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Chenite

A valid IMA mineral species
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About CheniteHide

Formula:
Pb4Cu(SO4)2(OH)6
Colour:
Sky bkue, pale blue
Lustre:
Adamantine, Vitreous, Resinous
Hardness:
Specific Gravity:
5.98
Crystal System:
Triclinic
Name:
Named in honor of Tzong Tzy Chen (b. 1942), mineralogist with the Canada Centre for Mineral and Energy Technology (CANMET), Ottawa, Ontario, Canada, for his contributions to mineralogy.

Unique IdentifiersHide

Mindat ID:
987
Long-form identifier:
mindat:1:1:987:6
GUID
(UUID V4):
f6199c6e-6537-42d9-b2ea-6eca0c8384a9

IMA Classification of CheniteHide

Approved
IMA Formula:
CuPb4(SO4)2(OH)6
Approval year:
1983
First published:
1986

Classification of CheniteHide

7.BC.70

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations
30.1.16.1

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p>2:1
25.7.8

25 : Sulphates
7 : Sulphates of Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
CheIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CheniteHide

Adamantine, Vitreous, Resinous
Transparency:
Transparent, Translucent
Colour:
Sky bkue, pale blue
Streak:
Pale blue
Hardness:
2½ on Mohs scale
Hardness Data:
Measured
Cleavage:
Distinct/Good
On {100}; traces of another cleavage on {001}.
Density:
5.98(2) g/cm3 (Measured)    6.044 g/cm3 (Calculated)

Optical Data of CheniteHide

Type:
Biaxial (-)
RI values:
nα = 1.871 nβ = 1.909 nγ = 1.927
2V:
Measured: 67° (1), Calculated: 66°
Max Birefringence:
δ = 0.056
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
Very strong, r >> v.
Pleochroism:
Weak

Chemistry of CheniteHide

Mindat Formula:
Pb4Cu(SO4)2(OH)6

Crystallography of CheniteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 5.791(1) Å, b = 7.940(1) Å, c = 7.976(1) Å
α = 112.02(1)°, β = 97.73(1)°, γ = 100.45(1)°
Ratio:
a:b:c = 0.729 : 1 : 1.005
Unit Cell V:
326.00 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Tabular, pointed, rich in faces. Forms include dominant {132} and {221}, less dominant {100}. Also {253}, {154}, {110}, {010}, {001}, {101}, {111}, {112}.
Twinning:
Twinning observed.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014826CheniteHess H, Keller P, Riffel H (1988) The crystal structure of chenite, Pb4Cu(OH)6(SO4)2 Neues Jahrbuch fur Mineralogie, Monatshefte 1988 259-2641988Leadhills, Scotland0293
0015326CheniteMereiter K (2009) Chenite, Pb4Cu(SO4)2(OH)6, from Susanna mine, Leadhills, Scotland. Private communication 0 0-02009Susanna mine, Leadhills, Scotland0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.55 Å(70)
4.32 Å(60)
3.97 Å(30)
3.60 Å(100)
3.41 Å(90)
3.30 Å(50)
3.00 Å(50)
2.87 Å(40)
2.80 Å(70)
2.71 Å(40)
2.53 Å(30)
2.21 Å(40)
2.07 Å(60)
1.949 Å(40)
1.914 Å(30)
1.838 Å(40)
1.778 Å(50)
1.750 Å(30)
1.704 Å(30)
1.582 Å(30)
Comments:
Data from type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]

Type Occurrence of CheniteHide

General Appearance of Type Material:
Crystals to 1 x 0.5 x 0.2 mm in size, and a twinned crystal 1.5 mm in length.
Place of Conservation of Type Material:
Institut für Mineralogie und Kristallchemie, Universität Stuttgart, Stuttgart, Germany, number NM 14 (holotype).
National Museum of Natural History, Washington, D.C., USA, number 160384 (cotype).
Archiv der Universität Stuttgart, Stuttgart, Germany, number TM-83.69 (part of the holotype).
Royal Ontario Museum, Toronto, Ontario, Canada.
Institut fUr Mineralogie, Kristallographie und Strukturchemie der Technischen Universitat Wien, Wien, Austria.
Geological Setting of Type Material:
Secondary mineral in a lead-copper deposit.
Associated Minerals at Type Locality:

Synonyms of CheniteHide

Other Language Names for CheniteHide

German:Chenit
Russian:Ченит
Spanish:Chenita

Relationship of Chenite to other SpeciesHide

Other Members of this group:
FranksousaitePbCu(Se6+O4)(OH)2Mon. 2/m : P21/m
LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon. 2/m : P21/m

Common AssociatesHide

Associated Minerals Based on Photo Data:
10 photos of Chenite associated with ElyitePb4Cu(SO4)O2(OH)4 · H2O
7 photos of Chenite associated with LanarkitePb2(SO4)O
4 photos of Chenite associated with LeadhillitePb4(CO3)2(SO4)(OH)2
4 photos of Chenite associated with CaledonitePb5Cu2(SO4)3(CO3)(OH)6
3 photos of Chenite associated with CerussitePbCO3
2 photos of Chenite associated with MattheddleitePb5(SiO4)1.5(SO4)1.5(Cl,OH)
2 photos of Chenite associated with LinaritePbCu(SO4)(OH)2
1 photo of Chenite associated with CovelliteCuS
1 photo of Chenite associated with BrochantiteCu4(SO4)(OH)6
1 photo of Chenite associated with SteverustitePb2+5(OH)5[Cu+(S6+O3S2-)3](H2O)2

Related Minerals - Strunz-mindat GroupingHide

7.BC.Adranosite-(Fe)(NH4)4NaFe3+2(SO4)4Cl(OH)2Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.BC.Adranosite(NH4)4NaAl2(SO4)4Cl(OH)2Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.BC.D'Ansite-(Mn)Na21Mn2+(SO4)10Cl3Iso. 4 3m : I4 3d
7.BC.AgaitePb3CuTeO5(OH)2(CO3) Orth. mm2 : Pca21
7.BC.D'Ansite-(Fe)Na21Fe2+(SO4)10Cl3Iso. 4 3m : I4 3d
7.BC.Acmonidesite(NH4,K,Pb)8NaFe2+4(SO4)5Cl8Orth. 2 2 2 : C2 2 21
7.BC.BackitePb2AlTeO6ClTrig. 3 2 : P3 1 2
7.BC.HagstromitePb8Cu2+(Te6+O6)2(CO3)Cl4Orth. mmm (2/m 2/m 2/m) : Ibam
7.BC.WildcatiteCaFe3+Te6+O5(OH)Trig. 3m (3 2/m) : P3 1m
7.BC.FranksousaitePbCu(Se6+O4)(OH)2Mon. 2/m : P21/m
7.BC.ZincochenitePb4Zn(OH)6(SO4)2Tric. 1 : P1
7.BC.ViskontitePb5Cu2(SO4)3(SeO3)(OH)6Orth. mm2 : Pmn21
7.BC.05D'AnsiteNa21Mg(SO4)10Cl3Iso. 4 3m : I4 3m
7.BC.07ApateliteFe3(SO4)2(OH)5 · 0.5H2O
7.BC.07Unnamed (Ba-Fe Vanadate)Ba, Fe, V, O, H
7.BC.10AluniteKAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Ammonioalunite(NH4)Al3(SO4)2(OH)6Trig.
7.BC.10Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10DorallchariteTlFe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10HuangiteCa0.5Al3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10JarositeKFe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Natroalunite-2c(Na,Ca0.5,K)Al3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10NatroaluniteNaAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10PlumbojarositePb0.5Fe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10WalthieriteBa0.5Al3(SO4)2(OH)6Trig.
7.BC.10Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.15Ye'elimiteCa4Al6(SO4)O12Iso. 4 3 2 : I41 3 2
7.BC.20AtlasoviteK(BiO)Cu6Fe3+(SO4)5O3ClTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.20NabokoiteKCu7(SO4)5(Te4+O3)OClTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.20PuniniteNa2Cu3O(SO4)3Mon. 2/m : B2/b
7.BC.25ChlorothioniteK2Cu(SO4)Cl2Orth. mmm (2/m 2/m 2/m) : Pnma
7.BC.30EuchlorineKNaCu3(SO4)3OMon. 2/m
7.BC.30FedotoviteK2Cu3(SO4)3OMon. 2/m : B2/b
7.BC.35KamchatkiteKCu3(SO4)2OClOrth. mmm (2/m 2/m 2/m) : Pnma
7.BC.40PiypiteK4Cu4O2(SO4)4 · (Na,Cu)ClTet. 4 : I4
7.BC.45KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2Mon. 2
7.BC.45AlumoklyuchevskiteK3Cu3(Al,Fe3+)(SO4)4O2Tric. 1 : P1
7.BC.45BelousoviteKZn(SO4)ClMon. 2/m : P21/b
7.BC.47MülleritePb2Fe3+(Te6+O6)ClTrig. 3 2 : P31 1 2
7.BC.50CaledonitePb5Cu2(SO4)3(CO3)(OH)6Orth. mm2 : Pmn21
7.BC.50ElasmochloiteNa3Cu6BiO4(SO4)5Mon. 2/m
7.BC.52Eleomelanite(K2Pb)Cu4O2(SO4)4Mon. 2/m
7.BC.55WherryitePb7Cu2(SO4)4(SiO4)2(OH)2Mon. 2/m : B2/m
7.BC.55FalgariteK4(VO)3(SO4)5Mon. 2/m : B2/b
7.BC.57KrasheninnikoviteKNa2CaMg(SO4)3FHex. 6/mmm (6/m 2/m 2/m) : P63/mcm
7.BC.60MammothitePb6Cu4AlSb5+O2(OH)16Cl4(SO4)2Mon. 2 : B2
7.BC.60WulffiteK3NaCu4O2(SO4)4Orth. mm2
7.BC.60ParawulffiteK5Na3Cu8O4(SO4)8Mon. 2/m : P2/b
7.BC.62ShuvaloviteK2(Ca2Na)(SO4)3FOrth. mmm (2/m 2/m 2/m) : Pnma
7.BC.65LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
7.BC.65SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon. 2/m : P21/m
7.BC.65MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
7.BC.65Therasiaite(NH4)3KNa2Fe2+Fe3+(SO4)3Cl5Mon. m : Bb
7.BC.65SaccoiteCa2Mn3+2F(OH)8 · 0.5(SO4)Tet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.75KrivovichevitePb3Al(OH)6(SO4)(OH)Trig. 3m : R3c
7.BC.80AnhydrokainiteKMg(SO4)Cl

Fluorescence of CheniteHide

Not fluorescent.

Other InformationHide

Notes:
Does NOT effervesce in dilute hydrochloric acid, allowing it to be distinguished from caledonite.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CheniteHide

References for CheniteHide

Localities for CheniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • Río Negro Province
    • Valcheta Department
      • San Martin pluton
Herrmann et al. (2007)
Austria
 
  • Carinthia
    • Sankt Veit an der Glan District
      • Guttaring
        • Waitschach
Kolitsch et al. (2013)
      • Hüttenberg
        • Sankt Martin am Silberberg
Blaß et al. (1997)
  • Styria
    • Liezen District
      • Öblarn
        • Walchen
50. +1 other reference
Belgium
 
  • Flanders
    • Limburg
      • Dilsen-Stokkem
        • Rotem
  • Wallonia
    • Namur
      • Andenne
        • Seilles
China
 
  • Anhui
    • Hefei
      • Lujiang Co.
LIU et al. (2021)
France
 
  • Auvergne-Rhône-Alpes
    • Loire
      • Roanne
        • Le Crozet
Vernay (1997) +1 other reference
    • Rhône
      • Villefranche-sur-Saône
        • Poule-les-Écharmeaux
Chollet Pascal Collection
  • Brittany
    • Finistère
      • Châteaulin
        • Poullaouen
Germain C. et al. (1990)
  • Occitanie
    • Aude
      • Narbonne
        • Padern
Favreau et al. (2003)
    • Aveyron
      • Villefranche-de-Rouergue
        • Asprières
Lesénéchal.T. & Desor (04/21)
    • Lozère
      • Florac
        • Vialas
Georges Favreau collection
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Breisgau-Hochschwarzwald
        • Badenweiler
          • Badenweiler Pb mining district
            • Sehringen
Weiß (1990)
        • Müllheim
50. (in German) +1 other reference
      • Emmendingen
        • Freiamt
Walenta (1992)
      • Waldshut
        • St Blasien
Walenta (1992)
  • Lower Saxony
    • Goslar District
      • Clausthal-Zellerfeld
        • Oberschulenberg
Schnorrer-Köhler (1991)
"Lithothek" collection of the ...
inCollection Gerhard Niceus
      • Goslar
- (n.d.)
      • Langelsheim
        • Astfeld
        • Lautenthal
  • North Rhine-Westphalia
    • Arnsberg
      • Hochsauerlandkreis
        • Meschede
Weiss: "Mineralienfundstellen et al. (Munich)
        • Sundern
          • Bönkhausen
Wittern (2001)
    • Cologne
      • Euskirchen
        • Kall
Blaß et al. (1995)
  • Rhineland-Palatinate
    • Neuwied
      • Unkel
        • Rheinbreitbach
Krause (1991)
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Lavrion mining district
          • Lophos
            • Agrileza mines
90. +1 other reference
Italy
 
  • Tuscany
    • Grosseto Province
      • Massa Marittima
        • Valpiana - Castello della Marsiliana area slag sites
Jansen et al. (1998)
    • Livorno Province
      • Campiglia Marittima
Jansen et al. (1998)
      • Piombino
Jansen et al. (1998)
      • Sassetta
        • Canina Valley
Jansen et al. (1998)
Japan
 
  • Shimane Prefecture
    • Ōda City
Akasaka (2007)
Spain
 
  • Andalusia
    • Jaén
      • Linares
Calvo Rebollar et al. (2022)
  • Catalonia
    • Tarragona
      • Baix Camp
        • Alforja
Joan Abella i Creus (Joanabellacreus@gmail.com)
UK
 
  • England
    • Cornwall
      • Porthleven
G.Curtis collection
    • County Durham
      • Healeyfield
Norman Wilson collection +1 other reference
    • Cumbria
      • Allerdale
        • Caldbeck
          • Deer Hills
Green et al. (2008)
Green et al. (1996) +1 other reference
          • Roughton Gill
Green et al. (2008)
Green et al. (2008)
      • Eden
        • Mungrisdale
Briscoe et al. (2008)
  • Scotland
    • Dumfries and Galloway
      • Wanlockhead
Green (1987) +2 other references
S. Rust collection.
S Rust collection
S.Rust Collection
    • South Lanarkshire
      • Leadhills
Day (1999)
Paar et al. (1986)
        • Wanlock Dod
Steve Rust collection
S.Rust Collection
  • Wales
    • Ceredigion
      • Ceulanymaesmawr
        • Tal-y-bont
S Rust
Rust (1997)
      • Trefeirig
        • Pen-bont Rhydybeddau
Rust (1994)
USA
 
  • North Carolina
    • Haywood County
      • Waterville Lake
A. Kampf or C. Emproto PXRD and/EDS ...
 
Mineral and/or Locality  
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