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Vermiculite

Formula:
(Mg,Fe,Al)
 
3
(Al,Si)
 
4
O
 
10
(OH)
 
2
·4H
 
2
O
System:MonoclinicColour:Brown, bronze-yellow
Hardness:1½ - 2
Name:From Latin "vermiculare", to breed worms, in allusion to its peculiar exfoliation on intense heating.


Montmorillonite-Vermiculite Group.

Forms as an alteration product of biotite or phlogopite, by weathering or hydrothermal action. Vermiculite is mined as a natural insulation material.

Classification of Vermiculite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:8/H.21-10
Nickel-Strunz 10th (pending) edition ID:9.EC.50

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
Dana 8th edition ID:71.2.2d.3

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
Hey's CIM Ref.:16.19.22

16 : Silicates Containing Aluminum and other Metals
19 : Aluminosilicates of Fe and Mg
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Type Occurrence of Vermiculite

Type Locality:Millbury, Worcester Co., Massachusetts, USA
Year of Discovery:1824

Physical Properties of Vermiculite

Colour:Brown, bronze-yellow
Hardness (Mohs):1½ - 2

Crystallography of Vermiculite

Crystal System:Monoclinic
Cell Parameters:a = 5.24Å, b = 9.17Å, c = 28.6Å
β = 94.6°
Ratio:a:b:c = 0.571 : 1 : 3.119
Unit Cell Volume:V 1,369.83 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data: Peaks:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Vermiculite

Type:Biaxial (-)
RI values: nα = 1.525 - 1.561 nβ = 1.545 - 1.581 nγ = 1.545 - 1.581
Maximum Birefringence:δ = 0.020

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low
Dispersion:weak

Chemical Properties of Vermiculite

Formula:
(Mg,Fe,Al)
 
3
(Al,Si)
 
4
O
 
10
(OH)
 
2
·4H
 
2
O
Essential elements:Al, H, Mg, O
All elements listed in formula:Al, Fe, H, Mg, O, Si
Common Impurities:Ca,Na,K

Relationship of Vermiculite to other Species

Related to:
  • Montmorillonite-Vermiculite Group
  • Related Minerals - Nickel-Strunz Grouping):
    9.EC.05Minnesotaite
    (Fe,Mg)
     
    3
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    9.EC.05Talc
    Mg
     
    3
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    9.EC.05Willemseite
    (Ni,Mg)
     
    3
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    9.EC.10Ferripyrophyllite
    Fe
     
    2
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    9.EC.10Pyrophyllite
    Al
     
    2
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    9.EC.15Boromuscovite
    KAl
     
    2
    [(OH)
     
    2
    |BSi
     
    3
    O
     
    10
    ]
    9.EC.15Celadonite
    K(Mg,Fe
    2+
     
    )(Fe
    3+
     
    ,Al)[(OH)
     
    2
    |Si
     
    4
    O
     
    10
    ]
    9.EC.15Chernykhite
    (Ba,Na)(V
    3+
     
    ,Al,Mg)
     
    2
    [(OH)
     
    2
    |(Si,Al)
     
    4
    O
     
    10
    ]
    9.EC.15Montdorite
    (K,Na)
     
    2
    (Fe
    2+
     
    ,Mn
    2+
     
    ,Mg)
     
    5
    [(OH,F)
     
    2
    |Si
     
    4
    O
     
    10
    ]
     
    2
    9.EC.15Muscovite
    KAl
     
    2
    [(OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.15Nanpingite
    CsAl
     
    2
    [(OH,F)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.15Paragonite
    NaAl
     
    2
    [(OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.15Roscoelite
    K(V,Al)
     
    2
    [(OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.15Tobelite
    (NH
     
    4
    ,K)Al
     
    2
    [(OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.15Aluminoceladonite
    K(Mg,Fe
    2+
     
    )(Al,Fe
    3+
     
    )[(OH)
     
    2
    |Si
     
    4
    O
     
    10
    ]
    9.EC.15Chromphyllite
    K(Cr,Al)
     
    2
    [(OH,F)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.15Ferro-aluminoceladonite
    K(Fe
    2+
     
    ,Mg)(Al,Fe
    3+
     
    )[(OH)
     
    2
    |Si
     
    4
    O
     
    10
    ]
    9.EC.15Ferroceladonite
    K(Fe
    2+
     
    ,Mg)(Fe
    3+
     
    ,Al)[(OH)
     
    2
    |Si
     
    4
    O
     
    10
    ]
    9.EC.15Chromceladonite
    K(Mg,Fe
    2+
     
    )(Cr,Al)[(OH)
     
    2
    |Si
     
    4
    O
     
    10
    ]
    9.EC.15Tainiolite
    KLiMg
     
    2
    [F
     
    2
    |Si
     
    4
    O
     
    10
    ]
    9.EC.15Ganterite
    (Ba,Na,K)(Al,Mg)
     
    2
    [(OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.20Annite
    KFe
    2+
    3
    [(OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.20Biotite
    9.EC.20Ephesite
    NaLiAl
     
    2
    [(OH)
     
    2
    |Al
     
    2
    Si
     
    2
    O
     
    10
    ]
    9.EC.20Hendricksite
    K(Zn,Mg,Mn
    2+
     
    )
     
    3
    [(OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.20Masutomilite
    (K,Rb)(Li,Mn
    3+
     
    ,Al)
     
    3
    [(F,OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.20Norrishite
    KLiMn
    2+
    2
    [(OH)
     
    2
    |Si
     
    4
    O
     
    10
    ]
    9.EC.20Phlogopite
    KMg
     
    3
    [(OH,F)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.20Polylithionite
    KLi
     
    2
    Al[(F,OH)
     
    2
    |Si
     
    4
    O
     
    10
    ]
    9.EC.20Preiswerkite
    NaMg
     
    2
    Al[(OH)
     
    2
    |Al
     
    2
    Si
     
    2
    O
     
    10
    ]
    9.EC.20Siderophyllite
    KFe
    2+
    2
    Al[(F,OH)
     
    2
    |Al
     
    2
    Si
     
    2
    O
     
    10
    ]
    9.EC.20Tetra-ferriphlogopite
    KMg
     
    3
    [(OH,F)
     
    2
    |(Fe
    3+
     
    ,Al)Si
     
    3
    O
     
    10
    ]
    9.EC.20Wonesite
    (Na,K)(Mg,fe,Al)
     
    6
    (Al,Si)
     
    8
    O
     
    20
    (OH,F)
     
    4
    9.EC.20Zinnwaldite
    KLiFe
    2+
     
    Al[(F,OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.20Eastonite
    KMg
     
    2
    Al[(OH)
     
    2
    |Al
     
    2
    Si
     
    2
    O
     
    10
    ]
    9.EC.20Tetraferriannite
    KFe
    2+
    3
    [(OH)
     
    2
    |(Fe
    3+
     
    ,Al)Si
     
    3
    O
     
    10
    ]
    9.EC.20Trilithionite
    K(Li,Al)
     
    3
    [(F,OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.20Fluorannite
    KFe
    2+
    3
    [(F,OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.20Shirokshinite
    KNaMg
     
    2
    [F
     
    2
    |Si
     
    4
    O
     
    10
    ]
    9.EC.20Shirozulite
    K(Mn
    2+
     
    ,Mg)
     
    3
    [(OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.20Sokolovaite
    CsLi
     
    2
    AlSi
     
    4
    O
     
    10
    F
     
    2
    9.EC.20Aspidolite
    NaMg
     
    3
    [(OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.20Fluorophlogopite
    KMg
     
    3
    [(F,OH)
     
    2
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.25Brammallite
    Na
     
    0.65
    Al
     
    2.0
    ٱAl
     
    0.65
    Si
     
    3.35
    O
     
    10
    (OH)
     
    2
    9.EC.30Margarite
    CaAl
     
    2
    [(OH)
     
    2
    |Al
     
    2
    Si
     
    2
    O
     
    10
    ]
    9.EC.35Anandite
    (Ba,K)(Fe
    2+
     
    ,Mg)
     
    3
    [(O,OH)
     
    2
    |(Si,Al,Fe)
     
    4
    O
     
    10
    ]
    9.EC.35Bityite
    CaLiAl
     
    2
    [(OH)
     
    2
    |BeAlSi
     
    2
    O
     
    10
    ]
    9.EC.35Clintonite
    Ca(Mg,Al)
     
    3
    [(OH)
     
    2
    |Al
     
    3
    SiO
     
    10
    ]
    9.EC.35Kinoshitalite
    (Ba,K)(Mg,Mn
    2+
     
    ,Al)
     
    3
    [(OH)
     
    2
    |Al
     
    2
    Si
     
    2
    O
     
    10
    ]
    9.EC.35Ferrokinoshitalite
    (Ba,K)(Fe
    2+
     
    ,Mg)
     
    3
    [(OH,F)
     
    2
    |Al
     
    2
    Si
     
    2
    O
     
    10
    ]
    9.EC.35Oxykinoshitalite
    (Ba,K)(Mg,Ti,Fe
    3+
     
    ,Fe
    2+
     
    )
     
    3
    [(O,OH,F)
     
    2
    |(Si,Al)
     
    4
    O
     
    10
    ]
    9.EC.40Beidellite
    (Na,Ca
     
    0.5
    )
     
    0.3
    Al
     
    2
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    2
    ·nH
     
    2
    O
    9.EC.40Kurumsakite
    (Zn,Ni,Cu)
     
    8
    Al
     
    8
    V
     
    2
    Si
     
    5
    O
     
    35
    ·27H
     
    2
    O (or near)
    9.EC.40Montmorillonite
    (Na,Ca)
     
    0.33
    (Al,Mg)
     
    2
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    ·nH
     
    2
    O
    9.EC.40Nontronite
    Na
     
    0.3
    Fe
     
    2
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    2
    ·nH
     
    2
    O
    9.EC.40Volkonskoite
    Ca
     
    0.3
    (Cr,Mg,Fe)
     
    2
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    2
    ·4H
     
    2
    O
    9.EC.40Yakhontovite
    (Ca,Na)
     
    0.5
    (Cu,Fe,Mg)
     
    2
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    ·3H
     
    2
    O
    9.EC.40Smectite
    9.EC.45Hectorite
    Na
     
    0.3
    (Mg,Li)
     
    3
    Si
     
    4
    O
     
    10
    (F,OH)
     
    2
    9.EC.45Saponite
    Ca
     
    0.25
    (Mg,Fe)
     
    3
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    2
    ·nH
     
    2
    O
    9.EC.45Sauconite
    Na
     
    0.3
    Zn
     
    3
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    2
    ·4H
     
    2
    O
    9.EC.45Spadaite
    MgSiO
     
    2
    (OH)
     
    2
    ·H
     
    2
    O
    9.EC.45Stevensite
    (Ca,Na)
     
    x
    Mg
     
    3
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    9.EC.45Swinefordite
    Li(Al,Li,Mg)
     
    4
    (Si,Al)
     
    8
    O
     
    20
    ,(OH,F)
     
    4
    ·xH
     
    2
    O
    9.EC.45Zincsilite
    Zn
     
    3
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    ·4H
     
    2
    O
    9.EC.45Ferrosaponite
    Ca
     
    0.3
    (Fe
    2+
     
    ,Mg,Fe
    3+
     
    )
     
    3
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    2
    ·4H
     
    2
    O
    9.EC.55Baileychlore
    (Zn,Fe,Al,Mg)
     
    6
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    8
    9.EC.55Chamosite
    (Fe
    2+
     
    ,Mg)
     
    5
    Al[(OH)
     
    8
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.55Clinochlore
    (Mg,Fe
    2+
     
    )
     
    5
    Al[(OH)
     
    8
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.55Cookeite
    LiAl
     
    4
    (Si
     
    3
    Al)O
     
    10
    (OH)
     
    8
    9.EC.55Franklinfurnaceite
    Ca
     
    2
    FeMn
     
    3
    MnZn
     
    2
    Si
     
    2
    O
     
    10
    (OH)
     
    8
    9.EC.55Gonyerite
    (Mn,Mg)
     
    5
    Fe(Si
     
    3
    Fe)O
     
    10
    (OH)
     
    8
    9.EC.55Nimite
    (Ni,Mg,Al)
     
    6
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    8
    9.EC.55Orthochamosite
    (Fe,Mg,Fe)
     
    5
    Al(Si
     
    3
    Al)O
     
    10
    (OH,O)
     
    8
    9.EC.55Pennantite
    (Mn
     
    5
    Al)(Si
     
    3
    Al)O
     
    10
    (OH)
     
    8
    9.EC.55Sudoite
    (Mg,Fe
    2+
     
    )
     
    2
    Al
     
    3
    [(OH)
     
    8
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.55Donbassite
    Al
     
    2
    [Al
     
    2.33
    ][Si
     
    3
    AlO
     
    10
    ](OH)
     
    8
    9.EC.55Glagolevite
    Na(Mg,Al)
     
    6
    [(OH,O)
     
    8
    |AlSi
     
    3
    O
     
    10
    ]
    9.EC.55Borocookeite
    Li
     
    1+3x
    Al
     
    4-x
    [(BSi
     
    3
    )O
     
    10
    ](OH)
     
    8
    [0.00 <= x <=0.33]
    9.EC.60Aliettite
    Ca
     
    0.2
    Mg
     
    6
    (Si,Al)
     
    8
    O
     
    20
    (OH)
     
    4
    ·4H
     
    2
    O
    9.EC.60Corrensite
    (Mg,Fe)
     
    9
    (Si,Al)
     
    8
    O
     
    20
    (OH)
     
    10
    ·nH
     
    2
    O
    9.EC.60Dozyite
    Mg
     
    7
    Al
     
    2
    [(OH)
     
    12
    |Al
     
    2
    Si
     
    4
    O
     
    15
    ]
    9.EC.60Hydrobiotite
    9.EC.60Karpinskite
    (Ni,Mg)
     
    2
    Si
     
    2
    O
     
    5
    (OH)
     
    2
    9.EC.60Kulkeite
    Mg
     
    8
    Al(AlSi
     
    7
    )O
     
    20
    (OH)
     
    10
    9.EC.60Lunijianlaite
    Li
     
    0.7
    Al
     
    6.2
    (Si
     
    7
    AlO
     
    20
    )(OH,O)
     
    10
    9.EC.60Rectorite
    (Na,Ca)Al
     
    4
    (Si,Al)
     
    8
    O
     
    20
    (OH)
     
    4
    ·2H
     
    2
    O
    9.EC.60Saliotite
    Li
     
    0.5
    Na
     
    0.5
    Al
     
    3
    Si
     
    3
    AlO
     
    10
    (OH)
     
    5
    9.EC.60Tosudite
    9.EC.60Brinrobertsite
    Na
     
    0.3
    Al
     
    4
    [(OH)
     
    2
    |Si
     
    4
    O
     
    10
    ]
     
    2
    · 3.5 H
     
    2
    O
    9.EC.65Macaulayite
    (Fe,Al)
     
    24
    Si
     
    4
    O
     
    43
    (OH)
     
    2
    9.EC.70Burckhardtite
    Pb
     
    2
    (Fe,Mn)AlTeO
     
    2
    Si
     
    3
    O
     
    10
    (OH)
     
    2
    ·H
     
    2
    O
    9.EC.75Ferrisurite
    (Pb,Ca)
     
    2-3
    (CO
     
    3
    )
     
    1.5-2
    (OH,F)
     
    0.5-1
    [(Fe,Al)
     
    2
    Si
     
    4
    O
     
    10
    (OH)
     
    2
    ]·nH
     
    2
    O
    9.EC.75Surite
    Pb(Pb,Ca)(CO
     
    3
    )
     
    2
    (Al,Fe,Mg)
     
    2
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    2
    9.EC.75Niksergievite
    (Ba,Ca)
     
    2
    (Al,Si)
     
    7
    O
     
    10
    (CO
     
    3
    )(OH)
     
    6
    ·nH
     
    2
    O
    9.EC.80Kegelite
    Pb
     
    12
    (Zn,Fe)
     
    2
    Al
     
    4
    (SO
     
    4
    )
     
    4
    Si
     
    11
    O
     
    38
    or near
    Related Minerals - Hey's Index Grouping:
    16.19.1Indialite
    Mg
     
    2
    Al
     
    4
    Si
     
    5
    O
     
    18
    16.19.2Cordierite
    (Mg,Fe)
     
    2
    Al
     
    4
    Si
     
    5
    O
     
    18
    16.19.3Sekaninaite
    (Fe,Mg)
     
    2
    Al
     
    4
    Si
     
    5
    O
     
    18
    16.19.4Ferrogedrite
    ☐[Fe
    2+
    2
    ][Fe
    2+
    3
    Al
     
    2
    ][(OH)
     
    2
    |Al
     
    2
    Si
     
    6
    O
     
    22
    ]
    16.19.5Staurolite
    (Fe
    2+
     
    ,Mg,Zn)
     
    1.5-2
    Al
     
    9
    [O
     
    6
    |(OH,O)
     
    2
    |(SiO
     
    4
    )
     
    4
    ]
    16.19.6Chloritoid
    (Fe
    2+
     
    ,Mg,Mn
    2+
     
    )Al
     
    2
    [O|(OH)
     
    2
    |SiO
     
    4
    ]
    16.19.7Amesite
    Mg
     
    2
    Al[(OH)
     
    4
    |AlSiO
     
    5
    ]
    16.19.8Corundophilite
    (Mg,Fe,Al)
     
    6
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    8
    16.19.9Yoderite
    Mg(Al,Fe
    3+
     
    )
     
    3
    [O|OH|(SiO
     
    4
    )
     
    2
    ]
    16.19.10Delessite
    (Mg,Fe,Fe,Al)(Si,Al)
     
    4
    O
     
    10
    (O,OH)
     
    8
    16.19.11Ferrocarpholite
    (Fe
    2+
     
    ,Mg)Al
     
    2
    [(OH)
     
    4
    |Si
     
    2
    O
     
    6
    ]
    16.19.12Magnesiocarpholite
    (Mg,Fe
    2+
     
    )Al
     
    2
    [(OH)
     
    4
    |Si
     
    2
    O
     
    6
    ]
    16.19.13Chamosite
    (Fe
    2+
     
    ,Mg)
     
    5
    Al[(OH)
     
    8
    |AlSi
     
    3
    O
     
    10
    ]
    16.19.14Orthochamosite
    (Fe,Mg,Fe)
     
    5
    Al(Si
     
    3
    Al)O
     
    10
    (OH,O)
     
    8
    16.19.15Berthierine
    (Fe,Fe,Mg)
     
    2-3
    (Si,Al)
     
    2
    O
     
    5
    (OH)
     
    4
    16.19.16Odinite
    (Fe,Mg,Al,Fe,Ti,Mn)
     
    2.4
    (Si,Al)
     
    2
    O
     
    5
    (OH)
     
    4
    16.19.17Clinochlore
    (Mg,Fe
    2+
     
    )
     
    5
    Al[(OH)
     
    8
    |AlSi
     
    3
    O
     
    10
    ]
    16.19.18Gedrite
    ☐[Mg
     
    2
    ][Mg
     
    3
    Al
     
    2
    ][(OH)
     
    2
    |Al
     
    2
    Si
     
    6
    O
     
    22
    ]
    16.19.19Magnesiogedrite
    16.19.20Diabantite
    (Mg,Fe,Al)
     
    6
    (Si,Al)
     
    4
    O
     
    10
    (OH)
     
    8
    16.19.21Sudoite
    (Mg,Fe
    2+
     
    )
     
    2
    Al
     
    3
    [(OH)
     
    8
    |AlSi
     
    3
    O
     
    10
    ]
    16.19.23Corrensite
    (Mg,Fe)
     
    9
    (Si,Al)
     
    8
    O
     
    20
    (OH)
     
    10
    ·nH
     
    2
    O

    Other Names for Vermiculite

    Synonyms:
    BrodrickiteCulsageeiteJefferisiteZonolite
    German names:
    Vermiculit
    Russian names:
    Вермикулит
    Spanish names:
    Vermiculita
    Varieties:
    BataviteCopper VermiculiteEastonite (of Hamilton)Lucasite (of Chatard)Vaalite

    Other Information

    Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

    References for Vermiculite

    Reference List:American Journal of Science (1824): 7: 55.

    American Mineralogist (1966): 51: 1124.

    American Mineralogist (1975): 60: 175.

    Clays and Clay Minerals (1992): 40: 335.

    Internet Links for Vermiculite

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  • Look for Vermiculite on Wikipedia
  • Look for Vermiculite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Vermiculite in the Natural History Museum (London) online catalogue
  • Vermiculite details from Handbook of Mineralogy (PDF)
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    Localities for Vermiculite

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