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Phosphohedyphane

A valid IMA mineral species

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Photos of Phosphohedyphane (150)

Phosphohedyphane Gallery Search Photos of Phosphohedyphane

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Phosphohedyphane

Preguiça Mine, Sobral da Adiça, Moura, Beja, Portugal

Phosphohedyphane

Whytes Cleuch, Wanlockhead, Dumfries and Galloway, Scotland, UK

Phosphohedyphane, etc.

Monte Cavaglione, Curagnata, Cairo Montenotte, Savona Province, Liguria, Italy

Phosphohedyphane

Preguiça Mine, Sobral da Adiça, Moura, Beja, Portugal

Phosphohedyphane

Whytes Cleuch, Wanlockhead, Dumfries and Galloway, Scotland, UK

Phosphohedyphane, etc.

Monte Cavaglione, Curagnata, Cairo Montenotte, Savona Province, Liguria, Italy

Phosphohedyphane

Preguiça Mine, Sobral da Adiça, Moura, Beja, Portugal

Phosphohedyphane

Whytes Cleuch, Wanlockhead, Dumfries and Galloway, Scotland, UK

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About PhosphohedyphaneHide

Formula:

Ca₂Pb₃(PO₄)₃Cl

Colour:

Colourless

Lustre:

Vitreous, Greasy

Hardness:

Specific Gravity:

5.92 (Calculated)

Crystal System:

Hexagonal

Member of:

Hedyphane Group > Apatite Supergroup

Name:

For its phosphate content and relationship with hedyphane.

Type Locality:

ⓘ Capitana Mine, Copiapó, Copiapó Province, Atacama, Chile

Isostructural with:

Hedyphane

The phosphate analogue of hedyphane. The Pb3Ca2 analogue of pyromorphite and chlorapatite. The Cl analogue of fluorphosphohedyphane.

An unnamed OH analogue is IMA-coded as UM2002-53-PO:CaHPb.

Pb and Ca atoms are ordered on two different sites in the crystal structure.

Specimens from numerous localities worldwide have previously been labelled "calcian pyromorphite", and some of them may be identical with this species.

Unique IdentifiersHide

Mindat ID:

27608

Long-form identifier:

mindat:1:1:27608:9

GUID
(UUID V4):

b454a0ae-60df-4238-89e5-91fad105c7ed

IMA Classification of PhosphohedyphaneHide

IMA status:

Approved

Approval year:

2005

First published:

2006

Classification of PhosphohedyphaneHide

Strunz-mindat (2024):

8.BN.05

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H₂O
N : With only large cations, (OH, etc.):RO₄ = 0.33:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Phdy	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PhosphohedyphaneHide

Lustre:

Vitreous, Greasy

Transparency:

Transparent

Colour:

Colourless

Streak:

White

Hardness:

4 on Mohs scale

Hardness Data:

Measured

Tenacity:

Brittle

Cleavage:

None Observed

Fracture:

Sub-Conchoidal

Density:

5.92 g/cm³ (Calculated)

Optical Data of PhosphohedyphaneHide

Type:

Uniaxial (-)

RI values:

n_ω = 1.935 n_ε = 1.928

Max Birefringence:

δ = 0.007

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

Very High

Chemistry of PhosphohedyphaneHide

Mindat Formula:

Ca₂Pb₃(PO₄)₃Cl

Elements listed:

Ca, Cl, O, P, Pb - search for minerals with similar chemistry

Crystallography of PhosphohedyphaneHide

Crystal System:

Hexagonal

Class (H-M):

6/m - Dipyramidal

Space Group:

P6₃/m

Cell Parameters:

a = 9.857 Å, c = 7.13 Å

Ratio:

a:c = 1 : 0.723

Unit Cell V:

599.9 Å³

Morphology:

Forms observed are {100} and {101} good, {411} poor, and {10.0.1} and {20.0.1} (approx.)

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0004255	Phosphohedyphane	Kampf A R, Steele I M, Jenkins R A (2006) Phosphohedyphane, Ca2Pb3(PO4)3Cl, the phosphate analogue of hedyphane: Description and crystal structure American Mineralogist 91 1909-1917		2006	Capitana mine, Copiapo, Atacama Province, Chile	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Phosphohedyphane'
loop_
_publ_author_name
'Kampf A R'
'Steele I M'
'Jenkins R A'
_journal_name_full 'American Mineralogist'
_journal_volume 91 
_journal_year 2006
_journal_page_first 1909
_journal_page_last 1917
_publ_section_title
;
 Phosphohedyphane, Ca2Pb3(PO4)3Cl, the phosphate analogue of hedyphane:
 Description and crystal structure
;
_database_code_amcsd 0004255
_chemical_compound_source 'Capitana mine, Copiapo, Atacama Province, Chile'
_chemical_formula_sum 'Ca1.838 Pb3.162 (P2.721 As.279) O12 Cl'
_cell_length_a 9.857
_cell_length_b 9.857
_cell_length_c 7.130
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 599.943
_exptl_crystal_density_diffrn      5.876
_symmetry_space_group_name_H-M 'P 63/m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x+y,-x,1/2-z'
  'x-y,x,1/2+z'
  'y,-x+y,-z'
  '-y,x-y,z'
  'x,y,1/2-z'
  '-x,-y,1/2+z'
  'x-y,x,-z'
  '-x+y,-x,z'
  '-y,x-y,1/2-z'
  'y,-x+y,1/2+z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Ca1   0.33333   0.66667   0.00680   0.91900   0.01400
Pb1   0.33333   0.66667   0.00680   0.08100   0.01400
Pb2   0.25740   0.00830   0.25000   1.00000   0.01500
P   0.41920   0.38680   0.25000   0.90700   0.01000
As   0.41920   0.38680   0.25000   0.09300   0.01000
O1   0.36770   0.50990   0.25000   1.00000   0.01600
O2   0.60290   0.46810   0.25000   1.00000   0.01700
O3   0.36400   0.28010   0.07610   1.00000   0.02600
Cl   0.00000   0.00000   0.00000   1.00000   0.01700
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Ca1 0.01400 0.01400 0.01500 0.00700 0.00000 0.00000
Pb1 0.01400 0.01400 0.01500 0.00700 0.00000 0.00000
Pb2 0.01000 0.01300 0.02000 0.00500 0.00000 0.00000
P 0.00800 0.00700 0.01400 0.00400 0.00000 0.00000
As 0.00800 0.00700 0.01400 0.00400 0.00000 0.00000
O1 0.01500 0.01200 0.02500 0.01000 0.00000 0.00000
O2 0.00500 0.00700 0.03800 0.00200 0.00000 0.00000
O3 0.03700 0.02500 0.02500 0.02200 -0.02000 -0.01300
Cl 0.01500 0.01500 0.01900 0.00800 0.00000 0.00000

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
8.538 Å	(20)
4.054 Å	(60)
3.565 Å	(30)
2.942 Å	(100)
2.882 Å	(30)
2.139 Å	(35)
1.918 Å	(25)
1.890 Å	(25)

Comments:

Capitana Mine, Copiapó Province, Chile. Data from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 7: Great Oxidation Event	<2.4
45b : [Other oxidized fumarolic minerals]
47c : [Carbonates, phosphates, borates, nitrates]
47g : [Halogen-bearing surface weathering minerals]

Type Occurrence of PhosphohedyphaneHide

Type Locality:

ⓘ Capitana Mine, Copiapó, Copiapó Province, Atacama, Chile

General Appearance of Type Material:

Transparent, colourless, tapering hexagonal prisms, as individuals up to about 0.5 mm in length and 0.1 mm in diameter, commonly doubly terminated; often in subparallel intergrowths and irregular clusters.

Place of Conservation of Type Material:

Natural History Museum of Los Angeles County, Los Angeles, California, USA, number 55429 (holotype).

Geological Setting of Type Material:

Secondary mineral in the oxidized zone of a Cu-Pb-Ag deposit.

Associated Minerals at Type Locality:

Quartz

Duftite

Bayldonite

Synonyms of PhosphohedyphaneHide

IMA2005-026

Polysphaerite

Other Language Names for PhosphohedyphaneHide

German:Phosphohedyphan

Japanese:燐ヘディフェン

Spanish:Fosfohedifana

Relationship of Phosphohedyphane to other SpeciesHide

Member of:

Hedyphane Group > Apatite Supergroup

Other Members of this group:

Aiolosite	Na₄Bi(SO₄)₃Cl	Hex. 6/m : P6₃/m
Caracolite	Na₃Pb₂(SO₄)₃Cl	Mon. 2/m : P2₁/m
Cesanite	Na₃Ca₂(SO₄)₃(OH)	Hex. 6 : P6
Fluorphosphohedyphane	Ca₂Pb₃(PO₄)₃F	Hex. 6/m : P6₃/m
Fluorsigaiite	Ca₂Sr₃(PO₄)₃F	Hex. 6/m : P6₃/m
Hedyphane	Ca₂Pb₃(AsO₄)₃Cl	Hex. 6/mmm (6/m 2/m 2/m) : P6₃/mmc
Hydroxylhedyphane	Ca₂Pb₃(AsO₄)₃(OH)	Trig. 3 : P3
Miyahisaite	(Sr,Ca)₂Ba₃(PO₄)₃F	Hex. 6/m : P6₃/m
Morelandite	Ca₂Ba₃(AsO₄)₃Cl	Hex.
Parafiniukite	Ca₂Mn₃(PO₄)₃Cl	Hex. 6/m : P6₃/m
UM2002-53-PO:CaHPb	Ca₂Pb₃(PO₄)₃(OH,Cl,F)

Common AssociatesHide

Associated Minerals Based on Photo Data:

57 photos of Phosphohedyphane associated with Vanadinite	Pb₅(VO₄)₃Cl
40 photos of Phosphohedyphane associated with Quartz	SiO₂
38 photos of Phosphohedyphane associated with Mottramite	PbCu(VO₄)(OH)
33 photos of Phosphohedyphane associated with Wulfenite	Pb(MoO₄)
27 photos of Phosphohedyphane associated with Descloizite	PbZn(VO₄)(OH)
20 photos of Phosphohedyphane associated with Cerussite	PbCO₃
18 photos of Phosphohedyphane associated with Goethite	α-Fe³⁺O(OH)
11 photos of Phosphohedyphane associated with Calcium-bearing Pyromorphite	(Pb,Ca)₅(PO₄)₃Cl
11 photos of Phosphohedyphane associated with Willemite	Zn₂SiO₄
10 photos of Phosphohedyphane associated with Hematite	Fe₂O₃

Related Minerals - Strunz-mindat Grouping Hide

8.BN.	Aradite	BaCa₆[(SiO₄)(VO₄)](VO₄)₂F	Trig. 3m : R3m
8.BN.	Magganasite	CuFe³⁺₃O(AsO₄)₃	Tric. 1 : P1
8.BN.	Fluorpyromorphite	Pb₅(PO₄)₃F	Hex. 6/m : P6₃/m
8.BN.	Fluorsigaiite	Ca₂Sr₃(PO₄)₃F	Hex. 6/m : P6₃/m
8.BN.	Fluoralforsite	Ba₅(PO₄)₃F	Hex. 6/m : P6/m
8.BN.05	Alforsite	Ba₅(PO₄)₃Cl	Hex. 6/m : P6₃/m
8.BN.05	Belovite-(Ce)	NaCeSr₃(PO₄)₃F	Trig. 3 : P3
8.BN.05	Chlorapatite	Ca₅(PO₄)₃Cl	Hex. 6/m : P6₃/m
8.BN.05	Mimetite-M	Pb₅(AsO₄)₃Cl	Mon. 2/m : P2₁/b
8.BN.05	Johnbaumite-M	Ca₅(AsO₄)₃OH	Mon. 2/m : P2₁/m
8.BN.05	Fluorapatite	Ca₅(PO₄)₃F	Hex. 6/m : P6₃/m
8.BN.05	Hedyphane	Ca₂Pb₃(AsO₄)₃Cl	Hex. 6/mmm (6/m 2/m 2/m) : P6₃/mmc
8.BN.05	Hydroxylapatite	Ca₅(PO₄)₃(OH)	Hex. 6/m : P6₃/m
8.BN.05	Johnbaumite	Ca₅(AsO₄)₃(OH)	Hex. 6/m : P6₃/m
8.BN.05	Mimetite	Pb₅(AsO₄)₃Cl	Hex. 6/m : P6₃/m
8.BN.05	Morelandite	Ca₂Ba₃(AsO₄)₃Cl	Hex.
8.BN.05	Oxypyromorphite	Pb₁₀(PO₄)₆O
8.BN.05	Pyromorphite	Pb₅(PO₄)₃Cl	Hex. 6/m : P6₃/m
8.BN.05	Fluorstrophite	SrCaSr₃(PO₄)₃F	Hex. 6/m : P6₃/m
8.BN.05	Svabite	Ca₅(AsO₄)₃F	Hex. 6/mmm (6/m 2/m 2/m) : P6₃/mmc
8.BN.05	Turneaureite	Ca₅(AsO₄)₃Cl	Hex. 6/m : P6₃/m
8.BN.05	Vanadinite	Pb₅(VO₄)₃Cl	Hex. 6/m : P6₃/m
8.BN.05	Belovite-(La)	NaLaSr₃(PO₄)₃F	Trig. 3 : P3
8.BN.05	Deloneite	(Na_0.5REE_0.25Ca_0.25)(Ca_0.75REE_0.25)Sr_1.5(CaNa_0.25REE_0.25)(PO₄)₃F_0.5(OH)_0.5	Trig. 3 : P3
8.BN.05	Fluorcaphite	SrCaCa₃(PO₄)₃F	Hex. 6/m : P6₃/m
8.BN.05 va	Germanate-pyromorphite	Pb₅(PO₄)₂GeO₄
8.BN.05	Kuannersuite-(Ce)	NaCeBa₃(PO₄)₃F_0.5Cl_0.5	Trig. 3 : P3
8.BN.05	Hydroxylapatite-M	Ca₅(PO₄)₃OH	Mon. 2/m : P2₁/b
8.BN.05	Hydroxylpyromorphite	Pb₅(PO₄)₃(OH)	Hex. 6/mmm (6/m 2/m 2/m) : P6₃/mcm
8.BN.05	Stronadelphite	Sr₅(PO₄)₃F	Hex. 6/m : P6₃/m
8.BN.05	Fluorphosphohedyphane	Ca₂Pb₃(PO₄)₃F	Hex. 6/m : P6₃/m
8.BN.05	Carlgieseckeite-(Nd)	NaNdCa₃(PO₄)₃F	Trig. 3 : P3
8.BN.05	Vanackerite	Pb₄Cd(AsO₄)₃Cl	Trig. 3 : P3
8.BN.05	Miyahisaite	(Sr,Ca)₂Ba₃(PO₄)₃F	Hex. 6/m : P6₃/m
8.BN.05	Unnamed (OH-analogue of Mimetite)	Pb₅(AsO₄)₃(OH)	Hex. 6/m : P6₃/m
8.BN.05	Pieczkaite	Mn₅(PO₄)₃Cl	Hex. 6/m : P6₃/m
8.BN.05	Hydroxylhedyphane	Ca₂Pb₃(AsO₄)₃(OH)	Trig. 3 : P3
8.BN.05	Pliniusite	Ca₅(VO₄)₃F	Hex. 6/m : P6₃/m
8.BN.05	Parafiniukite	Ca₂Mn₃(PO₄)₃Cl	Hex. 6/m : P6₃/m
8.BN.10	Arctite	Na₂Ca₄(PO₄)₃F	Trig. 3m (3 2/m) : R3m
8.BN.15	Goryainovite	Ca₂(PO₄)Cl	Orth. mmm (2/m 2/m 2/m) : Pbcm

Fluorescence of PhosphohedyphaneHide

In UV light:

Not fluorescent.

Other InformationHide

Notes:

Decomposes quickly in dilute HCl and the residue dissolves slowly.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for PhosphohedyphaneHide

mindat.org URL:

https://www.mindat.org/min-27608.html
Please feel free to link to this page.

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External Links:

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for PhosphohedyphaneHide

Reference List:

Kampf, A. R., Steele, I. M., Jenkins, R. A. (2006) Phosphohedyphane, Ca₂Pb₃(PO₄)₃Cl, the phosphate analog of hedyphane: Description and crystal structure. American Mineralogist, 91 (11) 1909-1917 doi:10.2138/am.2006.2268

Birch, W.D., Mills, S.J. (2007). Sulphide–carbonate reaction in recrystallised limestone at Lilydale, Victoria, Australia: a new occurrence of phosphohedyphane. Australian Journal of Mineralogy, 13(2), 73–82.

Frost, Ray L., Scholz, Ricardo, López, Andrés, Firmino, Bárbara E., Lana, Cristiano, Xi, Yunfei (2014) A Raman and infrared spectroscopic characterisation of the phosphate mineral phosphohedyphane Ca₂Pb₃(PO₄)₃Cl from the Roote mine, Nevada, USA. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 127. 237-242 doi:10.1016/j.saa.2014.02.067

(2023) Phosphohedyphane. Handbook of Mineralogy. Mineralogical Society of America

Localities for PhosphohedyphaneHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Australia
New South Wales Yancowinna Co. Broken Hill district ⓘ Broken Hill	Kampf et al. (2006)
Northern Territory Barkly Region ⓘ Tennant Creek	Kampf et al. (2006)
South Australia Flinders Ranges North Flinders Ranges Mount Lyndhurst station ⓘ Avondale Mine	Ben Grguric
Victoria Yarra Ranges Shire Lilydale ⓘ Cave Hill Quarry (David Mitchell Limestone Quarry; Lilydale Quarry)	Birch et al. (2007)
Western Australia Northampton Shire ⓘ Northampton	Downes et al. (2017)
ⓘ Mendip	Downes et al. (2017)

Austria
Burgenland Oberpullendorf District Markt Sankt Martin Pauliberg ⓘ Basalt quarry	Kolitsch et al. (2019)
Lower Austria Melk District Dunkelsteinerwald Häusling ⓘ In der Luck’n	Knobloch et al. (2018)

Bolivia
Oruro Cercado Province Oruro ⓘ San José Mine	Analysis by Dr Frank Keutsch on ...

Brazil
Minas Gerais Vazante ⓘ Extremo Norte mine	Slezak et al. (pdf available at https://qspace.library.queensu.ca/handle/1974/7027?mode=full)

Canada
Nova Scotia Halifax Co. Musquodoboit Harbour ⓘ Dunbrack mine	Lykova (2003)

Chile (TL)
Atacama Copiapó Province Copiapó ⓘ Capitana Mine (TL)	Kampf et al. (2006)
Tierra Amarilla Pampa Larga mining district ⓘ Maria Catalina mine	Yang et al. (2011)

China
Guangdong Yunfu Luoding Co. ⓘ Pyromorphite occurrence	Cuitian Qiu (1983)

Czech Republic
Central Bohemian Region ⓘ Příbram District	is.muni.cz (n.d.)
Milín Slivice ⓘ Karel vein	Sejkora et al. (žíla Karel)
Olomouc Region Jeseník District Lipová-lázně ⓘ Smrčník hill	Pauliš et al. (2023)
Skorošice Petrovice ⓘ Hraničná deposit	Jirásek J et al. (2020)

France
Auvergne-Rhône-Alpes Allier Vichy Échassières Montmins mining district ⓘ Ste Barbe vein (Les Montmins)	SEM-EDS analysed at Laboratoire "Magmas ...
Rhône Villefranche-sur-Saône Chénelette ⓘ Nuizière (Nuissière Mine)	Kampf et al. (2006)

Germany
Baden-Württemberg Freiburg Region Lörrach Kleines Wiesental ⓘ Neuenweg	Niels van Velzen collection Mindat ...
Ortenaukreis Oberwolfach ⓘ Clara Mine	Schimak et al. (02/2024)
Waldshut Dachsberg Urberg ⓘ Gottesehre Mine	Markl (2017)
Bavaria Upper Palatinate Schwandorf District Neunburg vorm Wald Krandorf ⓘ Krandorf Mine	Hauner (2024)
Hesse Giessen Region Limburg-Weilburg Weinbach ⓘ Bangertsheck Mine	Legner et al. (2022)
Saxony Erzgebirgskreis Bärenstein Niederschlag ⓘ Niederschlag mine	Müller et al. (2021)

Greece
Attica East Attica Lavreotiki ⓘ Lavrion Mining District	Rieck et al. (2020)
Plaka Plaka mines ⓘ Plaka Porphyry Deposit ("Porphyry Hill")	Rieck et al. (2020)

Italy
Liguria Savona Province Cairo Montenotte Curagnata ⓘ Monte Cavaglione	Balestra et al. (2009)
Sardinia South Sardinia Province Domusnovas ⓘ Sa Duchessa Mine	Orlandi (2011)

Japan
Gunma Prefecture Numata City ⓘ Sonohara	Hirama et al. (2011) +1 other reference

Kazakhstan
Karaganda Region Karkaraly ⓘ Ken'-Choku deposit (Ken'-Cheku; Ken'-Shoko)	Lemanski (2009)
Shet District ⓘ Ken-Choku (Kenshoky) deposit	Kampf et al. (2006)
ⓘ Kyzylespe (Kyzyl-Espe)	Pavel.M. Kartashov (n.d.)

Mexico
Chihuahua Ascención Municipality ⓘ La Morita Mine	Peter Megaw
Zacatecas Ojocaliente Municipality La Blanca ⓘ Bilbao Mine	Parker (2010)

Morocco
Drâa-Tafilalet Region Errachidia Province Er-Rissani Cercle Taouz Caïdat Tadaout ⓘ Vein 12	Joan Rosell - Rosell Minerals

Norway
Viken Lunner Grua Grua mining district ⓘ Skjerpemyr Mine	Folvik (2019)

Poland
Lower Silesian Voivodeship Ząbkowice Śląskie County Gmina Ząbkowice Śląskie Szklary ⓘ Mt. Szklana Mine (Szklary pegmatite)	Pieczka et al. (2013) +3 other references

Portugal
Beja Moura Sobral da Adiça ⓘ Preguiça Mine	Alves (n.d.)
Odemira São Luís ⓘ Courela dos Gaviões Mine	Pedro Alves collection and analytical ...
ⓘ Herdade dos Pendões Mine	Alves et al. (2017)
ⓘ Torgal Mine	Pedro Alves collection and analytical ...
Bragança Freixo de Espada à Cinta Lagoaça e Fornos ⓘ Cabeço da Roda Mine	Pedro Alves collection and analytical ...

Republic of the Congo
Bouenza Department Mfouati District ⓘ Mfouati	Spirifer Minerals specimens (neon green phosphohedyphane pseudomorphs after cerussite)

Russia
Altai Krai Krasnoshchyokovsky District ⓘ Murzinskoe gold deposit	webmineral.ru (2020)
Sverdlovsk Oblast Beryozovsky ⓘ Berezovsk deposit	Kampf et al. (2006)

Slovakia
Banská Bystrica Region Brezno District Bacúch ⓘ Aplite dike occurrence	Ondrejka et al. (2020)
Žarnovica District Rudno nad Hronom ⓘ Rudno nad Hronom exploration area	Vlasáč et al. (2021)

South Africa
Northern Cape Namakwa District Municipality Khâi-Ma Local Municipality Aggeneys ⓘ Gamsberg zinc mine	Own collection XRD confirmed

Spain
Andalusia Almería Níjar Pozo de Los Frailes ⓘ Barranco Celejo	Castro et al. (2019)
San José ⓘ Mina Santa Barbara	SEM-EDS analysed +1 other reference
Córdoba Torrecampo ⓘ Mina de las Torcas	Christian Rewitzer collection - SEM-EDS ...
Granada Albuñuelas ⓘ Laura Mine	ACOPIOS 2011 V2:23-28 Actualización mineralógica de las minas de Albuñuelas (Granada)
ⓘ Los Lastonares Mines	Analysis made by César Menor Salván ...
Cantabria Torrelavega Viérnoles ⓘ Nieves Mine (Nieves Quarry)	Calvo (2015)
Castile-La Mancha Ciudad Real Almodóvar del Campo ⓘ Minas del Horcajo	www.foro-minerales.com (2022)
ⓘ María del Pilar vein	www.foro-minerales.com (2022) +1 other reference
ⓘ Pozo San Germán	www.foro-minerales.com (2022) +1 other reference
Toledo Madridejos Cerro de Pichita in La Perdiguera ⓘ Santa Bárbara Mine (La Pichita Mine; Perdiguera Mine)	Menor (2010)
Cerros de La Perdiguera ⓘ Ángel de mi Guardia Mine (Polvorín Mine)	Menor (2010)
ⓘ Polvorín shaft	Menor (2010)
Castile and Leon León El Bierzo Sobrado ⓘ Antonina Mine (Toral de los Vados)	Calvo (2015)
Catalonia Girona Mont-ras ⓘ Pepito mine	Joan Rosell - rosellminerals.com
Extremadura Badajoz Oliva de Mérida ⓘ Osa Quarry	Sainz de Baranda Graf et al. (2023)
Valle de la Serena ⓘ San Nicolás Mine	Sainz de Baranda Graf et al. (2023)
Cáceres Zarza la Mayor ⓘ La Paloma Mine	Calvo Rebollar (2015)

Tunisia
Siliana Siliana Djebel Sekarna ⓘ Djebel Sekarna Mine (Sekarna deposit)	Dill

Turkey
Niğde Province Çamardı District ⓘ Kestel Mine	Powell et al. (2021)

UK
England Cornwall Menheniot ⓘ Wheal Mary Ann	Tony Aldworth Collection/Chris Jewson ...
Perranzabuloe ⓘ Wheal Mexico (Trebellan Mine; incl. Treworthy Mine)	Rob Bowell (Cardiff University analysis)
Cumbria Allerdale Caldbeck Roughton Gill ⓘ Higher Roughton Gill (Balliway Rigg)	Green et al. (2008)
Derbyshire Bolsover District Hodthorpe and Belph ⓘ Whitwell Quarry	Peter Briscoe collection +1 other reference
Scotland Dumfries and Galloway Wanlockhead ⓘ New Glencrieff Mine (Wanlockhead Mine; East and West branch of New Glencrieff Vein)	S. Rust collection
Wanlock Dod-Whytes Cleuch ⓘ Belton Grain vein	Manchester University Museum
Whytes Cleuch ⓘ Cove Vein	Steve Rust
ⓘ Wilsons Vein	Steve Rust
South Lanarkshire Leadhills Wanlock Dod ⓘ Lady Anne Hopetoun shaft (Brow and Hopeful Veins)	S. Rust collection.

USA
Arizona Cochise County Carr Canyon ⓘ Reef Mine	"The Accidental Pocket" talk presented ...
Chiricahua Mountains California Mining District (Chiricahua Mining District) ⓘ Unnamed Zn-Pb-Ag-Cu-Sb-Cd prospect (Shaft; Trench; Decline prospect)	Luetcke (n.d.)
Tombstone Mining District ⓘ Gallagher Vanadium & Rare Minerals Corp Mine	Rob Bowell
ⓘ Manila Mine	Luetcke (n.d.)
Tombstone Extension Mines ⓘ San Diego Mine	Luetcke (n.d.)
Yellowstone Mining District Johnny Lyon Hills Tres Alamos Wash ⓘ Unnamed Pb-Cu-Ag-Au-Zn-W prospect	Robert Jenkins Raman Spectroscopy
Gila County Banner Mining District Christmas ⓘ C and B Mine (C & B Mine; Vanadium Mine)	Raman analyzed at the University of ...
Hayden area Chilito ⓘ 79 Mine	Luetcke (n.d.)
Maricopa County Osborn Mining District Tonopah Belmont Mountain ⓘ Tonopah-Belmont Mine	Kampf et al. (2006)
Pinal County Mammoth Mining District Tiger St. Anthony deposit ⓘ Mammoth-Saint Anthony Mine	Kampf et al. (2006)
Tortilla Mountains Ripsey Mining District Ripsey Hill area ⓘ Florence Mine (Florence Lead Silver Mine)	Luetcke (n.d.)
Santa Cruz County Patagonia Mountains Fresno Canyon Palmetto District Tres de Mayo Mine group ⓘ Robert E. Lee Mine (Bob Lee Mine; Bob Lee and Widow Mine)	Luetcke (n.d.)
Harshaw Mining District Harshaw Hardshell Gulch ⓘ Hardshell Mine (Manto Mine; Eagle-Picher properties)	Kampf et al. (2006)
California Inyo County Inyo Mts (Inyo Range) Russ Mining District Reward ⓘ Reward Mine	Adams (2010)
San Bernardino County Ord Mining District Ord Mountains Ord Mountain Ord Mountain Mine (Ord Mountain Mine System; Ord Mine; Ord Mountain deposits; Osborn; Rio Vista claim; Brilliant claim; Josephine claim; Belgium claim; Copper Junction claim) ⓘ Josephine Mine (Josephine ledge; Josephine claim)	MarekC Collection (2017)
Silver Lake Mining District Soda Mountains Baker ⓘ Otto Mountain	Kampf et al. (2010)
ⓘ Aga Mine	Thorne (n.d.)
ⓘ Bird Nest drift	Joe Marty specimens
ⓘ Bird Nest E3	Thorne (n.d.)
ⓘ Library Mine	Thorne (n.d.)
ⓘ NE2 vein	Housley R.
ⓘ SW cut
Zzyzx ⓘ Blue Bell Mine	Specimen from the 2A glory hole ...
Nevada Clark County Spring Mountains Goodsprings Mining District ⓘ Argentena Mine	Kampf et al. (2006)
ⓘ Boss Mine	Collected and analyzed by Joy Desor.
ⓘ Mobile Mine	Kampf et al. (2006)
ⓘ Monte Cristo Mine	Kampf et al. (2006)
ⓘ Root Mine	Kampf et al. (2006)
ⓘ Singer Mine	Hayes et al. (2008)
ⓘ Smithsonite Mine	Thorne (n.d.)
Humboldt County Iron Point Mining District Valmy ⓘ Silver Coin Mine	Kampf et al. (2006)
New Mexico Grant County Burro Mountains Mining District Tyrone Area Tyrone Mine ⓘ Gettysburg pit	Jerry Cone Collection

Phosphohedyphane

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