Arthurite
A valid IMA mineral species
This page kindly sponsored by The Russell Society
About Arthurite
Formula:
CuFe3+2(AsO4)2(OH)2 · 4H2O
Colour:
Apple-green, emerald-green, pale olive-green.
Lustre:
Vitreous
Hardness:
3 - 4
Specific Gravity:
3.2
Crystal System:
Monoclinic
Member of:
Name:
Named in 1964 by Richard J. Davis and Max Hutchinson Hey in honor of Sir Arthur Edward Ian Montagu Russell [November 30, 1878 Folkestone, Kent, England, UK - February 23, 1964 UK], British mineral collector and Mr Arthur William Gerald Kingsbury [June 27, 1906 East Meon, Hampshire, England, UK - August 3, 1968 UK], English mineralogists and collectors. Sir Arthur Edward Ian Montagu Russell (1878-1964) 6th Baronet, of Swallowfield Park, Reading, Berkshire, was perhaps the greatest British mineral collector of the 20th century. Sir Arthur Russell’s will directed that his collection should be given to the British Museum (Natural History) – now the Natural History Museum. The Russell Society, an organisation for amateur and professional mineralogists, dedicated to British topographical mineralogy, was named in his honor. Arthur Kingsbury, Russell's friend was an indefatigable field collector and prolific author of mineralogical articles.
Unique Identifiers
Mindat ID:
376
Long-form identifier:
mindat:1:1:376:6
GUID
(UUID V4):
(UUID V4):
7e1bc392-19f8-4738-b787-b3a39304e8a0
IMA Classification of Arthurite
Approved
Approval year:
1964
First published:
1964
Classification of Arthurite
8.DC.15
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
42.11.20.2
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
20.1.16
20 : Arsenates (also arsenates with phosphate, but without other anions)
1 : Arsenates of Cu
20 : Arsenates (also arsenates with phosphate, but without other anions)
1 : Arsenates of Cu
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Atu | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Arthurite
Vitreous
Transparency:
Transparent, Translucent
Colour:
Apple-green, emerald-green, pale olive-green.
Streak:
(not reported)
Hardness:
3 - 4 on Mohs scale
Density:
3.2 g/cm3 (Measured) 3.29 g/cm3 (Calculated)
Optical Data of Arthurite
Type:
Biaxial (+/-)
RI values:
nα = 1.736 nβ = 1.767 nγ = 1.796
2V:
Calculated: 86°
Max Birefringence:
δ = 0.060
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r > v
Pleochroism:
Weak
Comments:
X = colorless to pale green; Y = gray-green; Z = olive-green.
Chemistry of Arthurite
Mindat Formula:
CuFe3+2(AsO4)2(OH)2 · 4H2O
Common Impurities:
P,S
Crystallography of Arthurite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 10.09 Å, b = 9.62 Å, c = 5.55 Å
β = 92.2°
β = 92.2°
Ratio:
a:b:c = 1.049 : 1 : 0.577
Unit Cell V:
538.32 ų (Calculated from Unit Cell)
Z:
2
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0014708 | Arthurite | Keller P, Hess H (1978) Die kristallstruktur von arthurit, CuFe2[(H2O)4|(OH)2|(AsO4)2] Neues Jahrbuch fur Mineralogie, Abhandlungen 133 291-302 | 1978 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
4.28 Å | (vvs) |
4.81 Å | (vvs) |
6.97 Å | (vvs) |
10.08 Å | (vs) |
2.801 Å | (vs) |
2.912 Å | (s) |
3.44 Å | (ms) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47d : [Arsenates, antimonates, selenates, bismuthinates] |
Type Occurrence of Arthurite
General Appearance of Type Material:
Apple-green crusts
Place of Conservation of Type Material:
The Natural History Museum, London, England, 1964,74–75 and 1964,80.
Geological Setting of Type Material:
formed by alteration of arsenopyrite or enargite.
Associated Minerals at Type Locality:
Reference:
Davis, R.J., Hey, M.H. (1964) Arthurite, a new copper-iron arsenate from Cornwall: Mineralogical Magazine: 33(266): 937-941.
Synonyms of Arthurite
Other Language Names for Arthurite
Varieties of Arthurite
Relationship of Arthurite to other Species
Member of:
Other Members of this group:
Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Cobaltarthurite | (Co,Mg)Fe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Earlshannonite | Mn2+Fe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Kunatite | CuFe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Ojuelaite | ZnFe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
UKI-2006-(PO:AlCuFeH) | Fe2+Al3+2(PO4)2(OH)2 · 4H2O | |
UM2006-27-PO:FeHZn | ZnFe3+2(PO4)2(OH)2 · 4H2O | Mon. |
Whitmoreite | Fe2+Fe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Common Associates
Associated Minerals Based on Photo Data:
52 photos of Arthurite associated with Pharmacosiderite | KFe3+4(AsO4)3(OH)4 · 6-7H2O |
40 photos of Arthurite associated with Scorodite | Fe3+AsO4 · 2H2O |
14 photos of Arthurite associated with Olivenite | Cu2(AsO4)(OH) |
11 photos of Arthurite associated with Quartz | SiO2 |
8 photos of Arthurite associated with Chenevixite | Cu2Fe3+2(AsO4)2(OH)4 |
6 photos of Arthurite associated with Bobierrite | Mg3(PO4)2 · 8H2O |
6 photos of Arthurite associated with Wavellite | Al3(PO4)2(OH,F)3 · 5H2O |
6 photos of Arthurite associated with Cuprite | Cu2O |
4 photos of Arthurite associated with Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O |
3 photos of Arthurite associated with Bariopharmacosiderite | Ba0.5Fe3+4(AsO4)3(OH)4 · 5H2O |
Related Minerals - Strunz-mindat Grouping
8.DC. | Ianbruceite | Zn2(AsO4)(OH) · 3H2O |
8.DC. | Césarferreiraite | Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O |
8.DC. | Ferrivauxite | Fe3+Al2(PO4)2(OH)3 · 5H2O |
8.DC.05 | Nissonite | Cu2Mg2(PO4)2(OH)2 · 5H2O |
8.DC.07 | Euchroite | Cu2(AsO4)(OH) · 3H2O |
8.DC.10 | Legrandite | Zn2(AsO4)(OH) · H2O |
8.DC.12 | Strashimirite | Cu8(AsO4)4(OH)4 · 5H2O |
8.DC.15 | Earlshannonite | Mn2+Fe3+2(PO4)2(OH)2 · 4H2O |
8.DC.15 | Ojuelaite | ZnFe3+2(AsO4)2(OH)2 · 4H2O |
8.DC.15 | Whitmoreite | Fe2+Fe3+2(PO4)2(OH)2 · 4H2O |
8.DC.15 | Cobaltarthurite | (Co,Mg)Fe3+2(AsO4)2(OH)2 · 4H2O |
8.DC.15 | Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O |
8.DC.15 | Kunatite | CuFe3+2(PO4)2(OH)2 · 4H2O |
8.DC.15 | UM2006-27-PO:FeHZn | ZnFe3+2(PO4)2(OH)2 · 4H2O |
8.DC.15 | UKI-2006-(PO:AlCuFeH) | Fe2+Al3+2(PO4)2(OH)2 · 4H2O |
8.DC.17 | Kleemanite | ZnAl2(PO4)2(OH)2 · 3H2O |
8.DC.20 | Bermanite | Mn2+Mn3+2(PO4)2(OH)2 · 4H2O |
8.DC.20 | Coralloite | Mn2+Mn3+2(AsO4)2(OH)2 · 4H2O |
8.DC.20 | Magnesiobermanite | MgMn3+2(PO4)2(OH)2 · 4H2O |
8.DC.22 | Kovdorskite | Mg2(PO4)(OH) · 3H2O |
8.DC.25 | Ferristrunzite | Fe3+Fe3+2(PO4)2(OH)3 · 5H2O |
8.DC.25 | Ferrostrunzite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O |
8.DC.25 | Metavauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O |
8.DC.25 | Metavivianite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O |
8.DC.25 | Strunzite | Mn2+Fe3+2(PO4)2(OH)2 · 6H2O |
8.DC.25 | Zincostrunzite | ZnFe3+2(PO4)2(OH)2 · 6.5H2O |
8.DC.27 | Beraunite | Fe3+6(PO4)4O(OH)4 · 6H2O |
8.DC.27 | Tvrdýite | Fe2+Fe3+2 Al3(PO4)4(OH)5(H2O)4 · 2H2O |
8.DC.27 | Zincoberaunite | ZnFe3+5(PO4)4(OH)5 · 6H2O |
8.DC.30 | Gordonite | MgAl2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Laueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Mangangordonite | Mn2+Al2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Paravauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Pseudolaueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Sigloite | Fe3+Al2(PO4)2(OH)3 · 7H2O |
8.DC.30 | Stewartite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Ushkovite | MgFe3+2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Ferrolaueite | Fe2+Fe3+2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Kastningite | (Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Maghrebite | MgAl2(AsO4)2(OH)2 · 8H2O |
8.DC.30 | Nordgauite | MnAl2(PO4)2(F,OH)2 · 5H2O |
8.DC.30 | Kayrobertsonite | [MnAl2(PO4)2(OH)2(H2O)4] · 2H2O |
8.DC.30 | Kummerite | Mn2+Fe3+Al(PO4)2(OH)2 · 8H2O |
8.DC.32 | Tinticite | Fe3+3(PO4)2(OH)3 · 3H2O |
8.DC.32 | Kamarizaite | Fe3+3(AsO4)2(OH)3 · 3H2O |
8.DC.35 | Vauxite | Fe2+Al2(PO4)2(OH)2 · 6H2O |
8.DC.37 | Vantasselite | Al4(PO4)3(OH)3 · 9H2O |
8.DC.40 | Cacoxenite | Fe3+24AlO6(PO4)17(OH)12 · 75H2O |
8.DC.45 | Gormanite | (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O |
8.DC.45 | Souzalite | (Mg,Fe2+)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O |
8.DC.47 | Kingite | Al3(PO4)2F2(OH) · 7H2O |
8.DC.50 | Wavellite | Al3(PO4)2(OH,F)3 · 5H2O |
8.DC.50 | Allanpringite | Fe3+3(PO4)2(OH)3 · 5H2O |
8.DC.50 | Fluorwavellite | Al3(PO4)2(OH)2F · 5H2O |
8.DC.52 | Kribergite | Al5(PO4)3(SO4)(OH)4 · 4H2O |
8.DC.55 | Mapimite | Zn2Fe3+3(AsO4)3(OH)4 · 10H2O |
8.DC.57 | Ogdensburgite | Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O |
8.DC.60 | Nevadaite | (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O |
8.DC.60 | Cloncurryite | Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O |
8.DC.62 | Kenngottite | Mn2+3Fe3+4(PO4)4(OH)6(H2O)2 |
8.DC.67 | Molinelloite | Cu(H2O)(OH)V4+O(V5+O4) |
8.DC.70 | Whitecapsite | H16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2O |
8.DC.75 | Heimite | PbCu2(AsO4)(OH)3 · 2H2O |
8.DC.80 | Lednevite | Cu[PO3(OH)] · H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Arthurite
mindat.org URL:
https://www.mindat.org/min-376.html
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References for Arthurite
Localities for Arthurite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Australia | |
| Anthony et al. (2000) +1 other reference |
Austria | |
| Hackenberg 2003 |
Chile | |
| SEM-EDS by Joy Desor |
| Samples analysed by Dr. Jochen Schlüter (Hamburg University) |
| Anthony et al. (2000) |
| maurizio dini collection - analysed ... |
Czech Republic | |
| www.researchgate.net (n.d.) +2 other references |
France | |
| Lebocey et al. (2010) |
| Queneau (n.d.) |
| Jean-Marie Claude collection +1 other reference |
Germany | |
| Walenta (1992) |
| Wittern (2001) |
| Wittern (2001) |
Greece | |
| Branko Rieck collection |
| |
Rieck (1999) | |
| |
Hungary | |
| HOM Collection-Szakáll S.-2010 |
Italy | |
| Fernando Caboni et al. (2024) |
Fernando Caboni et al. (2024) | |
| Orlandi et al. (2005) |
| Ferretti et al. (2018) |
| Ferretti et al. (2019) |
| Domenico Saccardo (2019) |
Namibia | |
| von Bezing et al. (2016) |
Portugal | |
| Schnorrer-Köhler (1991) |
Russia | |
| Pavel.M. Kartashov (n.d.) |
Spain | |
| Calvo (2015) |
| Sainz de Baranda et al. (2003) |
| Joan Vinals & Miguel Calvo (2007) |
UK (TL) | |
| Davis et al. (1964) +1 other reference |
Golley et al. (1995) +2 other references | |
| U. Kolitsch (X-ray powder diffraction) +2 other references |
| Golley et al. (1995) |
USA | |
| Waisman (1992) +1 other reference |
| The Minerals of Rhyolite Pass |
| Ameican Mineralogist +2 other references |
- (n.d.) +1 other reference | |
| Roberts et al. (1965) |
| Thorne (n.d.) |
Thorne (n.d.) | |
SEM-EDS analyzed by Kerry Day | |
Collected by and in the collection of ... | |
| Anthony et al. (2000) |
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Majuba Hill Mine, Antelope Mining District, Pershing County, Nevada, USA