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Fluorchegemite

A valid IMA mineral species
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Formula:
Ca7(SiO4)3F2
Colour:
Colorless
Hardness:
5½ - 6
Specific Gravity:
2.91 (Calculated)
Crystal System:
Orthorhombic
Name:
For the mineral chegemite and its fluorine content.
F-dominant analogue of chegemite


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Unique IdentifiersHide

Mindat ID:
42739
Long-form identifier:
mindat:1:1:42739:1
GUID
(UUID V4):
c3002da8-f83a-491e-b263-411b76c1cd69

IMA Classification of FluorchegemiteHide

Classification of FluorchegemiteHide

9.AF.50

9 : SILICATES (Germanates)
A : Nesosilicates
F : Nesosilicates with additional anions; cations in [4], [5] and/or only [6] coordination

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
FcgmIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FluorchegemiteHide

Colour:
Colorless
Streak:
White
Hardness:
5½ - 6 on Mohs scale
Hardness:
VHN50=480 - 511 kg/mm2 - Vickers
Cleavage:
Imperfect/Fair
Imperfect on (010).
Fracture:
Irregular/Uneven
Density:
2.91 g/cm3 (Calculated)
Comment:
Density could not be measured due to numerous inclusions.

Optical Data of FluorchegemiteHide

Type:
Biaxial (-)
RI values:
nα = 1.610(2) nβ = 1.615(2) nγ = 1.619(2)
2V:
Measured: 80° (8), Calculated: 84°
Max Birefringence:
δ = 0.009
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r > v, weak
Optical Extinction:
X = a; Y = b.
Pleochroism:
Non-pleochroic

Chemistry of FluorchegemiteHide

Mindat Formula:
Ca7(SiO4)3F2

Crystallography of FluorchegemiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Cell Parameters:
a = 5.0620(1) Å, b = 11.3917(2) Å, c = 23.5180(3) Å
Ratio:
a:b:c = 0.444 : 1 : 2.064
Unit Cell V:
1356.16 ų
Z:
4
Morphology:
Irregular grains up to 0.2 mm.
Twinning:
Twins have been noted.
Comment:
space group Pbnm

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.636 Å(52)
3.013 Å(57)
2.991 Å(56)
2.832 Å(51)
2.718 Å(63)
2.699 Å(46)
2.531 Å(100)
1.905 Å(95)
Comments:
Calculated data based on material from Xenolith no. 1, Lakargi Mountain, Upper Chegem volcanic caldera, Russia. Data from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
9 : Lava/xenolith minerals (hornfels, sanidinite facies)

Type Occurrence of FluorchegemiteHide

General Appearance of Type Material:
Irregular grains up to 0.2 mm.
Place of Conservation of Type Material:
Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia, catalogue number 4163/1.
Geological Setting of Type Material:
An edgrewite-bearing zone of endoskarn at the contact of a large altered calciferous xenolith within ignimbrites of the Upper Chegem Caldera, Russia.
Associated Minerals at Type Locality:
Reference:
Galuskina, I.O., Krüger, B., Galuskin, E.V. ,Armbruster, T., Gazeev, V.M., Włodyka, R., Dulski, M. & Dzierżanowski, P. (2015) Fluorchegemite, Ca7(SiO4)3F2, a new mineral from the edgrewitebearing endoskarn zone of an altered xenolith in ignimbrites from Upper Chegem Caldera, Northern Caucasus, Kabardina-balkaria, Russia; Occurrence, crystal structure, and new data on the mineral assemblages. The Canadian Mineralogist, 53, 325-344.

Synonyms of FluorchegemiteHide

Relationship of Fluorchegemite to other SpeciesHide

Other Members of this group:
ChegemiteCa7(SiO4)3(OH)2Orth. mmm (2/m 2/m 2/m)
EdgrewiteCa9(SiO4)4F2 Mon. 2/m : P21/b
HydroxyledgrewiteCa9(SiO4)4(OH)2 Mon. 2/m : P21/b
KumtyubeiteCa5(SiO4)2F2Mon. 2/m : P21/b
ReinhardbraunsiteCa5(SiO4)2(OH,F)2Mon. 2/m : P21/b
Forms a series with:

Related Minerals - Strunz-mindat GroupingHide

9.AF.ChegemiteCa7(SiO4)3(OH)2Orth. mmm (2/m 2/m 2/m)
9.AF.BarwooditeMn2+6Nb5+(SiO4)2O3(OH)3Trig. 3 : P3
9.AF.Jingwenite-(Y)YAlV4+(SiO4)O2(OH)2Mon. 2/m
9.AF.05SillimaniteAl2(SiO4)OOrth. mmm (2/m 2/m 2/m)
9.AF.05XenoliteAl10Si8O31
9.AF.10AndalusiteAl2(SiO4)OOrth. mmm (2/m 2/m 2/m) : Pnnm
9.AF.10KanonaiteMn3+Al(SiO4)OOrth. mmm (2/m 2/m 2/m) : Pnnm
9.AF.15KyaniteAl2(SiO4)OTric. 1 : P1
9.AF.20MulliteAl4+2xSi2-2xO10-xOrth. mmm (2/m 2/m 2/m) : Pbam
9.AF.20KrieseliteAl2(GeO4)F2Orth. mmm (2/m 2/m 2/m) : Pnma
9.AF.23BoromulliteAl9BSi2O19Orth. mm2 : Cmc21
9.AF.25YoderiteMg(Al,Fe3+)3(SiO4)2O(OH)Mon. 2/m : P21/m
9.AF.30MagnesiostauroliteMg(Mg,Li)3(Al,Mg)18Si8O44(OH)4Mon. 2/m : B2/m
9.AF.30StauroliteFe2+2Al9Si4O23(OH)Mon. 2/m : B2/m
9.AF.30ZincostauroliteZn2Al9Si4O23(OH)Mon. 2/m : B2/m
9.AF.35TopazAl2(SiO4)(F,OH)2Orth. mmm (2/m 2/m 2/m)
9.AF.40NorbergiteMg3(SiO4)F2Orth. mmm (2/m 2/m 2/m)
9.AF.45AlleghanyiteMn2+5(SiO4)2(OH)2Mon. 2/m : P21/b
9.AF.45ChondroditeMg5(SiO4)2F2Mon. 2/m : P21/b
9.AF.45ReinhardbraunsiteCa5(SiO4)2(OH,F)2Mon. 2/m : P21/b
9.AF.45KumtyubeiteCa5(SiO4)2F2Mon. 2/m : P21/b
9.AF.45HydroxylchondroditeMg5(SiO4)2(OH)2Mon. 2/m : P21/b
9.AF.50HumiteMg7(SiO4)3F2Orth. mmm (2/m 2/m 2/m) : Pnma
9.AF.50Manganhumite(Mn2+,Mg)7(SiO4)3(OH)2Orth. mmm (2/m 2/m 2/m)
9.AF.50Unnamed (Ca-analogue of Humite)Ca7(SiO4)4F2Orth. mmm (2/m 2/m 2/m)
9.AF.50Unnamed (OH-analogue of humite)Mg7(SiO4)3(OH)2Orth.
9.AF.55ClinohumiteMg9(SiO4)4F2Mon. 2/m : P21/b
9.AF.55SonoliteMn2+9(SiO4)4(OH)2Mon. 2/m : P21/b
9.AF.55HydroxylclinohumiteMg9(SiO4)4(OH)2Mon. 2/m : P21/b
9.AF.60LeucophoeniciteMn2+7(SiO4)3(OH)2Mon. 2/m : P21/b
9.AF.65RibbeiteMn2+5(SiO4)2(OH)2Orth. mmm (2/m 2/m 2/m)
9.AF.70JerrygibbsiteMn2+9(SiO4)4(OH)2Orth. mmm (2/m 2/m 2/m) : Pbcn
9.AF.75FranciscaniteMn2+6(V5+,◻)2(SiO4)2(O,OH)6Trig. 3 : P3
9.AF.75ÖrebroiteMn2+3(Sb5+,Fe3+)(SiO4)(O,OH)3Trig. 3 : P3
9.AF.75WeliniteMn2+6(W6+,Mg)2(SiO4)2(O,OH)6Trig. 3 : P3
9.AF.75ScorticoiteMn6(Sb,◻)Σ2(SiO4)2O3(OH)3Trig. 3 : P3
9.AF.80EllenbergeriteMg6(Mg,Ti,Zr,◻)2(Al,Mg)6Si8O28(OH)10Hex. 6 : P63
9.AF.85Chloritoid(Fe2+,Mg,Mn2+)Al2(SiO4)O(OH)2Mon. 2/m : B2/b
9.AF.85MagnesiochloritoidMgAl2(SiO4)O(OH)2Mon. 2/m : B2/b
9.AF.85Ottrélite(Mn2+,Fe2+,Mg)Al2(SiO4)O(OH)2Mon.
9.AF.90PoldervaartiteCaCa[SiO3(OH)](OH)Orth. mmm (2/m 2/m 2/m) : Pbca
9.AF.90OlmiiteCaMn2+[SiO3(OH)](OH)Orth. mmm (2/m 2/m 2/m) : Pbca
9.AF.95Pilawite-(Y)Ca2Y2Al4(SiO4)4O2(OH)2Mon. 2/m : P21/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FluorchegemiteHide

References for FluorchegemiteHide

Localities for FluorchegemiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Georgia
 
  • South Ossetia
    • Greater Caucasus Mountain Range
      • Kel’ volcanic area
        • Shadil-Khokh volcano
Russia
 
  • Kabardino-Balkaria
    • Baksan Valley
        • Lakargi Mountain
 
Mineral and/or Locality  
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