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Ferrosaponite

A valid IMA mineral species
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About FerrosaponiteHide

Formula:
Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O
Colour:
Dark green
Lustre:
Vitreous
Hardness:
2
Specific Gravity:
2.49
Crystal System:
Monoclinic
Member of:
Name:
Named for being the ferrous-iron analogue of saponite.
This page provides mineralogical data about Ferrosaponite.


Unique IdentifiersHide

Mindat ID:
29079
Long-form identifier:
mindat:1:1:29079:7
GUID
(UUID V4):
f5f8e4db-ca66-4597-8c96-852a6b62baf5

IMA Classification of FerrosaponiteHide

Classification of FerrosaponiteHide

9.EC.45

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
FsapIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
FsapWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of FerrosaponiteHide

Vitreous
Transparency:
Translucent
Colour:
Dark green
Streak:
green
Hardness:
Cleavage:
Perfect
(001)
Fracture:
Irregular/Uneven
Density:
2.49(5) g/cm3 (Measured)    2.435 g/cm3 (Calculated)

Optical Data of FerrosaponiteHide

Type:
Biaxial (-)
RI values:
nα = 1.448 nβ = 1.641(2) nγ = 1.642(2)
2V:
Measured: -5° (2), Calculated: -7.5°
Max Birefringence:
δ = 0.194
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Pleochroism:
Visible
Comments:
Brown
Comments:
Alpha index calculated from Gladstone-Dale

Chemistry of FerrosaponiteHide

Mindat Formula:
Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O

Crystallography of FerrosaponiteHide

Crystal System:
Monoclinic
Cell Parameters:
a = 5.365(2) Å, b = 9.337(4) Å, c = 14.65(2) Å
β = 94.9(1)°
Ratio:
a:b:c = 0.575 : 1 : 1.569
Unit Cell V:
731.18 ų (Calculated from Unit Cell)
Z:
2
Comment:
Point Group: n.d.; Space Group: n.d.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.03 Å(100)
7.37 Å(90)
4.72 Å(90)
2.585 Å(90)
2.429 Å(90)
1.549 Å(90)
3.80 Å(80)
14.61 Å(40)
Comments:
14.61 (40) - (expands to 17.9 after glycolation).

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3b: Earth’s earliest hydrosphere>4.45
13 : Hadean serpentinization
16 : Low-𝑇 aqueous alteration of Hadean subaerial lithologies (see also #23)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]

Type Occurrence of FerrosaponiteHide

General Appearance of Type Material:
spherulites, up to 2 тmm diameter, ог radiating/columnar aggregates included into calcite crystals.
Place of Conservation of Type Material:
Geoscientific Collections of Freiberg University of Mining and
Technology, Germany (the inventory number 80252).
Geological Setting of Type Material:
Basalt pillow lavas
Associated Minerals at Type Locality:
Reference:
Chukanov, N.V., Pekov, I.V., Zadov, A.E., Chukanova, V.N., Möckel, S. (2003) Ferrosaponite Ca0.3(Fe2+,Mg,Fe3+)3·(Si,Al)4O10(OH)2·4H2O, the new trioctahedral smectite. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 132(2): 68-74.

Other Language Names for FerrosaponiteHide

Simplified Chinese:铁皂石
Traditional Chinese:鐵皂石

Relationship of Ferrosaponite to other SpeciesHide

Member of:
Other Members of this group:
Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon. 2/m : B2/m
Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
PimeliteNi3Si4O10(OH)2 · 4H2OHex.
Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon. 2/m : B2/m
SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
SwineforditeLi(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2OMon. 2/m : B2/m
VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m
VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.
Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
ZincsiliteZn3Si4O10(OH)2 · 4H2O (?)Mon.

Common AssociatesHide

Associated Minerals Based on Photo Data:
8 photos of Ferrosaponite associated with CalciteCaCO3
6 photos of Ferrosaponite associated with PrehniteCa2Al2Si3O10(OH)2
3 photos of Ferrosaponite associated with DatoliteCaB(SiO4)(OH)
3 photos of Ferrosaponite associated with AdulariaKAlSi3O8
1 photo of Ferrosaponite associated with VesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9
1 photo of Ferrosaponite associated with LizarditeMg3(Si2O5)(OH)4
1 photo of Ferrosaponite associated with Phillipsite Subgroup
1 photo of Ferrosaponite associated with Chabazite
1 photo of Ferrosaponite associated with Heulandite Subgroup(Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O

Related Minerals - Strunz-mindat GroupingHide

9.EC.BalestraiteKLi2V5+Si4O12Mon. 2 : B2
9.EC.MeifuiteKFe6(Si7Al)O19(OH)4Cl2Tric. 1 : P1
9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.05WillemseiteNi3Si4O10(OH)2Mon.
9.EC.9.EC.VoloshiniteRb(LiAl1.50.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon. 2/m
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.10LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m : B2/b
9.EC.10FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m : B2/m
9.EC.10ManganiceladoniteK(MgMn3+◻)(Si4O10)(OH)2Mon.
9.EC.10GarmiteCsLiMg2(Si4O10)F2Mon.
9.EC.10GorbunoviteCsLi2(Ti,Fe)Si4O10(F,OH,O)2Mon.
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon. 2/m
9.EC.15CeladoniteK(MgFe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15Tobelite(NH4,K)Al2(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.15AluminoceladoniteK(MgAl◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroaluminoceladoniteK(Fe2+Al◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15FerroceladoniteK(Fe2+Fe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(MgCr◻)(Si4O10)(OH)2Mon. 2 : B2
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.15Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15UM1988-22-SiO:AlCaFFeHKLiMgKLiMgAl2Si3O10F2Mon.
9.EC.15KreiteriteCsLi2Fe3+(Si4O10)F2Mon.
9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric. 1 : P1
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2Mon. 2 : B2
9.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2Mon. 2/m : B2/m
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
9.EC.20Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20ShirokshiniteK(NaMg2)(Si4O10)F2Mon. 2/m : B2/m
9.EC.20ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20FluorophlogopiteKMg3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20UM2004-49-SiO:AlCsFHKLi(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m : B2/m
9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.20Chloroferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2
9.EC.22PimeliteNi3Si4O10(OH)2 · 4H2OHex.
9.EC.30Chlorophaeite(Ca,Mg,Fe)2Fe2Si4O13 · 10H2O
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m : B2/b
9.EC.35BityiteCaLiAl2(AlBeSi2O10)(OH)2Mon. 2/m : B2/b
9.EC.35ClintoniteCaAlMg2(SiAl3O10)(OH)2Mon. 2/m : B2/m
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon. 2/m : B2/m
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon. 2/m : B2/m
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m : B2/m
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m : B2/m
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon. 2/m : B2/m
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
9.EC.45SwineforditeLi(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2OMon. 2/m : B2/m
9.EC.45ZincsiliteZn3Si4O10(OH)2 · 4H2O (?)Mon.
9.EC.45HanjiangiteBa2CaV3+Al(H2AlSi3O12)(CO3)2FMon. 2 : B2
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m
9.EC.52Tarasovitenear NaKAl11Si13O40(OH)9 · 3H2O
9.EC.55Baileychlore(Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8Tric. 1
9.EC.55Chamosite(Fe2+)5Al(Si,Al)4O10(OH,O)8Mon. 2/m : B2/m
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Cookeite(LiAl4◻)[AlSi3O10](OH)8Mon. 2/m
9.EC.55FranklinfurnaceiteCa2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 : B2
9.EC.55Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8Orth.
9.EC.55Nimite(Ni,Mg,Al)6((Si,Al)4O10)(OH)8Mon. 2/m : B2/m
9.EC.55Orthochamosite(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
9.EC.55SudoiteMg2Al3(Si3Al)O10)(OH)8Mon. 2/m : B2/m
9.EC.55DonbassiteAl4.33(Si3Al)O10(OH)8Mon. 2 : B2
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
9.EC.55Borocookeite(LiAl4◻)[BSi3O10](OH)8Mon. m : Bb
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2OMon.
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2OOrth.
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2OMon. 2/m : B2/m
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2OMon.
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon. 2/m : B2/m
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2OMon. 2 : B2
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2OMon.
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m (3 2/m) : P3 1m
9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2OMon.
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon. 2 : P21
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2OMon.
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FerrosaponiteHide

References for FerrosaponiteHide

Localities for FerrosaponiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Antarctica
 
  • Western Antarctica
    • Antarctic Peninsula
      • South Shetland Islands
        • King George Island
Sorrell (n.d.)
Australia
 
  • Tasmania
    • Launceston City municipality
      • The Sideling
Bottrill et al. (2020)
Brazil
 
  • São Paulo
    • Pederneiras
      • Pederneiras
Färber (n.d.)
Germany
 
  • Rhineland-Palatinate
    • Vulkaneifel
      • Gerolstein
        • Hillesheim
ko.jansen
India
 
  • Maharashtra
    • Konkan Division
      • Raigad District
Jewel Tunnel specimens
Italy
 
  • Trentino-Alto Adige (Trentino-South Tyrol)
    • Trento Province (Trentino)
      • Ala
        • Pilcante
Bortolozzi (n.d.)
  • Veneto
    • Verona Province
      • Montecchia di Crosara
Gianluca Fontana collection
Mattioli et al. (2008)
Mattioli et al. (2008)
Mattioli et al. (2008)
Japan
 
  • Yamanashi Prefecture
    • Minamikoma District
      • Minobu
        • Shimobe
japanese specimen label dated 20-11-1994
Poland
 
  • Lower Silesian Voivodeship
    • Lubań County
      • Gmina Leśna
        • Grabiszyce Średnie
www.spiriferminerals.com (2018) +1 other reference
Russia (TL)
 
  • Krasnoyarsk Krai
    • Evenkiysky District
      • Nizhnyaya Tunguska River Basin
Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva (2) +1 other reference
Spain
 
  • Catalonia
    • Girona
      • Maçanet de la Selva
Jordi Fabre
USA
 
  • California
    • Los Angeles County
      • Los Angeles
        • Hollywood Hills
          • Hollywood
            • Cahuenga Pass
              • Cahuenga Boulevard roadcut
Fred DeVito collection +1 other reference
  • Connecticut
    • Hartford County
      • Farmington
Moritz (n.d.)
    • Litchfield County
      • Woodbury
        • Orenaug Hills
Former Bill Barrett collection
 
Mineral and/or Locality  
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