Filipstadite
A valid IMA mineral species
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About Filipstadite
Formula:
(Fe3+0.5Sb5+0.5)Mn2O4
Colour:
Black
Lustre:
Metallic
Hardness:
6 - 6½
Specific Gravity:
4.9 (Calculated)
Crystal System:
Isometric
Member of:
Name:
For the town of Filipstad, Sweden, which is near the LĂ„ngban mine.
The Fe3+ analogue of tegengrenite.
Chemically somewhat similar to manganoschafarzikite, and melanostibite, garpenbergite.
Crystal structure details:
- ions occupy â of the octahedral and Âœ of the tetrahedral holes of the spinel-type ccp oxygen lattice
- tetrahedral sites are split into 5 subsites, as a result of cation ordering
- octahedral sites are split into 6 subsites, as a result of cation ordering
- unit cell edge is tripled due to cation ordering
- M sites, octahedral, host Sb, part of Mn and Fe, and most of Mg
- T sites host the rest of Mn, Fe, and trace Mg, Zn, and Si
Chemically somewhat similar to manganoschafarzikite, and melanostibite, garpenbergite.
Crystal structure details:
- ions occupy â of the octahedral and Âœ of the tetrahedral holes of the spinel-type ccp oxygen lattice
- tetrahedral sites are split into 5 subsites, as a result of cation ordering
- octahedral sites are split into 6 subsites, as a result of cation ordering
- unit cell edge is tripled due to cation ordering
- M sites, octahedral, host Sb, part of Mn and Fe, and most of Mg
- T sites host the rest of Mn, Fe, and trace Mg, Zn, and Si
Unique Identifiers
Mindat ID:
1548
Long-form identifier:
mindat:1:1:1548:2
GUID
(UUID V4):
(UUID V4):
4d98b266-9da2-44b4-afa7-3cf65b436176
IMA Classification of Filipstadite
Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
(Fe3+0.5Sb5+0.5)Mn2+2O4
Approval history:
Redefined by IMA as (Fe3+0.5Sb5+0.5)Mn2O4 (Bosi et al., 2019).
Classification of Filipstadite
4.BB.05
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
B : Metal: Oxygen = 3:4 and similar
B : With only medium-sized cations
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
B : Metal: Oxygen = 3:4 and similar
B : With only medium-sized cations
7.2.13.1
7 : MULTIPLE OXIDES
2 : AB2X4
7 : MULTIPLE OXIDES
2 : AB2X4
7.19.6
7 : Oxides and Hydroxides
19 : Oxides of Mn and Fe
7 : Oxides and Hydroxides
19 : Oxides of Mn and Fe
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Fps | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Filipstadite
Metallic
Transparency:
Opaque
Colour:
Black
Streak:
Brown
Hardness:
6 - 6½ on Mohs scale
Hardness:
VHN100=792 - 882 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Conchoidal
Density:
4.9 g/cm3 (Calculated)
Comment:
Could not be measured ( Type description)
Optical Data of Filipstadite
Type:
Biaxial
Anisotropism:
Weak; in shades of dark brownish gray
Dispersion:
r > v strong
Colour in reflected light:
gray
Internal Reflections:
amber-orange, brown, or red
Chemistry of Filipstadite
Mindat Formula:
(Fe3+0.5Sb5+0.5)Mn2O4
Elements listed:
Crystallography of Filipstadite
Crystal System:
Isometric
Cell Parameters:
a = 25.9300 Å, b = 25.9300 Å, c = 25.9300 Å
Ratio:
a:b:c = 1 : 1 : 1
Unit Cell V:
17,434.42 Ă
Âł (Calculated from Unit Cell)
Z:
216
Morphology:
Euhedral to subhedral equant crystals up to 200 micron
Twinning:
Poorly developed sector twinning evident in reflected light
Comment:
Orthorhombic, pseudocubic. Point Group: n.d.; Space Group: n.d.
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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Big Balls | Small Balls | Just Balls | Spacefill
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Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
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View
CIF File Best | x | y | z | a | b | c
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Rotation
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0001146 | Filipstadite | Dunn P J, Peacor D R, Criddle A J, Stanley C J (1988) Filipstadite, a new Mn-Fe3+-Sb derivative of spinel, from Lanban, Sweden American Mineralogist 73 413-419 | 1988 | Langban, Varmland, Sweden | 0 | 293 | |
0019779 | Filipstadite | Bonazzi P, Chelazzi L, Bindi L (2013) Superstructure, crystal chemistry, and cation distribution in filipstadite, a Sb5+-bearing, spinel-related mineral American Mineralogist 98 361-366 | 2013 | Langban, Filipstad district, Varmland, Sweden | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
2.56 Ă | (100) |
1.527 Ă | (70) |
1.662 Ă | (60) |
2.157 Ă | (40) |
3.05 Ă | (30) |
1.1251 Ă | (30) |
4.97 Ă | (20) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-đ alteration and/or metamorphism | |
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits |
Type Occurrence of Filipstadite
General Appearance of Type Material:
As euhedral equant crystals up to 200 mikron in diameter and aggregates
Place of Conservation of Type Material:
British Museum (Natural History)catalogue number BM1986,410: E.1177 and BM1986,411: E.1178.
Associated Minerals at Type Locality:
Reference:
Dunn P J, Peacor D R, Criddle A J, Stanley C J (1988) Filipstadite, a new Mn-Fe3+-Sb derivative of spinel, from LĂ„nban, Sweden. American Mineralogist 73, 413-419
Synonyms of Filipstadite
Other Language Names for Filipstadite
German:Filipstadit
Spanish:Filipstadita
Relationship of Filipstadite to other Species
Member of:
Other Members of this group:
Ahrensite | SiFe2O4 | Iso. m3m (4/m 3 2/m) |
Brunogeierite | Ge4+Fe2+2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Qandilite | (Mg,Fe3+)2(Ti,Fe3+,Al)O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Ringwoodite | (Mg,Fe2+)2SiO4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Tegengrenite | (Mn3+0.5Sb5+0.5)Mg2O4 | Trig. 3 : R3 |
Ulvöspinel | TiFe2+2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
Common Associates
Associated Minerals Based on Photo Data:
3 photos of Filipstadite associated with Calcite | CaCO3 |
3 photos of Filipstadite associated with Jacobsite | Mn2+Fe3+2O4 |
3 photos of Filipstadite associated with Svabite | Ca5(AsO4)3F |
2 photos of Filipstadite associated with Ingersonite | Ca3Mn2+Sb5+4O14 |
2 photos of Filipstadite associated with Friedelite | Mn2+8Si6O15(OH,Cl)10 |
2 photos of Filipstadite associated with Hausmannite | Mn2+Mn3+2O4 |
2 photos of Filipstadite associated with Roméite Group | A2(Sb5+)2O6Z |
1 photo of Filipstadite associated with Tegengrenite | (Mn3+0.5Sb5+0.5)Mg2O4 |
Related Minerals - Strunz-mindat Grouping
4.BB. | Elgoresyite | (Mg5Si2)O9 |
4.BB. | Chenmingite | FeCr2O4 |
4.BB. | Dellagiustaite | V2+Al2O4 |
4.BB. | Thermaerogenite | CuAl2O4 |
4.BB. | Chukochenite | LiAl5O8 |
4.BB. | Garpenbergite | Mn6â»AsSbO10(OH)2 |
4.BB. | Magnéliite | Ti3+2Ti4+2O7 |
4.BB. | Jianmuite | ZrTi4+Ti3+5Al3O16 |
4.BB.05 | Chromite | Fe2+Cr3+2O4 |
4.BB.05 | Cochromite | CoCr2O4 |
4.BB.05 | Coulsonite | Fe2+V3+2O4 |
4.BB.05 | Cuprospinel | Cu2+Fe3+2O4 |
4.BB.05 | Franklinite | Zn2+Fe3+2O4 |
4.BB.05 | Gahnite | ZnAl2O4 |
4.BB.05 | Galaxite | Mn2+Al2O4 |
4.BB.05 | Hercynite | Fe2+Al2O4 |
4.BB.05 | Jacobsite | Mn2+Fe3+2O4 |
4.BB.05 | Manganochromite | Mn2+Cr2O4 |
4.BB.05 | Magnesiocoulsonite | MgV2O4 |
4.BB.05 | Magnesiochromite | MgCr2O4 |
4.BB.05 | Magnesioferrite | MgFe3+2O4 |
4.BB.05 | Magnetite | Fe2+Fe3+2O4 |
4.BB.05 | Nichromite | (Ni,Co,Fe)(Cr,Fe,Al)2O4 |
4.BB.05 | Qandilite | (Mg,Fe3+)2(Ti,Fe3+,Al)O4 |
4.BB.05 | Spinel | MgAl2O4 |
4.BB.05 | Trevorite | Ni2+Fe3+2O4 |
4.BB.05 | Ulvöspinel | TiFe2+2O4 |
4.BB.05 | Vuorelainenite | Mn2+V3+2O4 |
4.BB.05 | Zincochromite | ZnCr2O4 |
4.BB.05 | Harmunite | CaFe2O4 |
4.BB.05 | Wernerkrauseite | Ca(Fe3+,Mn3+)2Mn4+O6 |
4.BB.05 | Deltalumite | (Al0.67â»0.33)Al2O4 |
4.BB.05 | Guite | Co2+Co3+2O4 |
4.BB.10 | Hausmannite | Mn2+Mn3+2O4 |
4.BB.10 | Hetaerolite | ZnMn2O4 |
4.BB.10 | Manganostibite | (Mn,Fe)7SbAsO12 |
4.BB.15 | Maghemite | (Fe3+0.67â»0.33)Fe3+2O4 |
4.BB.15 | Titanomaghemite | (Ti4+0.5â»0.5)Fe3+2O4 |
4.BB.20 | Tegengrenite | (Mn3+0.5Sb5+0.5)Mg2O4 |
4.BB.25 | Xieite | Fe2+Cr2O4 |
4.BB.30 | Carmeltazite | ZrAl2Ti4O11 |
4.BB.35 | Feiite | Fe2+2(Fe2+Ti4+)O5 |
4.BB.40 | Maohokite | MgFe2O4 |
4.BB.45 | Tschaunerite | (Fe2+)(Fe2+Ti4+)O4 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Filipstadite
mindat.org URL:
https://www.mindat.org/min-1548.html
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References for Filipstadite
Reference List:
Dunn, Pete J., Peacor, Donald R., Criddle, Alan J., Stanley, Chris J. (1988) Filipstadite, a new Mn-Fe3+-Sb derivative of spinel, from LĂ„ngban, Sweden. American Mineralogist, 73 (3-4). 413-419
Localities for Filipstadite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Sweden (TL) | |
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Nordmark Odal Field, Filipstad, VĂ€rmland County, Sweden