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Tobelite

A valid IMA mineral species
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About TobeliteHide

Formula:
(NH4,K)Al2(AlSi3O10)(OH)2
Colour:
White, yellow-green
Lustre:
Silky, Dull, Earthy
Hardness:
2
Specific Gravity:
2.58 - 2.62
Crystal System:
Monoclinic
Name:
Named after its discovery locality, Tobe, Ehime Prefecture, Japan.
Mica Group.

1M, 2M2 polytypes.


Unique IdentifiersHide

Mindat ID:
3984
Long-form identifier:
mindat:1:1:3984:6
GUID
(UUID V4):
30265bea-4673-4e40-b0f8-464482a54885

IMA Classification of TobeliteHide

Approved
IMA Formula:
(NH4)Al2(Si3Al)O10(OH)2
First published:
1982

Classification of TobeliteHide

9.EC.15

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.2.2a.7

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
16.5.5

16 : Silicates Containing Aluminum and other Metals
5 : Aluminosilicates of Cs, NH4 and Cu

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
TblIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
TblWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of TobeliteHide

Silky, Dull, Earthy
Transparency:
Translucent
Colour:
White, yellow-green
Hardness:
Tenacity:
Waxy
Cleavage:
Perfect
{001}
Density:
2.58 - 2.62 g/cm3 (Measured)    2.617 g/cm3 (Calculated)

Optical Data of TobeliteHide

Type:
Biaxial (-)
RI values:
nα = 1.555 - 1.560 nβ = 1.575 - 1.587 nγ = 1.581 - 1.595
2V:
Measured: 28° , Calculated: 28° to 30°
Max Birefringence:
δ = 0.026 - 0.035
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
weak

Chemistry of TobeliteHide

Mindat Formula:
(NH4,K)Al2(AlSi3O10)(OH)2
Common Impurities:
Ti,Fe,Mg,Na,H2O

Crystallography of TobeliteHide

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Tobelite-1MTobelite-2M2
  
Monoclinic Monoclinic 
2/m - Prismatic2/m - Prismatic
B2/m B2/b
C2/m C2/c
a = 5.219(4) Å, b = 8.986(3) Å, c = 10.447(2) Å
β = 101.31(1)°
a = 9.024(1) Å, b = 5.2055(6) Å, c = 20.825(3) Å
β = 99.995(8)°
a:b:c = 0.581 : 1 : 1.163a:b:c = 1.734 : 1 : 4.001
V 480.43 ų
(Calculated from Unit Cell)
V 963.40 ų
(Calculated from Unit Cell)
 4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0019255TobeliteMesto E, Scordari F, Lacalamita M, Schingaro E (2012) Tobelite and NH4+ -rich muscovite single crystals from Ordovician Armorican sandstones (Brittany, France): Structure and crystal chemistry American Mineralogist 97 1460-14682012Ordovician Armorican sandstones, Brittany, France0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.24 Å(100)
5.12 Å(70)
4.486 Å(70)
3.408 Å(60)
2.566 Å(45)
3.103 Å(35)
4.360 Å(30)
Comments:
1M polytype

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 5: Initiation of plate tectonics<3.5-2.5
40 : Regional metamorphism (greenschist, amphibolite, granulite facies)
Stage 7: Great Oxidation Event<2.4
46 : Near-surface hydrothermal alteration of minerals (see also #22)

Type Occurrence of TobeliteHide

General Appearance of Type Material:
Aggregates of minute flakes (a few microns) in a groundmass or replacing feldspar and biotite phenocrysts, and occasionally forms lamellar crystals up to 0.2 mm.
Place of Conservation of Type Material:
National Science Museum, Tokyo, Japan, M23773.
Geological Setting of Type Material:
1) Hydrothermally altered biotite-andesite dyke 2) Hydrothermal alteration product of Cretaceous rhyolitic tuff
Associated Minerals at Type Locality:
Reference:
Higashi, S. (1982) Tobelite, a new ammonium dioctahedral mica. Mineralogical Journal: 11: 138-146.

Other Language Names for TobeliteHide

Relationship of Tobelite to other SpeciesHide

Other Members of this group:
BoromuscoviteKAl2(BSi3O10)(OH)2Mon. 2/m
Celadonite SubgroupA subgroup of the dioctahedral mica group.
ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
GlauconiteK0.60-0.85(Fe3+,Mg,Al)2(Si,Al)4O10](OH)2
MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
Natro-glauconite(Na,K)(Fe3+,Al,Mg)2((Si,Al)4O10)(OH)2
ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2Mon. 2/m : B2/b

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Tobelite associated with GalenaPbS
1 photo of Tobelite associated with QuartzSiO2

Related Minerals - Strunz-mindat GroupingHide

9.EC.BalestraiteKLi2V5+Si4O12Mon. 2 : B2
9.EC.MeifuiteKFe6(Si7Al)O19(OH)4Cl2Tric. 1 : P1
9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.05WillemseiteNi3Si4O10(OH)2Mon.
9.EC.9.EC.VoloshiniteRb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon. 2/m
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.10LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m : B2/b
9.EC.10FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m : B2/m
9.EC.10ManganiceladoniteK(MgMn3+◻)(Si4O10)(OH)2Mon.
9.EC.10GarmiteCsLiMg2(Si4O10)F2Mon.
9.EC.10GorbunoviteCsLi2(Ti,Fe)Si4O10(F,OH,O)2Mon.
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon. 2/m
9.EC.15CeladoniteK(MgFe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15AluminoceladoniteK(MgAl◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroaluminoceladoniteK(Fe2+Al◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15FerroceladoniteK(Fe2+Fe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(MgCr◻)(Si4O10)(OH)2Mon. 2 : B2
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.15Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15UM1988-22-SiO:AlCaFFeHKLiMgKLiMgAl2Si3O10F2Mon.
9.EC.15KreiteriteCsLi2Fe3+(Si4O10)F2Mon.
9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric. 1 : P1
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2Mon. 2 : B2
9.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2Mon. 2/m : B2/m
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
9.EC.20Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20ShirokshiniteK(NaMg2)(Si4O10)F2Mon. 2/m : B2/m
9.EC.20ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20FluorophlogopiteKMg3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20UM2004-49-SiO:AlCsFHKLi(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m : B2/m
9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.20Chloroferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2
9.EC.22PimeliteNi3Si4O10(OH)2 ¡ 4H2OHex.
9.EC.30Chlorophaeite(Ca,Mg,Fe)2Fe2Si4O13 ¡ 10H2O
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m : B2/b
9.EC.35BityiteCaLiAl2(AlBeSi2O10)(OH)2Mon. 2/m : B2/b
9.EC.35ClintoniteCaAlMg2(SiAl3O10)(OH)2Mon. 2/m : B2/m
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon. 2/m : B2/m
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon. 2/m : B2/m
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m : B2/m
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m : B2/m
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 ¡ nH2OMon. 2/m : B2/m
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 ¡ 27H2O (?)Orth.
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 ¡ nH2OMon. 2/m : B2/m
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 ¡ nH2OMon. 2/m : B2/m
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 ¡ 4H2OMon.
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 ¡ 3H2OMon.
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon. 2/m : B2/m
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 ¡ nH2OMon.
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 ¡ 4H2OMon.
9.EC.45SpadaiteMgSiO2(OH)2 ¡ H2O (?)
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
9.EC.45SwineforditeLi(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 ¡ nH2OMon. 2/m : B2/m
9.EC.45ZincsiliteZn3Si4O10(OH)2 ¡ 4H2O (?)Mon.
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 ¡ 4H2OMon.
9.EC.45HanjiangiteBa2CaV3+Al(H2AlSi3O12)(CO3)2FMon. 2 : B2
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 ¡ 8H2OMon. 2/m
9.EC.52Tarasovitenear NaKAl11Si13O40(OH)9 ¡ 3H2O
9.EC.55Baileychlore(Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8Tric. 1
9.EC.55Chamosite(Fe2+)5Al(Si,Al)4O10(OH,O)8Mon. 2/m : B2/m
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Cookeite(LiAl4◻)[AlSi3O10](OH)8Mon. 2/m
9.EC.55FranklinfurnaceiteCa2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 : B2
9.EC.55Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8Orth.
9.EC.55Nimite(Ni,Mg,Al)6((Si,Al)4O10)(OH)8Mon. 2/m : B2/m
9.EC.55Orthochamosite(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
9.EC.55SudoiteMg2Al3(Si3Al)O10)(OH)8Mon. 2/m : B2/m
9.EC.55DonbassiteAl4.33(Si3Al)O10(OH)8Mon. 2 : B2
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
9.EC.55Borocookeite(LiAl4◻)[BSi3O10](OH)8Mon. m : Bb
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 ¡ 4H2OMon.
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 ¡ nH2OOrth.
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 ¡ nH2OMon. 2/m : B2/m
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 ¡ 2H2OMon.
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon. 2/m : B2/m
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 ¡ 5H2OMon. 2 : B2
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 ¡ 3.5 H2OMon.
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m (3 2/m) : P3 1m
9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 ¡ nH2OMon.
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon. 2 : P21
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 ¡ nH2OMon.
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TobeliteHide

References for TobeliteHide

Reference List:

Localities for TobeliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
China
 
  • Chongqing
Dai et al. (2017)
  • Guizhou
    • Zunyi
      • Zheng'an County
Li +6 other references
  • Shanxi
    • Jincheng
Zhang et al. (2024)
France
 
  • Pays de la Loire
    • Loire-Atlantique
      • Châteaubriant-Ancenis
        • Saint-Aubin-des-Châteaux
Capitani +6 other references
Japan (TL)
 
  • Ehime Prefecture
    • Iyo district
      • Tobe-cho
Higashi (1982)
  • Hiroshima Prefecture
    • Kamo District
Min.Journ.Japan (1982) +1 other reference
Poland
 
  • Silesian Voivodeship
    • Rybnik County
      • Gmina Czerwionka-Leszczyny
Parafiniuk et al. (2009)
    • Wodzisław County
      • Radlin
Łukasz Kruszewski (2012)
      • Rydułtowy
        • ROW Ruch Rydułtowy Mine
Kruszewski et al. (2019)
Ukraine
 
  • Zhytomyr Oblast
    • Zhytomyr Raion
      • Khoroshiv Raion (Volodarsk-Volynskii)
Popov (2023)
USA
 
  • Utah
    • Tooele County
Clays and Clay Minerals
Vietnam
 
  • Quảng Ninh Province
    • Cam Pha Coalfield
Nguyen et al. (2022)
 
Mineral and/or Locality  
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