystallography of Magnussonite
Crystal System:
Isometric
Class (H-M):
m3m (4/m 3 2/m) - Hexoctahedral
Space Group:
Ia3d
Cell Parameters:
a = 19.680 Å
Unit Cell V:
7,622.11 Ă
Âł (Calculated from Unit Cell)
Z:
32
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0000713 | Magnussonite | Moore P B, Araki T (1979) Magnussonite, manganese arsenite, a fluorite derivative structure American Mineralogist 64 390-401 | 1979 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
8.01 Ă | (10) |
5.26 Ă | (5) |
4.92 Ă | (5) |
4.02 Ă | (10) |
3.20 Ă | (5) |
3.125 Ă | (30) |
2.850 Ă | (100) |
2.710 Ă | (5) |
2.470 Ă | (30) |
2.350 Ă | (5) |
2.030 Ă | (5) |
1.740 Ă | (20) |
1.700 Ă | (5) |
1.690 Ă | (5) |
1.610 Ă | (5) |
1.480 Ă | (10) |
1.420 Ă | (5) |
Comments:
ICDD 10-407
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-đ alteration and/or metamorphism | |
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits | |
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47d : [Arsenates, antimonates, selenates, bismuthinates] | |
47e : [Vanadates, chromates, manganates] | |
47h : [Near-surface oxidized, dehydrated minerals] |
Geological Setting:
Irregular masses to several cm carbonate-hosted zinc oress.
Type Occurrence of Magnussonite
General Appearance of Type Material:
As finegrained encrustations in fissures in hausmannite impregnated dolomite or in finegrained hematite.
Associated Minerals at Type Locality:
Other Language Names for Magnussonite
Common Associates
Associated Minerals Based on Photo Data:
16 photos of Magnussonite associated with Franklinite | Zn2+Fe3+2O4 |
15 photos of Magnussonite associated with Zincite | ZnO |
14 photos of Magnussonite associated with Calcite | CaCO3 |
13 photos of Magnussonite associated with Willemite | Zn2SiO4 |
8 photos of Magnussonite associated with Adelite | CaMg(AsO4)(OH) |
4 photos of Magnussonite associated with Hausmannite | Mn2+Mn3+2O4 |
3 photos of Magnussonite associated with Dolomite | CaMg(CO3)2 |
3 photos of Magnussonite associated with Allactite | Mn2+7(AsO4)2(OH)8 |
1 photo of Magnussonite associated with Pyrobelonite | PbMn2+(VO4)(OH) |
1 photo of Magnussonite associated with Hematite | Fe2O3 |
Related Minerals - Strunz-mindat Grouping
4.JB. | Cuyaite | Ca2Mn3+As3+14O24Cl |
4.JB. | Brattforsite | Mn19(AsO 3)12Cl2 |
4.JB.05 | Fetiasite | (Fe3+,Fe2+,Ti)3(As2O5)O2 |
4.JB.10 | Manganarsite | Mn3(As2O4)(OH)4 |
4.JB.15 | UM1984-09-AsO:ClHMn | Mn10As6O18(OH)Cl |
4.JB.20 | Armangite | Mn2+26(AsO3)14(HAsO3)4(CO3) |
4.JB.25 | Nanlingite | Na(Ca5Li)Mg12(AsO3)2[Fe(AsO3)6]F14 |
4.JB.30 | Asbecasite | Ca3(Ti,Sn4+)Be2(AsO3)6(SiO4)2 |
4.JB.35 | Stenhuggarite | CaFeSb(AsO3)2O |
4.JB.40 | Trigonite | Pb3Mn2+(AsO3)2(HAsO3) |
4.JB.45 | Finnemanite | Pb5(AsO3)3Cl |
4.JB.50 | Gebhardite | Pb8(As2O5)2OCl6 |
4.JB.55 | Derbylite | Fe3+4Ti3Sb3+O13(OH) |
4.JB.55 | Tomichite | (V,Fe)4Ti3AsO13(OH) |
4.JB.55 | Graeserite | Fe3+4Ti3As3+O13(OH) |
4.JB.60 | Hemloite | (Ti,V3+,Fe3+,Al)12(As3+,Sb3+)2O23(OH) |
4.JB.65 | Freedite | Cu+Pb8(AsO3)2O3Cl5 |
4.JB.70 | Georgiadesite | Pb4(As3+O3)Cl4(OH) |
4.JB.75 | Ekatite | (Fe3+,Fe2+,Zn)12(AsO3)6(AsO3,HSiO4)2(OH)6 |
4.JB.75 | Szklaryite | â»Al6BAs3+3O15 |
4.JB.85 | Lepageite | Mn2+3(Fe3+7Fe2+4)O3[Sb3+5As3+8O34] |
4.JB.90 | Bianchiniite | Ba2(TiV)(As2O5)2OF |
Fluorescence of Magnussonite
Not fluorescent in ultraviolet
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Magnussonite
mindat.org URL:
https://www.mindat.org/min-2543.html
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References for Magnussonite
Reference List:
Moore, Paul B., Araki, Takaharu (1979) Magnussonite, manganese arsenite, a fluorite derivative structure. American Mineralogist, 64 (3-4) 390-401
Dunn, Pete J., Ramik, Robert A. (1984) Magnussonite: new chemical data, an occurrence at Sterling Hill, New Jersey, and new data on a related phase from the Brattfors mine, Sweden. American Mineralogist, 69 (7-8) 800-802
Localities for Magnussonite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Sweden | |
| Nysten (2003) +1 other reference |
| Gabrielson (1956) +1 other reference |
| Moore (1978) |
USA | |
| Frondel (1961) +2 other references |
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LĂ„ngban Mine, LĂ„ngban Ore District, Filipstad, VĂ€rmland County, Sweden