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Wagnerite

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Formula:
(Mg,Fe2+)2(PO4)F
System:
Monoclinic
Colour:
Yellow, brown, red ...
Hardness:
5 - 5½
Member of:
Name:
Named in 1821 by Johann Nepomuk von Fuchs in honor of Franz Michael von Wagner [August 20, 1768 Waldershof, Germany - April 27, 1851 Munich (Germany], mining administrator at Fichtelberg in 1791, later at Chiemgau in 1794, at Reichenhall and Traunstein in 1803, Schwarz, Tyrol in 1806, etc. In 1820, Wagner became head of mining, salt mines, and the mint. Wagner was also important in the development of mining in Bavaria.
Wagnerite Group.

Several polytypes are known. The most common one is wagnerite-Ma2bc.

Classification of Wagnerite

Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
8.BB.15

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
B : With only medium-sized cations, (OH, etc.):RO4 about 1:1
41.6.2.1

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
6 : A2(XO4)Zq
22.1.22

22 : Phosphates, Arsenates or Vanadates with other Anions
1 : Phosphates, arsenates or vanadates with fluoride
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http://www.mindat.org/min-4229.html
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First Recorded Occurrence of Wagnerite

Year of Discovery:
1821
Associated Minerals at First Recorded Locality:

Physical Properties of Wagnerite

Sub-Vitreous, Resinous, Greasy
Diaphaneity (Transparency):
Transparent, Translucent
Colour:
Yellow, brown, red brown, light grey, green, red; colourless in transmitted light.
Streak:
White
Hardness (Mohs):
5 - 5½
Tenacity:
Brittle
Cleavage:
Imperfect/Fair
On {100} and {120}, imperfect; on {001}, in traces.
Fracture:
Conchoidal, Sub-Conchoidal
Density:
3.15 g/cm3 (Measured)    3.15 g/cm3 (Calculated)
Comment:
Slightly lesser values in opaque material (altered [?] or calcian material).

Crystallography of Wagnerite

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Wagnerite-Ma2bcWagnerite-Ma3bcWagnerite-Ma5bcWagnerite-Ma7bcWagnerite-Ma9bc
     
  Monoclinic   
m - Domatic
     
     


a = 9.645(2) Å, b = 31.659(6) Å, c = 11.914(2) Å
β = 108.26(3)°


  a:b:c = 0.305 : 1 : 0.376  
  V 3454.76 ų  
     
X-Ray Powder Diffraction Data:
d-spacingIntensity
3.297 (65)
3.123 (63)
2.985 (100)
2.854 (59)
2.758 (25)
2.710 (22)
1.584 (15)

Optical Data of Wagnerite

Type:
Biaxial (+)
RI values:
nα = 1.568 nβ = 1.572 nγ = 1.582
2V:
Measured: 25° to 35°
Birefringence:
0.046
Max Birefringence:
δ = 0.015
Image shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
r > v weak
Optical Extinction:
Y = b, Z^c = 21°
Pleochroism:
Non-pleochroic

Chemical Properties of Wagnerite

Formula:
(Mg,Fe2+)2(PO4)F
Essential elements:
All elements listed in formula:

Relationship of Wagnerite to other Species

Member of:
Other Members of Group:
HydroxylwagneriteMg2(PO4)(OH)
JoosteiteMn2+(Mn3+,Fe3+)(PO4)O
SarkiniteMn22+(AsO4)(OH)
Stanĕkite(Mn2+,Fe2+,Mg)Fe3+(PO4)O
Triploidite(Mn2+,Fe2+)2(PO4)(OH)
Wolfeite(Fe2+,Mn2+)2(PO4)(OH)
8.BB.05AmblygoniteLiAl(PO4)F
8.BB.05MontebrasiteLiAl(PO4)(OH)
8.BB.05TavoriteLiFe3+(PO4)(OH)
8.BB.10Triplite(Mn2+,Fe2+)2(PO4)(F,OH)
8.BB.10Zwieselite(Fe2+,Mn2+)2(PO4)F
8.BB.15SarkiniteMn22+(AsO4)(OH)
8.BB.15Triploidite(Mn2+,Fe2+)2(PO4)(OH)
8.BB.15Wolfeite(Fe2+,Mn2+)2(PO4)(OH)
8.BB.15Stanĕkite(Mn2+,Fe2+,Mg)Fe3+(PO4)O
8.BB.15JoosteiteMn2+(Mn3+,Fe3+)(PO4)O
8.BB.15HydroxylwagneriteMg2(PO4)(OH)
8.BB.20HoltedahliteMg2(PO4)(OH)
8.BB.20Satterlyite(Fe2+,Mg,Fe3+)2(PO4)(OH,O)
8.BB.25AlthausiteMg4(PO4)2(OH,O)(F,☐)
8.BB.30AdamiteZn2(AsO4)(OH)
8.BB.30EveiteMn22+(AsO4)(OH)
8.BB.30LibetheniteCu2(PO4)(OH)
8.BB.30OliveniteCu2(AsO4)(OH)
8.BB.30ZincolibetheniteCuZn(PO4)(OH)
8.BB.30ZincoliveniteCuZn(AsO4)(OH)
8.BB.30AuriacusiteFe3+Cu2+(AsO4)O
8.BB.35ParadamiteZn2(AsO4)(OH)
8.BB.35TarbuttiteZn2(PO4)(OH)
8.BB.40BarbosaliteFe2+Fe23+(PO4)2(OH)2
8.BB.40HentscheliteCuFe23+(PO4)2(OH)2
8.BB.40Lazulite(Mg,Fe2+)Al2(PO4)2(OH)2
8.BB.40ScorzaliteFe2+Al2(PO4)2(OH)2
8.BB.40WilhelmkleiniteZnFe23+(AsO4)2(OH)2
8.BB.45TrolleiteAl4(PO4)3(OH)3
8.BB.50NamibiteCu(BiO)2(VO4)(OH)
8.BB.55PhosphoellenbergeriteMg14(PO4)6(HPO4,CO3)2(OH)6
8.BB.60UrusoviteCuAl(AsO4)O
8.BB.65TheoparacelsiteCu3(As2O7)(OH)2
8.BB.70TuraniteCu5(VO4)2(OH)4
8.BB.75StoiberiteCu5(VO4)2O2
8.BB.80FingeriteCu11(VO4)6O2
8.BB.85AverieviteCu6(VO4)2O2Cl2
8.BB.90LipscombiteFe2+Fe23+(PO4)2(OH)2
8.BB.90RichelliteCaFe23+(PO4)2(OH,F)2
8.BB.90ZinclipscombiteZnFe23+(PO4)2(OH)2
22.1.1AmblygoniteLiAl(PO4)F
22.1.2LacroixiteNaAl(PO4)F
22.1.3NatrophosphateNa7(PO4)2F · 19H2O
22.1.5NacaphiteNa2Ca(PO4)F
22.1.6ArctiteNa2Ca4(PO4)3F
22.1.7NefedoviteNa5Ca4(PO4)4F
22.1.9FluorapatiteCa2Ca3(PO4)3F
22.1.10HerderiteCaBePO4(F,OH)
22.1.11IsokiteCaMg(PO4)F
22.1.12PanasqueiraiteCaMg(PO4)(OH,F)
22.1.13BabefphiteBaBePO4(F,OH)
22.1.14FluelliteAl2(PO4)F2(OH) · 7H2O
22.1.15MinyuliteKAl2(PO4)2(OH,F) · 4H2O
22.1.16MoriniteNaCa2Al2(PO4)2(OH)F4 · 2H2O
22.1.17BøggilditeNa2Sr2Al2PO4F9
22.1.18FluorstrophiteSrCaSr3(PO4)3F
22.1.19ViitaniemiiteNa(Ca,Mn2+)Al(PO4)(F,OH)3
22.1.20VäyryneniteMn2+Be(PO4)(OH,F)
22.1.21MaxwelliteNaFe3+(AsO4)F
22.1.23Triplite(Mn2+,Fe2+)2(PO4)(F,OH)
22.1.24Magniotriplite(Mg,Fe2+,Mn2+)2PO4F
22.1.25Zwieselite(Fe2+,Mn2+)2(PO4)F
22.1.26McauslaniteFe3Al2(PO4)3(PO3OH)F · 18H2O
22.1.27RichelliteCaFe23+(PO4)2(OH,F)2
22.1.28SvabiteCa5(AsO4)3F
22.1.29TilasiteCaMg(AsO4)F
22.1.30Johnbaumite-MCa5(AsO4)3OH
22.1.31DurangiteNaAl(AsO4)F

Other Names for Wagnerite

Name in Other Languages:

Other Information

Not fluorescent in UV
Other Information:
Soluble in acids.

May alter to apatite.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Wagnerite

Reference List:
Fuchs (1821) Journal für Chemie und Physik, Nuremberg: 33: 269 (as Phosphorsaurer Talk and as Wagnerit).

Breithaupt, A. (1823) Vollständige Characteristik etc., 1st. ed.: 50, 193 (as Pleuroklas).

Brooke, H.J. and Miller, W.H. (1852) Introduction to Mineralogy by Wm. Phillips, London, 1823. New edition by Brooke and Miller. 8vo, London: 489.

Kobell (1873) Journal für praktische Chemie, Leipzig: 7: 272 (as Kjerulfin).

Brögger (1879) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 3: 476.

Pisani (1879) Bulletin de la Société française de Minéralogie: 2: 43 (Kjerulfine).

Bauer (1880) Jb. Min.: II: 77 (Frederici analysis).

Zambonini, Ferruccio (1910) Mineralogia Vesuviana. 368 pp., Naples: 200.

Goldschmidt, V. (1923) Atlas der Krystallformen. 9 volumes, atlas, and text, Heidelberg: vol. 9: 63.

Mellor, J.W. (1923) A Comprehensive Treatise on Inorganic and Theoretical Chemistry. 16 volumes, London: 4: 388.

Hegemann and Steinmetz (1927) Centralblatt für Mineralogie, Geologie und Paleontologie, Stuttgart: 45.

Hintze, Carl (1931) Handbuch der Mineralogie. Berlin and Leipzig. 6 volumes: 1 [4A]: 688, 694.

de Jesus (1936) Com. Serv. Geol. Portugal: 19: 65.

Klement and Dihn (1938) Zeitschrift für anorganische und allgemeine Chemie, Hamburg, Leipzig: 240: 31.

Kraus and Mussgnug (1938) Naturwiss.: 26: 801.

Richmond (1940) American Mineralogist: 25: 470.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 845-848.

Keunho Auh and F. A. Hummel (1974): Solid solution in the wagnerite structure. Can. Mineral, 12, 346-351.

Neues Jahrbuch für Mineralogie, Monatshefte (1976): 4: 158.

Canadian Mineralogist (1992): 30: 1165.

Zeitschrift für Kristallographie: 177: 15.

U.S. Geological Survey Professional Paper 955

Ren, L., Grew, E.S., Xiong, M. & Ma, Z. (2003): Wagnerite-Ma5bc, a new polytype of Mg2(PO4)(F,OH), from granulite-facies paragneiss, Larsemann Hills, Prydz Bay, East Antarctica. Canadian Mineralogist 41, 393-411.

Chopin, C., Armbruster, T. & Leyx, C. (2003) Polytypism in wagnerite, Mg2PO4(F,OH). Geophys. Res. Abstr. 5, 08323.

Armbruster, T.; Chopin, C.; Grew, E. S.; Baronnet, A. (2008): The triplite-wagnerite group: A modulated series. Geochimica et Cosmochimica Acta, Volume 72, Issue 12, p. A32.

Internet Links for Wagnerite

Localities for Wagnerite

map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
(TL) indicates type locality for a valid mineral species. (FRL) indicates first recorded locality for everything else. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
Antarctica
 
  • Eastern Antarctica
    • Enderby Land
http://gsa.confex.com/gsa/2003AM/finalprogram/abstract_60995.
        • Casey Bay
          • Khmara Bay
Edward S. Grew Surinamite, taafeite and beryllian saphirine from pegmatites in graulite-facies rocks of Casey Bay, Enderby Land, Antarctica, - Am. Miner., 1981,v.66, p.1022-1033.
    • Princess Elizabeth Land
      • Ingrid Christensen Coast
        • Prydz Bay
[Wagnerite-Ma5bc] Ren, L., Grew, E.S., Xiong, M. & Ma, Z. (2003): Wagnerite-Ma5bc, a new polytype of Mg2(PO4)(F,OH), from granulite-facies paragneiss, Larsemann Hills, Prydz Bay, East Antarctica. Canadian Mineralogist 41, 393-411
Edward S. Grew, et al (2007) European Journal of Mineralogy, 19, 29-245
            • Stornes Peninsula
Grew, E., Armbruster, Th., Medenbach, O., Yates, M.G., Carson, C.J. (2006): Stornesite-(Y), (Y,Ca)[]2Na6(Ca,Na)8(Mg,Fe)43(PO4)36, the first terrestrial Mg-dominant member of the fillowite group, from granulite-facies paragneiss in the Larsemann Hills, Prydz Bay, East Antarctica. American Mineralogist, 91, 1412-1424
Australia
 
  • South Australia
    • Olary Province
      • Bimbowrie Station
[var: Magniotriplite] Lottermoser, B.G., and Lu, J. (1997): Mineralogy and Petrology 59, 1-19.
  • Tasmania
    • Waratah district
      • Waratah
Bottrill
Austria
 
  • Salzburg
    • Abtenau
      • Webing
A. Strasser: Die Minerale Salzburgs (1989)
    • Hohe Tauern
      • Felben valley
        • Amerbach valley
A. Strasser: Die Minerale Salzburgs (1989)
    • Werfen
      • Pfarrwerfen
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 847; Canadian Mineralogist (1992): 30: 1161.
A. Strasser: Die Minerale Salzburgs, 1989
A. Strasser: Die Minerale Salzburgs, 1989
      • Pöham
        • Fritzbach valley
A. Strasser: Die Minerale Salzburgs, 1989
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 847.
      • Tennen Mts
        • Eiskogel
A. Strasser: Die Minerale Salzburgs, 1989
        • Tenneck
peter neschen collection
  • Upper Austria
    • Kirchdorf an der Krems
      • Spital am Pyhrn
        • Bosruck Mt
          • A9 motorway tunnel (Bosruck tunnel)
WALLENTA, O. (1985): Bosruck – Zur Mineralogie des Bosrucktunnels (Pyhrnautobahn, Österreich). Die Eisenblüte, Jg. 6, Neue Folge, Nr. 15, 9-17.
Canada
 
  • Manitoba
    • Sherridon District
Leroux, M. V. & Ercit, T. S. (1992): Wagnerite, an accessory phase in cordierite-anthophyllite gneiss from Star Lake, Manitoba. Can. Mineral. 30, 1161-1165.
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
No reference listed
China
 
  • Inner Mongolia Autonomous Region
    • Ulanhad League (Chifeng Prefecture)
      • Linxi Co.
Shuyin Niu, Aiqun Sun, Baode Wang, Jianming Liu, Lijun Guo, Huabin Hu, and Chuanshi Xu (2008): Geology in China 35(4), 714-724
Czech Republic
 
  • Bohemia (Böhmen; Boehmen)
    • Liberec Region
      • Frýdlant (Frýdlant v Čechác)
Seifert, W.; Thomas, R.; Rhede, D.; Förster, H.-J. (2010): Origin of coexisting wustite, MgFe and REE phosphate minerals in graphite-bearing fluorapatite from the Rumburk granite. European Journal of Mineralogy 22, 495-507.
  • Moravia (Mähren; Maehren)
    • Vysočina Region
      • Žďár nad Sázavou
Staněk, J.: Parageneze minerálů pegmatitových žil z Hatí u Dolních Borů na západní Moravě. Acta Mus. Moraviae, Sci. nat., vol. 76, pages 19-49.
Staněk, J.: Asociace minerálů významnějších pegmatitových žil v Hatích u Dolních Borů na západní Moravě. Acta Musei Moraviae, Scientiae naturales, 1997, roč. 82, 3-19.
France
 
  • Languedoc-Roussillon
    • Pyrénées-Orientales
Berbain,C., Riley, T., Favreau, G., (2012): Phosphates des pegmatites du massif des Albères (Pyrénées-Orientales). Le Cahier des Micromonteurs. 117, 121-172
        • Argelès-sur-Mer
Berbain, C., Favreau, G. & Aymar, J. (2005): Mines et minéraux des Pyrénées-Orientales et des Corbières, Association Française de Microminéralogie Ed., 135-137.
BERBAIN. C, RILEY. T, FAVREAU. G, (2012). Phosphates des pegmatites du massif des Albères. Ed Association française de Microminéralogie,
Germany
 
  • Bavaria
    • Lower Bavaria
      • Bodenmais
Weiss: "Mineralfundstellen, Deutschland West", Weise (Munich), 1990
  • Rhineland-Palatinate
    • Eifel
      • Andernach
        • Eich
Hentschel, G., Die Mineralien der Eifelvulkane, Weise Verlag, München (2. Auflage), 1987
      • Daun
        • Üdersdorf
Blass, G., Emmerich, F., Graf, HW., Schäfer, Ch., Tschörtner, J., (2006): Minerale der Eifelvulkane, Version 1.0, CD, published by authors
      • Mayen
        • Ettringen
          • Bellerberg volcano
Lapis, 15 (5), 9-36.
      • Polch
        • Ochtendung
Blass, G., Graf , HW., Die Wannenköpfe bei Ochtendung in der Vulkaneifel und ihre Mineralien, MW 6/1999
  • Saxony
    • Erzgebirge
Lapis 30(7/8):78-80 (2005)
Italy
 
  • Campania
    • Naples Province
      • Somma-Vesuvius Complex
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 847; Russo, M., Punzo, I. (2004): I minerali del Somma-Vesuvio, AMI
  • Piedmont
    • Cuneo Province
[MinRec 27:303]
      • Varaita Valley
        • Brossasco
Piccoli, G.C., Maletto, G., Bosio, P., Lombardo, B. (2007). Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo "F. Eusebio" Alba, Ed., Alba (Cuneo) 607 pp.
    • Verbano-Cusio-Ossola Province
      • Ossola Valley
        • Vigezzo Valley
          • Druogno
            • Antoliva Valley
              • Campra
Piccoli, G.C., Maletto, G., Bosio, P., Lombardo, B. (2007). Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo "F. Eusebio" Alba, Ed., Alba (Cuneo) 607 pp.
Kyrgyzstan
 
  • Osh Oblast
    • Turkestan Range
[var: Magniotriplite] Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
[var: Magniotriplite] [DAN-SSSR (1951) 77/1, 97-100; Nickel & Nichols, 1991 - "Mineral Reference Manual", p126]; Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
Norway
 
  • Telemark
Kobell (1873); Bauer (1875); Brøgger (1879, pp. 474-478); Pisani (1879); Neumann (1985, p. 117).
Neumann, H. (1985): Norges Mineraler. Norges Geologiske Undersøkelse Skrifter 68, p. 118
      • Havredal (Hafredal)
        • Midtre Havredal
Helland, A. (1874): Apatit, forekommende i rene Stokke og Gange i Bamle i Norge. Geologiska Föreningen i Stockholm Förhandlingar. 2: 148-156; Brøgger, W.C. & Reusch, H.H. (1875): Vorkommen des Apatit in Norwegen. Zeitschrift der Deutschen Geologischen Gesellschaft 27: 646-702
        • Nedre Havredal
Brøgger, W.C. & Reusch, H.H. (1880): Norske Apatitforekomster. Nyt Magasin for Naturvidenskaberne, 25: 255-300 Neumann (1985, p. 118).; Alf Olav Larsen, personal coments to Peter Andresen, 2010.
Hansen, R. (197?): Gruver og mineralforekomster i Bamble. Unpublished paper, 18p.; RRUFF specimen R050519.2
Brøgger, W.C. & Reusch, H.H. (1875): Vorkommen des Apatit in Norwegen.Zeitschrift der Deutschen Geologischen Gesellschaft 27: 646-702
Portugal
 
  • Castelo Branco District
    • Covilhã
      • Panasqueira
No reference listed
Russia
 
  • Urals Region
    • Southern Urals
      • Chelyabinsk Oblast'
Cesnokov, B., Kotrly, M. and Nisanbajev, T. (1998): Brennende Abraumhalden und Aufschlüsse im Tscheljabinsker Kohlenbecken - eine reiche Mineralienküche. Mineralien-Welt, 9 (3), 54-63 (in German).
Spain
 
  • Castile and Leon
    • Salamanca
      • Garcirrey
[var: Magniotriplite] American Mineralogist 89:110-125 (2004); Encarnación Roda-Robles, Alfonso Pesquera (2007) Locality no. 4: The Phosphates-Rich Cañada Pegmatite (Aldehuela de La Bóveda, Salamanca, Spain) in ALEXANDRE LIMA & ENCARNACIÓN RODA ROBLES ed (2007) GRANITIC PEGMATITES: THE STATE OF THE ART - FIELD TRIP GUIDEBOOK. MEMÓRIAS N. º 9, UNIV. DO PORTO, FACULDADE DE CIÊNCIAS, DEPARTAMENTO DE GEOLOGIA pp 67-72.
  • Catalonia
    • Girona (Gerona)
      • Alt Empordà
        • Cadaqués
[var: Magniotriplite] Bareche, E. (2005) "Els minerals de Catalunya. Segle XX" Ed. Museu Mollfulleda de Mineralogia - Grup Mineralògic Català, 269 p.
Sweden
 
  • Södermanland
[var: Magniotriplite] No reference listed
  • Värmland
    • Torsby
Grensman, F.(1989): Hålsjøberg- En fyndortsbeskrivning. NAGS-nytt 16(3), 24-27
USA
 
  • Arizona
    • La Paz Co.
      • Dome Rock Mts
Grant, Raymond W., Bideaux, R.A., and Williams, S.A. (2006) Minerals Added to the Arizona List 1995-2005: 9.
  • California
    • San Bernardino Co.
      • Hodge
        • Stoddard Well
Van King
  • Colorado
    • Clear Creek Co.
      • Clear Creek pegmatite Province
"Minerals of Colorado, updated & revised", by Eckel, Edwin B., 1997; U.S. Geological Survey Professional Paper 955
  • Maine
    • Hancock Co.
      • Blue Hill
Mineralogical Record 22:382
  • New York
    • St. Lawrence Co.
NY State Museum spec. no. 16020
        • Benson
Jaffe, H.W. , Hall, L.M. and Evans, H.T. (1992). "Wagnerite with isokite from the Benson Mines, west central Adirondack higlands, New York." Mineralogical Magazine, 56(2),pp:227-233.
Mineral and/or Locality  
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