Titanomaghemite
A valid IMA mineral species
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About Titanomaghemite
Formula:
(Ti4+0.5◻0.5)Fe3+2O4
Crystal System:
Isometric
Member of:
Name:
In allusion to its titanium content and relationship to maghemite.
May form by natural oxidation of original titanomagneite.
Occurs as inclusions in hematite in sea-floor basalt (Mid-Atlantic Ridge).
Also as grains in a doleritic intrusion in an area of Precambrian gneiss in Minas Gerais, Brazil; the grains host exsolution lamellae of ilmenite parallel to {111} (Allan et al., 1989).
Occurs as inclusions in hematite in sea-floor basalt (Mid-Atlantic Ridge).
Also as grains in a doleritic intrusion in an area of Precambrian gneiss in Minas Gerais, Brazil; the grains host exsolution lamellae of ilmenite parallel to {111} (Allan et al., 1989).
Unique Identifiers
Mindat ID:
29152
Long-form identifier:
mindat:1:1:29152:9
GUID
(UUID V4):
(UUID V4):
0154ff1d-e9ec-4184-a2fc-0770e6b4fe44
IMA Classification of Titanomaghemite
Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
(Ti0.5◻0.5)Fe3+2O4
Approval history:
Grandfathered (first described prior to 1959).
Marked as a questionable mineral in IMA list of Minerals as Fe(Fe,Ti)2O4.
2018: Redefined by IMA as (Ti4+0.5◻0.5)Fe2O4 (Bosi et al., 2019).
Marked as a questionable mineral in IMA list of Minerals as Fe(Fe,Ti)2O4.
2018: Redefined by IMA as (Ti4+0.5◻0.5)Fe2O4 (Bosi et al., 2019).
Classification of Titanomaghemite
4.BB.15
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
B : Metal: Oxygen = 3:4 and similar
B : With only medium-sized cations
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
B : Metal: Oxygen = 3:4 and similar
B : With only medium-sized cations
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Tmgh | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Pronunciation of Titanomaghemite
Pronunciation:
Play | Recorded by | Country |
---|---|---|
Jolyon Ralph | United Kingdom |
Chemistry of Titanomaghemite
Mindat Formula:
(Ti4+0.5◻0.5)Fe3+2O4
Elements listed:
Crystallography of Titanomaghemite
Crystal System:
Isometric
Class (H-M):
4 3 2 - Gyroidal
Space Group:
P43 3 2
Cell Parameters:
a = 8.348(3) Å
Unit Cell V:
581.76 ų (Calculated from Unit Cell)
Z:
8
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0001136 | Titanomaghemite | Collyer S, Grimes N W, Vaughan D J, Longworth G (1988) Studies of the crystal structure and crystal chemistry of titanomaghemite American Mineralogist 73 153-160 | 1988 | Pretoria, South Africa | 0 | 293 |
CIF Raw Data - click here to close
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47h : [Near-surface oxidized, dehydrated minerals] |
Type Occurrence of Titanomaghemite
Place of Conservation of Type Material:
Natural History Museum, London, UK, specimen BM1929,1687, is considered as the neotype (Bosi et al. 2019)
Other Language Names for Titanomaghemite
Russian:Титаномаггемит
Relationship of Titanomaghemite to other Species
Member of:
Other Members of this group:
Chromite | Fe2+Cr3+2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Cochromite | CoCr2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Coulsonite | Fe2+V3+2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Cuprospinel | Cu2+Fe3+2O4 | Iso. m3m (4/m 3 2/m) |
Dellagiustaite | V2+Al2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Deltalumite | (Al0.67◻0.33)Al2O4 | Tet. 4 2m : P4m2 |
Franklinite | Zn2+Fe3+2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Gahnite | ZnAl2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Galaxite | Mn2+Al2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Guite | Co2+Co3+2O4 | Iso. |
Hausmannite | Mn2+Mn3+2O4 | Tet. 4/mmm (4/m 2/m 2/m) : I41/amd |
Hercynite | Fe2+Al2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Hetaerolite | ZnMn2O4 | Tet. 4/mmm (4/m 2/m 2/m) : I41/amd |
Jacobsite | Mn2+Fe3+2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Jacobsite-Q | Mn2+(Fe3+,Mn3+)2O4 | Tet. 4/mmm (4/m 2/m 2/m) : I41/amd |
Maghemite | (Fe3+0.67◻0.33)Fe3+2O4 | Iso. 4 3 2 : P41 3 2 |
Magnesiochromite | MgCr2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Magnesiocoulsonite | MgV2O4 | Iso. m3m (4/m 3 2/m) |
Magnesioferrite | MgFe3+2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Magnetite | Fe2+Fe3+2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Manganochromite | Mn2+Cr2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Nichromite | (Ni,Co,Fe)(Cr,Fe,Al)2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Spinel | MgAl2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Thermaerogenite | CuAl2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Trevorite | Ni2+Fe3+2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
UM1994-06-O:AlCo | CoAl2O4 | |
Vuorelainenite | Mn2+V3+2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Zincochromite | ZnCr2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Common Associates
Associated Minerals Based on Photo Data:
1 photo of Titanomaghemite associated with Fluorapatite | Ca5(PO4)3F |
Related Minerals - Strunz-mindat Grouping
4.BB. | Elgoresyite | (Mg5Si2)O9 |
4.BB. | Chenmingite | FeCr2O4 |
4.BB. | Dellagiustaite | V2+Al2O4 |
4.BB. | Thermaerogenite | CuAl2O4 |
4.BB. | Chukochenite | LiAl5O8 |
4.BB. | Garpenbergite | Mn6◻AsSbO10(OH)2 |
4.BB. | Magnéliite | Ti3+2Ti4+2O7 |
4.BB. | Jianmuite | ZrTi4+Ti3+5Al3O16 |
4.BB.05 | Chromite | Fe2+Cr3+2O4 |
4.BB.05 | Cochromite | CoCr2O4 |
4.BB.05 | Coulsonite | Fe2+V3+2O4 |
4.BB.05 | Cuprospinel | Cu2+Fe3+2O4 |
4.BB.05 | Filipstadite | (Fe3+0.5Sb5+0.5)Mn2O4 |
4.BB.05 | Franklinite | Zn2+Fe3+2O4 |
4.BB.05 | Gahnite | ZnAl2O4 |
4.BB.05 | Galaxite | Mn2+Al2O4 |
4.BB.05 | Hercynite | Fe2+Al2O4 |
4.BB.05 | Jacobsite | Mn2+Fe3+2O4 |
4.BB.05 | Manganochromite | Mn2+Cr2O4 |
4.BB.05 | Magnesiocoulsonite | MgV2O4 |
4.BB.05 | Magnesiochromite | MgCr2O4 |
4.BB.05 | Magnesioferrite | MgFe3+2O4 |
4.BB.05 | Magnetite | Fe2+Fe3+2O4 |
4.BB.05 | Nichromite | (Ni,Co,Fe)(Cr,Fe,Al)2O4 |
4.BB.05 | Qandilite | (Mg,Fe3+)2(Ti,Fe3+,Al)O4 |
4.BB.05 | Spinel | MgAl2O4 |
4.BB.05 | Trevorite | Ni2+Fe3+2O4 |
4.BB.05 | Ulvöspinel | TiFe2+2O4 |
4.BB.05 | Vuorelainenite | Mn2+V3+2O4 |
4.BB.05 | Zincochromite | ZnCr2O4 |
4.BB.05 | Harmunite | CaFe2O4 |
4.BB.05 | Wernerkrauseite | Ca(Fe3+,Mn3+)2Mn4+O6 |
4.BB.05 | Deltalumite | (Al0.67◻0.33)Al2O4 |
4.BB.05 | Guite | Co2+Co3+2O4 |
4.BB.10 | Hausmannite | Mn2+Mn3+2O4 |
4.BB.10 | Hetaerolite | ZnMn2O4 |
4.BB.10 | Manganostibite | (Mn,Fe)7SbAsO12 |
4.BB.15 | Maghemite | (Fe3+0.67◻0.33)Fe3+2O4 |
4.BB.20 | Tegengrenite | (Mn3+0.5Sb5+0.5)Mg2O4 |
4.BB.25 | Xieite | Fe2+Cr2O4 |
4.BB.30 | Carmeltazite | ZrAl2Ti4O11 |
4.BB.35 | Feiite | Fe2+2(Fe2+Ti4+)O5 |
4.BB.40 | Maohokite | MgFe2O4 |
4.BB.45 | Tschaunerite | (Fe2+)(Fe2+Ti4+)O4 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Titanomaghemite
mindat.org URL:
https://www.mindat.org/min-29152.html
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References for Titanomaghemite
Localities for Titanomaghemite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Atlantic Ocean | |
Bernard et al. (2004) | |
Brazil | |
| Allan et al. (1989) |
Germany | |
| Collection of Volker Betz |
India | |
| Canadian Mineralogist (1965) |
Poland | |
| Harańczyk C. (Polish Carpathians) |
Sierra Leone | |
| Haggerty et al. (1990) |
South Africa (TL) | |
| American Mineralogist (1988) +1 other reference |
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Michelsberg Quarry, Katzenbuckel, Eberbach, Rhein-Neckar-Kreis, Karlsruhe Region, Baden-Württemberg, Germany