Stanfieldite
A valid IMA mineral species
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About Stanfieldite
Formula:
Ca4Mg5(PO4)6
formula likely to be modified (Britvin et al 2020) to: Ca7M2Mg9(PO4)12 (where M denotes Ca, Mg and Fe); see below for details
Colour:
Amber to pale red
Hardness:
4½ - 5
Specific Gravity:
3.15
Crystal System:
Monoclinic
Name:
Named after Stanley Field, Chairman, Board of Trustees, Field Museum of Natural History, USA (born May 13, 1875, Manchester England; died Chicago Oct. 28, 1964)
Type Locality:
Possibly represents more than a single species:
- "~Ca7(CaMg)Mg9(PO4)12 ≡ Ca4Mg5(PO4)6", that is, the "Mindat Formula" (Brahin and lots of other meteorites)
- Ca7Mg2Mg9(PO4)12 for material from Lunar "rusty rock" 66095 (Britvin et al. 2020).
- "~Ca7(CaMg)Mg9(PO4)12 ≡ Ca4Mg5(PO4)6", that is, the "Mindat Formula" (Brahin and lots of other meteorites)
- Ca7Mg2Mg9(PO4)12 for material from Lunar "rusty rock" 66095 (Britvin et al. 2020).
Unique Identifiers
Mindat ID:
3745
Long-form identifier:
mindat:1:1:3745:3
GUID
(UUID V4):
(UUID V4):
192ec3bc-b86d-457c-8ce3-f426faa06f95
Classification of Stanfieldite
Approved
Approval year:
1966
First published:
1967
Type description reference:
8.AC.70
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th ed.:
38.3.5.1
38.3.5.1
38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
3 : (AB)3(XO4)2
38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
3 : (AB)3(XO4)2
19.12.45
19 : Phosphates
12 : Phosphates of Mn
19 : Phosphates
12 : Phosphates of Mn
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Stf | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Stanfieldite
Transparency:
Transparent
Colour:
Amber to pale red
Comment:
pale bluish if weathered;
Hardness:
4½ - 5 on Mohs scale
Density:
3.15(1) g/cm3 (Measured) 3.15 g/cm3 (Calculated)
Optical Data of Stanfieldite
Type:
Biaxial (+)
RI values:
nα = 1.594 - 1.619 nβ = 1.596 - 1.622 nγ = 1.604 - 1.631
2V:
Measured: 50° to 60°, Calculated: 54° to 62°
Max Birefringence:
δ = 0.010 - 0.012
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r < v
Chemical Properties of Stanfieldite
Formula:
Ca4Mg5(PO4)6
formula likely to be modified (Britvin et al 2020) to: Ca7M2Mg9(PO4)12 (where M denotes Ca, Mg and Fe); see below for details
formula likely to be modified (Britvin et al 2020) to: Ca7M2Mg9(PO4)12 (where M denotes Ca, Mg and Fe); see below for details
Elements listed:
Crystallography of Stanfieldite
Crystal System:
Monoclinic
Cell Parameters:
a = 17.16(3) Å, b = 10.00(2) Å, c = 22.88(4) Å
β = 100.52°
β = 100.52°
Ratio:
a:b:c = 1.716 : 1 : 2.288
Unit Cell V:
3,860.21 ų (Calculated from Unit Cell)
Z:
8
Comment:
Point Group: 2/m or m.; Space Group: P2/c or Pc.
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0015640 | Stanfieldite | Dickens B, Brown W E (1971) The crystal structure of Ca7Mg9(Ca,Mg)2(PO4)12 Tschermaks Mineralogische und Petrographische Mitteilungen 16 79-104 | 1971 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
2.817 Å | (10) |
3.747 Å | (8) |
2.505 Å | (8) |
3.845 Å | (6) |
8.31 Å | (5) |
6.01 Å | (5) |
1.870 Å | (4) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 2: Planetesimal differentiation and alteration | 4.566-4.550 |
5 : Primary asteroid phases | 4.566–4.560 |
Stage 10b: Anthropogenic minerals | <10 Ka |
56 : Slag and smelter minerals (see also #51 and #55) | |
57 : Other minerals formed by human processes |
Type Occurrence of Stanfieldite
Place of Conservation of Type Material:
Masses of the Estherville meteorite are at: The Natural History Museum, London, England; Natural History Museum, Paris, France; Natural History Museum, Vienna, Austria; Field Museum of Natural History, Chicago, Illinois; Harvard University, Cambridge, Massachusetts; National Museum of Natural History, Washington, D.C., USA.
Geological Setting of Type Material:
Stony-iron meteorites
Associated Minerals at Type Locality:
Reference:
Fuchs, L.H. (1967) Stanfieldite, a new phosphate mineral from stony iron meteorites. Science: 158: 910-911.
Synonyms of Stanfieldite
Other Language Names for Stanfieldite
Common Associates
Associated Minerals Based on Photo Data:
1 photo of Stanfieldite associated with Chromite | Fe2+Cr3+2O4 |
1 photo of Stanfieldite associated with Hematite | Fe2O3 |
1 photo of Stanfieldite associated with Schreibersite | (Fe,Ni)3P |
1 photo of Stanfieldite associated with Troilite | FeS |
1 photo of Stanfieldite associated with Iron | Fe |
1 photo of Stanfieldite associated with Enstatite | Mg2Si2O6 |
Related Minerals - Strunz-mindat Grouping
8.AC. | Angarfite | NaFe3+5(PO4)4(OH)4 · 4H2O | Orth. 2 2 2 : C2 2 21 |
8.AC. | Wopmayite | Ca6Na3◻Mn(PO4)3(PO3OH)4 | Trig. 3m : R3c |
8.AC.X | Dyrnaesite-(La) | Na8Ce4+(La,REE)2(PO4)6 | Orth. mmm (2/m 2/m 2/m) : Pnma |
8.AC. | Edtollite | K2NaCu5Fe3+O2(AsO4)4 | Tric. 1 : P1 |
8.AC. | Alumoedtollite | K2NaCu5AlO2(AsO4)4 | Tric. 1 : P1 |
8.AC. | Crocobelonite | CaFe3+2O(PO4)2 | Orth. mmm (2/m 2/m 2/m) : Pnma |
8.AC. | Manganobadalovite | NaNaMn(MgFe3+)(AsO4)3 | Mon. 2/m : B2/b |
8.AC. | Beershevaite | CaFe3+3(PO4)3O | Mon. 2/m : P21/m |
8.AC. | Calciohatertite | NaNaCa(CaFe3+)(AsO4)3 | Mon. 2/m : B2/b |
8.AC. | Kabalovite | Fe2+3Fe3+4(PO4)6 | Tric. 1 : P1 |
8.AC. | Nazarchukite | Ca2NiFe3+2(PO4)4 | Orth. mmm (2/m 2/m 2/m) : Pbca |
8.AC. | Changesite–(Y) | (Ca8Y)◻Fe2+(PO4)7 | Trig. 3m : R3c |
8.AC. | Crocobelonite-1M | CaFe3+2O(PO4)2 | Mon. 2/m : P21/m |
8.AC. | Ebnerite | (NH4)Zn(PO4) | Hex. 6 : P63 |
8.AC.02 | Grigorievite | Cu3Fe3+2Al2(VO4)6 | Tric. 1 : P1 |
8.AC.02 | Koksharovite | CaMg2Fe3+4(VO4)6 | Tric. 1 : P1 |
8.AC.02 | Ziminaite | Fe3+ 6 (VO4)6 | Tric. 1 : P1 |
8.AC.05 | Calciojohillerite | NaCaMg3(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Howardevansite | NaCuFe2(VO4)3 | Tric. 1 : P1 |
8.AC.05 | O'Danielite | Na(Zn,Mg)3(AsO4)(AsO3OH)2 | Mon. 2/m : B2/b |
8.AC.05 va | Alluaudite-Na□ | ◻4Na4Mn2+4Fe3+8(PO4)12 | Mon. 2/m : B2/b |
8.AC.05 va | Alluaudite-Ca□ | ◻4Ca4Mn2+4Fe3+8(PO4)12 | Mon. 2/m : B2/b |
8.AC.05 va | Ferroalluaudite-NaNa | Na4Na4Fe2+4Fe3+8(PO4)12 | Mon. 2/m : B2/m |
8.AC.05 | Hagendorfite-NaNa | NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) | Mon. 2/m : B2/b |
8.AC.05 | Erikapohlite | Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O | Mon. 2/m : B2/m |
8.AC.05 | Hatertite | Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Unnamed (Na-Mg Arsenate Hydroxyarsenate) | NaMg3(AsO4)(AsO3OH)2 | Mon. 2/m : B2/b |
8.AC.05 | Unnamed (Na-Zn-H Arsenate Hydrxyarsenate) | Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 | Mon. 2/m : B2/b |
8.AC.05 | Zincobradaczekite | NaZn2Cu2(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Badalovite | Na2Mg2Fe(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Magnesiocanutite | NaMnMg2[AsO4]2[AsO2(OH)2] | Mon. 2/m : B2/b |
8.AC.05 | Magnesiohatertite | (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Khrenovite | Na3Fe3+2(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Paraberzeliite | NaCa2Mg2(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Camanchacaite | NaCaMg2[AsO4][AsO3(OH)]2 | Mon. 2/m : B2/b |
8.AC.07 | Zhanghuifenite | Na3Mn4Mg2Al(PO4)6 | Mon. 2/m |
8.AC.07 | Ferrobobfergusonite | Na2Fe2+5Fe3+Al(PO4)6 | Mon. |
8.AC.10 | Alluaudite | (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Arseniopleite | NaCaMnMn2(AsO4)3 | Mon. 2/m |
8.AC.10 | Caryinite | (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 | Mon. 2/m |
8.AC.10 | Ferroalluaudite | (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Hagendorfite | NaCaMn2+Fe2+2(PO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Johillerite | Na(Mg,Zn)3Cu(AsO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Maghagendorfite | (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 | Mon. 2/m |
8.AC.10 | Nickenichite | Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Varulite | NaCaMn2+Mn2+2(PO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Ferrohagendorfite | NaCaFe2+Fe2+2(PO4)3 | Mon. |
8.AC.10 | Bradaczekite | NaCu4(AsO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Groatite | NaCaMn2(PO4)[PO3(OH)]2 | Mon. 2/m : B2/b |
8.AC.15 | Bobfergusonite | Na2Mn5FeAl(PO4)6 | Mon. 2/m : P2/b |
8.AC.15 | Ferrowyllieite | (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 | Mon. 2/m : P21/b |
8.AC.15 | Qingheiite | NaNaMn2+(MgAl)(PO4)3 | Mon. 2/m : P21/b |
8.AC.15 | Rosemaryite | (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 | Mon. 2/m : P21/b |
8.AC.15 | Wyllieite | (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 | Mon. 2/m |
8.AC.15 | Ferrorosemaryite | ◻NaFe2+Fe3+Al(PO4)3 | Mon. 2/m |
8.AC.15 | Ferroqingheiite | NaNaFe2+(MgAl)(PO4)3 | Mon. 2/m : P21/m |
8.AC.17 | Czochralskiite | Na4Ca3Mg(PO4)4 | Orth. mmm (2/m 2/m 2/m) : Pnma |
8.AC.18 | Manitobaite | Na16Mn2+ 25Al8(PO4)30 | Mon. m : Pb |
8.AC.20 | Marićite | NaFe2+(PO4) | Orth. mmm (2/m 2/m 2/m) : Pmna |
8.AC.25 | Berzeliite | (NaCa2)Mg2(AsO4)3 | Iso. m3m (4/m 3 2/m) : Ia3d |
8.AC.25 | Manganberzeliite | (NaCa2)Mn2+2(AsO4)3 | Iso. m3m (4/m 3 2/m) : Ia3d |
8.AC.25 | Palenzonaite | (NaCa2)Mn2+2(VO4)3 | Iso. m3m (4/m 3 2/m) : Ia3d |
8.AC.25 | Schäferite | (NaCa2)Mg2(VO4)3 | Iso. m3m (4/m 3 2/m) : Ia3d |
8.AC.25 | Hedegaardite | (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) | Trig. 3m : R3c |
8.AC.25 | Matyhite | Ca18(Ca,◻)2Fe2+2(PO4)14 | Trig. 3m : R3c |
8.AC.30 | Brianite | Na2CaMg(PO4)2 | Mon. 2/m : P21/b |
8.AC.35 | Vitusite-(Ce) | Na3(Ce,La,Nd)(PO4)2 | Orth. mm2 : Pca21 |
8.AC.40 | Olgite | (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 | Trig. 3m (3 2/m) : P3m1 |
8.AC.40 | Bario-olgite | (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · | Trig. 3 : P3 |
8.AC.45 | Strontiowhitlockite | Sr9Mg(PO4)6(PO3OH) | Trig. 3m : R3c |
8.AC.45 | Whitlockite | Ca9Mg(PO4)6(PO3OH) | Trig. 3m : R3c |
8.AC.45 | Merrillite | Ca9NaMg(PO4)7 | Trig. 3m : R3m |
8.AC.45 | Tuite | Ca3(PO4)2 | Trig. 3m (3 2/m) : R3m |
8.AC.45 | Ferromerrillite | Ca9NaFe2+(PO4)7 | Trig. 3m : R3c |
8.AC.47 | Iwateite | Na2BaMn(PO4)2 | Trig. 3 : P3 |
8.AC.47 | Yurmarinite | Na7(Fe3+,Mg,Cu)4(AsO4)6 | Trig. 3m (3 2/m) : R3c |
8.AC.47 | Ozerovaite | Na2KAl3(AsO4)4 | Orth. mmm (2/m 2/m 2/m) : Cmca |
8.AC.47 | Anatolyite | Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 | Trig. 3m (3 2/m) : R3c |
8.AC.47 | Pansnerite | K3Na3(Fe3+,Al)6(AsO4)8 | Orth. mmm (2/m 2/m 2/m) |
8.AC.50 | Chladniite | Na3CaMg11(PO4)9 | Trig. 3 : R3 |
8.AC.50 | Fillowite | Na3CaMn2+11(PO4)9 | Trig. 3 : R3 |
8.AC.50 | Johnsomervilleite | Na3CaFe11(PO4)9 | Trig. 3 : R3 |
8.AC.50 | Galileiite | Na3Fe2+Fe2+11(PO4)9 | Trig. 3 : R3 |
8.AC.50 | Xenophyllite | Na4Fe2+7(PO4)6 | Tric. 1 : P1 |
8.AC.50 | Udinaite | NaMg4(VO4)3 | Tet. 4 2m : I4 2d |
8.AC.50 | Arsenudinaite | NaMg4(AsO4)3 | Tet. 4 2m : I4 2d |
8.AC.52 | Lasnierite | (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 | Orth. mmm (2/m 2/m 2/m) : Pbcn |
8.AC.55 | Pharmazincite | KZnAsO4 | Hex. 6 : P63 |
8.AC.57 | Zubkovaite | Ca3Cu3(AsO4)4 | Mon. 2 : B2 |
8.AC.60 | Kosnarite | KZr2(PO4)3 | Trig. 3m (3 2/m) : R3c |
8.AC.65 | Panethite | (Na,Ca)2(Mg,Fe2+)2(PO4)2 | Mon. 2/m : P21/b |
8.AC.75 | Ronneburgite | K2MnV4O12 | Mon. 2/m |
8.AC.80 | Tillmannsite | Ag3Hg[(V,As)O4] | Tet. 4 : I4 |
8.AC.85 | Filatovite | K(Al,Zn)2(As,Si)2O8 | Mon. 2/m |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Stanfieldite
mindat.org URL:
https://www.mindat.org/min-3745.html
Please feel free to link to this page.
Please feel free to link to this page.
External Links:
Mineral Dealers:
References for Stanfieldite
Reference List:
Localities for Stanfieldite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
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Finmarken meteorite, Porsanger, Troms og Finnmark, Norway