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Harmunite

A valid IMA mineral species
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About HarmuniteHide

Formula:
CaFe2O4
Colour:
Black
Specific Gravity:
4.404 (Calculated)
Crystal System:
Orthorhombic
Name:
Named after locality.
Post-spinel calcium ferrite. The Fe analogue of ellinaite and marokite.


Unique IdentifiersHide

Mindat ID:
43570
Long-form identifier:
mindat:1:1:43570:7
GUID
(UUID V4):
9ac027ca-4317-492b-827a-643872379ace

IMA Classification of HarmuniteHide

Classification of HarmuniteHide

4.BB.05

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
B : Metal: Oxygen = 3:4 and similar
B : With only medium-sized cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
HmuIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HarmuniteHide

Colour:
Black
Hardness:
VHN50=655 kg/mm2 - Vickers
Density:
4.404 g/cm3 (Calculated)

Chemistry of HarmuniteHide

Mindat Formula:
CaFe2O4

Crystallography of HarmuniteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pbcm
Cell Parameters:
a = 9.2183(3) Å, b = 3.0175(1) Å, c = 10.6934(4) Å
Ratio:
a:b:c = 3.055 : 1 : 3.544
Unit Cell V:
297.45 ų
Z:
4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020333HarmuniteGaluskina I O, Vapnik Y, Lazic B, Armbruster T, Murashko M, Galuskin E V (2014) Harmunite CaFe2O4: A new mineral from the Jabel Harmun, West Bank, Palestinian Autonomy, Israel American Mineralogist 99 965-9752014Hatrurim complex, West Bank, Palestinian Autonomy, Israel0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.670 Å(52)
2.663 Å(100)
2.524 Å(60)
2.523 Å(35)
2.232 Å(34)
1.834 Å(40)
1.831 Å(27)
1.510 Å(19)
Comments:
From Type Description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
50 : Coal and/or oil shale minerals<0.36
51 : Pyrometamorphic minerals (see also #54 and #56)<0.36
Stage 10b: Anthropogenic minerals<10 Ka
54 : Coal and other mine fire minerals (see also #51 and #56)

Type Occurrence of HarmuniteHide

General Appearance of Type Material:
Occurs in larnite pebbles of the pseudo-conglomerate, the cement of which consists of intensely altered larnite-bearing rocks. Srebrodolskite, magnesioferrite, and harmunite are intergrown forming black porous aggregates to the central part of the pebbles
Place of Conservation of Type Material:
St Petersburg University, Universytetskaya Naberezhnaya 7/9, 199034 St Petersburg, Russia, catalogue number 1/19518
Geological Setting of Type Material:
Hatrurim Complex of pyrometamorphic larnite rocks.
Associated Minerals at Type Locality:
Reference:
Galuskina, I.O., Vapnik Ye., Lazic B., Armbruster T., Murashko M. and Galuskin E. (2014) Harmunite CaFe2O4: A new mineral from the Jabel Harmun, West Bank, Palestinian Autonomy, Israel. American Mineralogist: 99: 965–975.

Synonyms of HarmuniteHide

Relationship of Harmunite to other SpeciesHide

Other Members of this group:
ChenmingiteFeCr2O4Orth. mmm (2/m 2/m 2/m) : Pnma
EllinaiteCaCr2O4Orth. mmm (2/m 2/m 2/m) : Pnma
MarokiteCaMn3+2O4Orth.
Tschaunerite (Fe2+)(Fe2+Ti4+)O4Orth. mmm (2/m 2/m 2/m) : Cmcm
WernerkrauseiteCa(Fe3+,Mn3+)2Mn4+O6Orth. mmm (2/m 2/m 2/m) : Pnma
XieiteFe2+Cr2O4Orth. mmm (2/m 2/m 2/m)

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Harmunite associated with SrebrodolskiteCa2Fe3+2O5
1 photo of Harmunite associated with FluorellestaditeCa5(SiO4)1.5(SO4)1.5F
1 photo of Harmunite associated with MagnesioferriteMgFe3+2O4
1 photo of Harmunite associated with AragoniteCaCO3
1 photo of Harmunite associated with Mica Group
1 photo of Harmunite associated with SchorlomiteCa3Ti2(SiO4)(Fe3+O4)2

Related Minerals - Strunz-mindat GroupingHide

4.BB.Elgoresyite(Mg5Si2)O9Mon. 2/m : B2/m
4.BB.ChenmingiteFeCr2O4Orth. mmm (2/m 2/m 2/m) : Pnma
4.BB.DellagiustaiteV2+Al2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.ThermaerogeniteCuAl2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.ChukocheniteLiAl5O8Orth. mmm (2/m 2/m 2/m) : Imma
4.BB.GarpenbergiteMn6◻AsSbO10(OH)2Orth. mmm (2/m 2/m 2/m)
4.BB.MagnéliiteTi3+2Ti4+2O7Tric. 1 : P1
4.BB.JianmuiteZrTi4+Ti3+5Al3O16Tet. 4 : I4
4.BB.05ChromiteFe2+Cr3+2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05CochromiteCoCr2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05CoulsoniteFe2+V3+2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05CuprospinelCu2+Fe3+2O4Iso. m3m (4/m 3 2/m)
4.BB.05Filipstadite(Fe3+0.5Sb5+0.5)Mn2O4Iso.
4.BB.05FrankliniteZn2+Fe3+2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05GahniteZnAl2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05GalaxiteMn2+Al2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05HercyniteFe2+Al2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05JacobsiteMn2+Fe3+2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05ManganochromiteMn2+Cr2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05MagnesiocoulsoniteMgV2O4Iso. m3m (4/m 3 2/m)
4.BB.05MagnesiochromiteMgCr2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05MagnesioferriteMgFe3+2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05MagnetiteFe2+Fe3+2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05Nichromite(Ni,Co,Fe)(Cr,Fe,Al)2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05Qandilite(Mg,Fe3+)2(Ti,Fe3+,Al)O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05SpinelMgAl2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05TrevoriteNi2+Fe3+2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05UlvöspinelTiFe2+2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05VuorelaineniteMn2+V3+2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05ZincochromiteZnCr2O4Iso. m3m (4/m 3 2/m) : Fd3m
4.BB.05WernerkrauseiteCa(Fe3+,Mn3+)2Mn4+O6Orth. mmm (2/m 2/m 2/m) : Pnma
4.BB.05Deltalumite(Al0.670.33)Al2O4Tet. 4 2m : P4m2
4.BB.05GuiteCo2+Co3+2O4Iso.
4.BB.10HausmanniteMn2+Mn3+2O4Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
4.BB.10HetaeroliteZnMn2O4Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
4.BB.10Manganostibite(Mn,Fe)7SbAsO12Orth. mmm (2/m 2/m 2/m)
4.BB.15Maghemite(Fe3+0.670.33)Fe3+2O4Iso. 4 3 2 : P41 3 2
4.BB.15Titanomaghemite(Ti4+0.50.5)Fe3+2O4Iso. 4 3 2 : P43 3 2
4.BB.20Tegengrenite(Mn3+0.5Sb5+0.5)Mg2O4Trig. 3 : R3
4.BB.25XieiteFe2+Cr2O4Orth. mmm (2/m 2/m 2/m)
4.BB.30CarmeltaziteZrAl2Ti4O11Orth. mmm (2/m 2/m 2/m) : Pnma
4.BB.35FeiiteFe2+2(Fe2+Ti4+)O5Orth. mmm (2/m 2/m 2/m) : Cmcm
4.BB.40MaohokiteMgFe2O4Orth. mmm (2/m 2/m 2/m) : Pnma
4.BB.45Tschaunerite (Fe2+)(Fe2+Ti4+)O4Orth. mmm (2/m 2/m 2/m) : Cmcm

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HarmuniteHide

References for HarmuniteHide

Localities for HarmuniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany
 
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Vordereifel
        • Ettringen
          • Caspar quarry
in the collection of Christof Schäfer
    • Vulkaneifel
      • Daun
        • Üdersdorf
Blaß et al. (2014)
      • Gerolstein
        • Hohenfels-Essingen
Collection Joachim Esche
Israel
 
  • Southern District (HaDarom District)
    • Tamar Regional Council
      • Hatrurim Basin
Krzątała et al. (2018)
Middle East
 
Vapnik et al. (2014)
Palestine (TL)
 
  • West Bank
    • Quds Governorate
Mineralogical Magazine +2 other references
Poland
 
  • Silesian Voivodeship
    • Wodzisław County
      • Rydułtowy
        • ROW Ruch Rydułtowy Mine
Ł. Kruszewski PXRD and EPMA data
Russia
 
  • Chelyabinsk Oblast
Sharygin (2015)
 
Mineral and/or Locality  
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