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Stanfieldite

A valid IMA mineral species
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About StanfielditeHide

09710070014948856153856.jpg
Stanley Fields 1934
Formula:
Ca4Mg5(PO4)6
formula likely to be modified (Britvin et al 2020) to: Ca7M2Mg9(PO4)12 (where M denotes Ca, Mg and Fe); see below for details
Colour:
Amber to pale red
Hardness:
4½ - 5
Specific Gravity:
3.15
Crystal System:
Monoclinic
Name:
Named after Stanley Field, Chairman, Board of Trustees, Field Museum of Natural History, USA (born May 13, 1875, Manchester England; died Chicago Oct. 28, 1964)
Possibly represents more than a single species:

- "~Ca7(CaMg)Mg9(PO4)12 ≡ Ca4Mg5(PO4)6", that is, the "Mindat Formula" (Brahin and lots of other meteorites)
- Ca7Mg2Mg9(PO4)12 for material from Lunar "rusty rock" 66095 (Britvin et al. 2020).


Unique IdentifiersHide

Mindat ID:
3745
Long-form identifier:
mindat:1:1:3745:3
GUID
(UUID V4):
192ec3bc-b86d-457c-8ce3-f426faa06f95

Classification of StanfielditeHide

Approved
Approval year:
1966
First published:
1967
8.AC.70

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th ed.:
38.3.5.1
38.3.5.1

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
3 : (AB)3(XO4)2
19.12.45

19 : Phosphates
12 : Phosphates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
StfIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of StanfielditeHide

Transparency:
Transparent
Colour:
Amber to pale red
Comment:
pale bluish if weathered;
Hardness:
4½ - 5 on Mohs scale
Density:
3.15(1) g/cm3 (Measured)    3.15 g/cm3 (Calculated)

Optical Data of StanfielditeHide

Type:
Biaxial (+)
RI values:
nα = 1.594 - 1.619 nβ = 1.596 - 1.622 nγ = 1.604 - 1.631
2V:
Measured: 50° to 60°, Calculated: 54° to 62°
Max Birefringence:
δ = 0.010 - 0.012
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r < v

Chemical Properties of StanfielditeHide

Formula:
Ca4Mg5(PO4)6

formula likely to be modified (Britvin et al 2020) to: Ca7M2Mg9(PO4)12 (where M denotes Ca, Mg and Fe); see below for details

Crystallography of StanfielditeHide

Crystal System:
Monoclinic
Cell Parameters:
a = 17.16(3) Å, b = 10.00(2) Å, c = 22.88(4) Å
β = 100.52°
Ratio:
a:b:c = 1.716 : 1 : 2.288
Unit Cell V:
3,860.21 ų (Calculated from Unit Cell)
Z:
8
Comment:
Point Group: 2/m or m.; Space Group: P2/c or Pc.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0015640StanfielditeDickens B, Brown W E (1971) The crystal structure of Ca7Mg9(Ca,Mg)2(PO4)12 Tschermaks Mineralogische und Petrographische Mitteilungen 16 79-1041971synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.817 Å(10)
3.747 Å(8)
2.505 Å(8)
3.845 Å(6)
8.31 Å(5)
6.01 Å(5)
1.870 Å(4)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 2: Planetesimal differentiation and alteration4.566-4.550
5 : Primary asteroid phases4.566–4.560
Stage 10b: Anthropogenic minerals<10 Ka
56 : Slag and smelter minerals (see also #51 and #55)
57 : Other minerals formed by human processes

Type Occurrence of StanfielditeHide

Place of Conservation of Type Material:
Masses of the Estherville meteorite are at: The Natural History Museum, London, England; Natural History Museum, Paris, France; Natural History Museum, Vienna, Austria; Field Museum of Natural History, Chicago, Illinois; Harvard University, Cambridge, Massachusetts; National Museum of Natural History, Washington, D.C., USA.
Geological Setting of Type Material:
Stony-iron meteorites
Associated Minerals at Type Locality:
Reference:
Fuchs, L.H. (1967) Stanfieldite, a new phosphate mineral from stony iron meteorites. Science: 158: 910-911.

Synonyms of StanfielditeHide

Other Language Names for StanfielditeHide

Simplified Chinese:磷镁钙石
Spanish:Stanfieldita

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Stanfieldite associated with ChromiteFe2+Cr3+2O4
1 photo of Stanfieldite associated with HematiteFe2O3
1 photo of Stanfieldite associated with Schreibersite(Fe,Ni)3P
1 photo of Stanfieldite associated with TroiliteFeS
1 photo of Stanfieldite associated with IronFe
1 photo of Stanfieldite associated with EnstatiteMg2Si2O6

Related Minerals - Strunz-mindat GroupingHide

8.AC.AngarfiteNaFe3+5(PO4)4(OH)4 · 4H2O Orth. 2 2 2 : C2 2 21
8.AC.WopmayiteCa6Na3◻Mn(PO4)3(PO3OH)4 Trig. 3m : R3c
8.AC.XDyrnaesite-(La)Na8Ce4+(La,REE)2(PO4)6Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.EdtolliteK2NaCu5Fe3+O2(AsO4)4Tric. 1 : P1
8.AC.AlumoedtolliteK2NaCu5AlO2(AsO4)4Tric. 1 : P1
8.AC.CrocobeloniteCaFe3+2O(PO4)2Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.ManganobadaloviteNaNaMn(MgFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.BeershevaiteCaFe3+3(PO4)3OMon. 2/m : P21/m
8.AC.CalciohatertiteNaNaCa(CaFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.KabaloviteFe2+3Fe3+4(PO4)6Tric. 1 : P1
8.AC.Nazarchukite Ca2NiFe3+2(PO4)4Orth. mmm (2/m 2/m 2/m) : Pbca
8.AC.Changesite–(Y)(Ca8Y)◻Fe2+(PO4)7Trig. 3m : R3c
8.AC.Crocobelonite-1MCaFe3+2O(PO4)2Mon. 2/m : P21/m
8.AC.Ebnerite(NH4)Zn(PO4)Hex. 6 : P63
8.AC.02GrigorieviteCu3Fe3+2Al2(VO4)6Tric. 1 : P1
8.AC.02KoksharoviteCaMg2Fe3+4(VO4)6Tric. 1 : P1
8.AC.02ZiminaiteFe3+ 6 (VO4)6Tric. 1 : P1
8.AC.05CalciojohilleriteNaCaMg3(AsO4)3Mon. 2/m : B2/b
8.AC.05HowardevansiteNaCuFe2(VO4)3Tric. 1 : P1
8.AC.05O'DanieliteNa(Zn,Mg)3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05 vaAlluaudite-Na□4Na4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
8.AC.05 vaAlluaudite-Ca□4Ca4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
8.AC.05 vaFerroalluaudite-NaNaNa4Na4Fe2+4Fe3+8(PO4)12Mon. 2/m : B2/m
8.AC.05Hagendorfite-NaNaNaNaFe2+(Mn2+,Mn3+)(PO4)3 (?)Mon. 2/m : B2/b
8.AC.05ErikapohliteCu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O Mon. 2/m : B2/m
8.AC.05HatertiteNa2(Ca,Na)(Fe3+,Cu)2(AsO4)3Mon. 2/m : B2/b
8.AC.05Unnamed (Na-Mg Arsenate Hydroxyarsenate)NaMg3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05Unnamed (Na-Zn-H Arsenate Hydrxyarsenate)Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05ZincobradaczekiteNaZn2Cu2(AsO4)3Mon. 2/m : B2/b
8.AC.05BadaloviteNa2Mg2Fe(AsO4)3Mon. 2/m : B2/b
8.AC.05MagnesiocanutiteNaMnMg2[AsO4]2[AsO2(OH)2]Mon. 2/m : B2/b
8.AC.05Magnesiohatertite(Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3Mon. 2/m : B2/b
8.AC.05KhrenoviteNa3Fe3+2(AsO4)3Mon. 2/m : B2/b
8.AC.05ParaberzeliiteNaCa2Mg2(AsO4)3Mon. 2/m : B2/b
8.AC.05CamanchacaiteNaCaMg2[AsO4][AsO3(OH)]2Mon. 2/m : B2/b
8.AC.07ZhanghuifeniteNa3Mn4Mg2Al(PO4)6Mon. 2/m
8.AC.07FerrobobfergusoniteNa2Fe2+5Fe3+Al(PO4)6Mon.
8.AC.10Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon. 2/m : B2/b
8.AC.10ArseniopleiteNaCaMnMn2(AsO4)3Mon. 2/m
8.AC.10Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m
8.AC.10Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3Mon. 2/m : B2/b
8.AC.10HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
8.AC.10JohilleriteNa(Mg,Zn)3Cu(AsO4)3Mon. 2/m : B2/b
8.AC.10Maghagendorfite(Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3Mon. 2/m
8.AC.10NickenichiteNa0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m : B2/b
8.AC.10VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
8.AC.10FerrohagendorfiteNaCaFe2+Fe2+2(PO4)3Mon.
8.AC.10BradaczekiteNaCu4(AsO4)3Mon. 2/m : B2/b
8.AC.10GroatiteNaCaMn2(PO4)[PO3(OH)]2Mon. 2/m : B2/b
8.AC.15BobfergusoniteNa2Mn5FeAl(PO4)6Mon. 2/m : P2/b
8.AC.15Ferrowyllieite(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15QingheiiteNaNaMn2+(MgAl)(PO4)3Mon. 2/m : P21/b
8.AC.15Rosemaryite(Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15Wyllieite(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3Mon. 2/m
8.AC.15Ferrorosemaryite◻NaFe2+Fe3+Al(PO4)3Mon. 2/m
8.AC.15FerroqingheiiteNaNaFe2+(MgAl)(PO4)3Mon. 2/m : P21/m
8.AC.17CzochralskiiteNa4Ca3Mg(PO4)4Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.18ManitobaiteNa16Mn2+ 25Al8(PO4)30Mon. m : Pb
8.AC.20MarićiteNaFe2+(PO4)Orth. mmm (2/m 2/m 2/m) : Pmna
8.AC.25Berzeliite(NaCa2)Mg2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Manganberzeliite(NaCa2)Mn2+2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Palenzonaite(NaCa2)Mn2+2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Schäferite(NaCa2)Mg2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Hedegaardite(Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.25MatyhiteCa18(Ca,◻)2Fe2+2(PO4)14Trig. 3m : R3c
8.AC.30BrianiteNa2CaMg(PO4)2Mon. 2/m : P21/b
8.AC.35Vitusite-(Ce)Na3(Ce,La,Nd)(PO4)2Orth. mm2 : Pca21
8.AC.40Olgite(Sr,Ba)(Na,Sr,REE)2Na(PO4)2Trig. 3m (3 2/m) : P3m1
8.AC.40Bario-olgite(Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · Trig. 3 : P3
8.AC.45StrontiowhitlockiteSr9Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.45WhitlockiteCa9Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.45MerrilliteCa9NaMg(PO4)7Trig. 3m : R3m
8.AC.45TuiteCa3(PO4)2Trig. 3m (3 2/m) : R3m
8.AC.45FerromerrilliteCa9NaFe2+(PO4)7Trig. 3m : R3c
8.AC.47IwateiteNa2BaMn(PO4)2Trig. 3 : P3
8.AC.47YurmariniteNa7(Fe3+,Mg,Cu)4(AsO4)6Trig. 3m (3 2/m) : R3c
8.AC.47OzerovaiteNa2KAl3(AsO4)4Orth. mmm (2/m 2/m 2/m) : Cmca
8.AC.47AnatolyiteNa6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6Trig. 3m (3 2/m) : R3c
8.AC.47PansneriteK3Na3(Fe3+,Al)6(AsO4)8Orth. mmm (2/m 2/m 2/m)
8.AC.50ChladniiteNa3CaMg11(PO4)9Trig. 3 : R3
8.AC.50FillowiteNa3CaMn2+11(PO4)9Trig. 3 : R3
8.AC.50JohnsomervilleiteNa3CaFe11(PO4)9Trig. 3 : R3
8.AC.50GalileiiteNa3Fe2+Fe2+11(PO4)9Trig. 3 : R3
8.AC.50XenophylliteNa4Fe2+7(PO4)6Tric. 1 : P1
8.AC.50UdinaiteNaMg4(VO4)3Tet. 4 2m : I4 2d
8.AC.50ArsenudinaiteNaMg4(AsO4)3Tet. 4 2m : I4 2d
8.AC.52Lasnierite(Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3Orth. mmm (2/m 2/m 2/m) : Pbcn
8.AC.55PharmazinciteKZnAsO4Hex. 6 : P63
8.AC.57ZubkovaiteCa3Cu3(AsO4)4Mon. 2 : B2
8.AC.60KosnariteKZr2(PO4)3Trig. 3m (3 2/m) : R3c
8.AC.65Panethite(Na,Ca)2(Mg,Fe2+)2(PO4)2Mon. 2/m : P21/b
8.AC.75RonneburgiteK2MnV4O12Mon. 2/m
8.AC.80TillmannsiteAg3Hg[(V,As)O4]Tet. 4 : I4
8.AC.85FilatoviteK(Al,Zn)2(As,Si)2O8Mon. 2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for StanfielditeHide

References for StanfielditeHide

Reference List:

Localities for StanfielditeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Tyrol
    • Innsbruck
      • Igls
Belarus
 
  • Gomel Region
Canada
 
  • Saskatchewan
    • Springwater
Chile
 
  • Antofagasta
    • Antofagasta Province
      • Augusta Victoria
        • Imilac
China
 
  • Inner Mongolia
    • Xilingol League (Xilinguole Prefecture)
      • East Ujimqin Banner (Dongwuzhumuqin Co.; Dongwu Qi)
Germany
 
  • Bavaria
    • Upper Bavaria
      • Traunstein District
Israel
 
  • Southern District (HaDarom District)
    • Tamar Regional Council
      • Hatrurim Basin
Japan
 
  • Kochi Prefecture
    • Kami City
Mexico
 
  • Baja California Sur
    • Mulegé Municipality
      • Santa Rosalía
Norway
 
  • Troms og Finnmark
    • Porsanger
Russia
 
  • Chukotka Autonomous Okrug
    • Chaunskii District (Chaun)
  • Magadan Oblast
    • Severo-Evensky District
USA
 
  • Arkansas
    • Jackson County
  • Iowa
    • Emmet County
  • Kentucky
    • Carroll County
    • Christian County
  • Wyoming
    • Laramie County
 
Mineral and/or Locality  
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