Valentinite
A valid IMA mineral species - grandfathered
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About Valentinite
Formula:
Sb2O3
Colour:
Colourless, white, light gray, light yellow
Lustre:
Adamantine, Pearly
Hardness:
2½ - 3
Specific Gravity:
5.76
Crystal System:
Orthorhombic
Name:
Named after Basilius Valentinus (Basil Valentine) [1394 Mainz, Germany - 1450 "Germany?"], who wrote about the properties of antimony. Valentinus may have been a real 15th-century chemist but some historians argue that it was a pseudonym used by one or more 16th-century German authors.
Dimorph of:
This page provides mineralogical data about Valentinite.
Unique Identifiers
Mindat ID:
4135
Long-form identifier:
mindat:1:1:4135:1
GUID
(UUID V4):
(UUID V4):
f1f5417a-eabb-4d38-9428-de242096c945
IMA Classification of Valentinite
Approved, 'Grandfathered' (first described prior to 1959)
Classification of Valentinite
4.CB.55
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
B : With medium-sized cations
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
B : With medium-sized cations
4.3.11.1
4 : SIMPLE OXIDES
3 : A2X3
4 : SIMPLE OXIDES
3 : A2X3
7.13.4
7 : Oxides and Hydroxides
13 : Oxides of As, Sb and Bi
7 : Oxides and Hydroxides
13 : Oxides of As, Sb and Bi
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Vln | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Valentinite
Adamantine, Pearly
Transparency:
Transparent
Colour:
Colourless, white, light gray, light yellow
Streak:
White
Hardness:
2½ - 3 on Mohs scale
Hardness Data:
Measured
Tenacity:
Brittle
Cleavage:
Perfect
on {110}, imperfect on {010}
on {110}, imperfect on {010}
Density:
5.76 g/cm3 (Measured) 5.76 g/cm3 (Calculated)
Optical Data of Valentinite
Type:
Biaxial (-)
RI values:
nα = 2.180 nβ = 2.350 nγ = 2.350
Max Birefringence:
δ = 0.170
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
extreme
Chemistry of Valentinite
Mindat Formula:
Sb2O3
Elements listed:
Common Impurities:
As
Crystallography of Valentinite
Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pccn
Cell Parameters:
a = 4.91 Å, b = 12.46 Å, c = 5.42 Å
Ratio:
a:b:c = 0.394 : 1 : 0.435
Unit Cell V:
331.59 ų (Calculated from Unit Cell)
Morphology:
Commonly prismatic either [001] or [100]; also tabular {010}. Prism faces often rounded by striations parallel to [001], and the brachydomes are striated [100]. Fan-shaped or stellate aggregates, in bundles and druses and as aggregates of thin plates. Massive, with lamellar, columnar, or granular structure.
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0000015 | Valentinite | Buerger M J (1936) The crystal structure of valentinite American Mineralogist 21 206-207 | 1936 | 0 | 293 | ||
0009500 | Valentinite | Svensson C (1974) The crystal structure of orthorhombic antimony trioxide, Sb2O3 Acta Crystallographica B30 458-461 | 1974 | synthetic | 0 | 293 | |
0010568 | Valentinite | Buerger M J, Hendricks S B (1938) The crystal structure of valentinite Zeitschrift fur Kristallographie 98 1-30 | 1938 | 0 | 293 | ||
0012431 | Valentinite | Whitten A E, Dittrich B, Spackman M A, Turner P, Brown T C (2004) Charge density analysis of two polymorphs of antimony(III) oxide Dalton Transactions 2004 23-29 | 2004 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Image Loading
Radiation - Copper Kα
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
4.571 Å | (18) |
3.494 Å | (25) |
3.174 Å | (20) |
3.142 Å | (100) |
3.118 Å | (75) |
2.650 Å | (14) |
1.8046 Å | (20) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47d : [Arsenates, antimonates, selenates, bismuthinates] | |
47h : [Near-surface oxidized, dehydrated minerals] | |
Stage 10b: Anthropogenic minerals | <10 Ka |
55 : Anthropogenic mine minerals | |
56 : Slag and smelter minerals (see also #51 and #55) |
Type Occurrence of Valentinite
Synonyms of Valentinite
Other Language Names for Valentinite
Common Associates
Associated Minerals Based on Photo Data:
181 photos of Valentinite associated with Stibnite | Sb2S3 |
93 photos of Valentinite associated with Quartz | SiO2 |
86 photos of Valentinite associated with Kermesite | Sb2S2O |
75 photos of Valentinite associated with Pyrite | FeS2 |
46 photos of Valentinite associated with Galena | PbS |
46 photos of Valentinite associated with Stibiconite | Sb3+Sb5+2O6(OH) |
45 photos of Valentinite associated with Senarmontite | Sb2O3 |
37 photos of Valentinite associated with Antimony | Sb |
24 photos of Valentinite associated with Sulphur | S8 |
17 photos of Valentinite associated with Metastibnite | Sb2S3 |
Related Minerals - Strunz-mindat Grouping
4.CB. | Ferrohögbomite-2N2S | [(Fe2+,Mg,Zn,Al)3(Al,Ti,Fe3+)8O15(OH)]2 |
4.CB. | Magnesiohögbomite-6N12S | Mg5Al11TiO23(OH) |
4.CB. | Zhenruite | (MoO3)2 · H2O |
4.CB. | Pengite | (Pb8Sb3+3)Σ11Sb5+9O35 |
4.CB. | Virgilluethite | MoO3 · H2O |
4.CB.05 | Brizziite | NaSb5+O3 |
4.CB.05 | Corundum | Al2O3 |
4.CB.05 | Ecandrewsite | (Zn,Fe2+,Mn2+)TiO3 |
4.CB.05 | Eskolaite | Cr2O3 |
4.CB.05 | Geikielite | MgTiO3 |
4.CB.05 | Hematite | Fe2O3 |
4.CB.05 | Ilmenite | Fe2+TiO3 |
4.CB.05 | Karelianite | V3+2O3 |
4.CB.05 | Melanostibite | Mn2+2Fe3+Sb5+O6 |
4.CB.05 | Pyrophanite | Mn2+TiO3 |
4.CB.05 | Akimotoite | (Mg,Fe2+)SiO3 |
4.CB.05 | Auroantimonate | AuSbO3 |
4.CB.05 | UM1998-11-O-AuHSb | Au+2Sb3+O2(OH) |
4.CB.05 | Tistarite | Ti3+2O3 |
4.CB.05 | Unnamed (Fe-Cr Oxide) | FeCrO3 |
4.CB.05 | Hemleyite | (Fe2+0.48Mg0.37Ca0.04Na0.04Mn2+0.03Al0.03Cr3+0.01)sum=1.00Si1.00O3 |
4.CB.10 | Avicennite | Tl2O3 |
4.CB.10 | Bixbyite-(Mn) | Mn3+2O3 |
4.CB.10 | Bixbyite-(Fe) | (Fe,Mn)2O3 |
4.CB.15 | Armalcolite | (Mg,Fe2+)Ti2O5 |
4.CB.15 | Sassite | Ti3+2Ti4+O5 |
4.CB.15 | Pseudobrookite | Fe2TiO5 |
4.CB.15 | Ferropseudobrookite | Fe2+Ti2O5 |
4.CB.15 | Griffinite | Al2TiO5 |
4.CB.15 | Pseudobrookite Group | |
4.CB.20 | Zincohögbomite-2N2S | [(Zn,Al,Fe2+)3(Al,Fe3+,Ti)8O15(OH)]2 |
4.CB.20 | Zincohögbomite-2N6S | [(Zn,Mg)7(Al,Fe3+,Ti)16O31(OH)]2 |
4.CB.20 | Magnesiohögbomite-6N6S | [(Mg,Fe2+)3(Al,Ti,Fe3+)8O15(OH)]6 |
4.CB.20 | Magnesiohögbomite-2N3S | [(Mg,Fe2+,Zn)4(Al,Ti,Fe3+)10O19(OH)]2 |
4.CB.20 | Magnesiohögbomite-2N2S | [(Mg,Fe2+)3[Al7(Ti,Fe3+)]O15(OH)]2 |
4.CB.20 | Ferrohögbomite-6N12S | [(Fe2+,Mg,Zn)5(Al,Ti,Fe3+)12O23(OH)]6 |
4.CB.20 | Magnesiohögbomite-2N4S | (Mg8.43Fe2+1.57)sum=10Al22Ti4+2O46(OH)2 |
4.CB.20 | Magnesiobeltrandoite-2N3S | (Mg6Al2)(Al18Fe3+2)O38(OH)2 |
4.CB.20 | Zincovelesite-6N6S | Zn3(Fe3+,Mn3+,Al,Ti)8O15(OH) |
4.CB.25 | Pseudorutile | Fe2Ti3O9 |
4.CB.25 | Kleberite | FeTi6O11(OH)5 |
4.CB.30 | Berdesinskiite | V3+2TiO5 |
4.CB.30 | Oxyvanite | V3+2V4+O5 |
4.CB.30 | Kaitianite | Ti3+2Ti4+O5 |
4.CB.35 | Olkhonskite | (Cr,V)2Ti3O9 |
4.CB.35 | Schreyerite | V3+2Ti3O9 |
4.CB.35 | Machiite | Al2Ti3O9 |
4.CB.35 | Vestaite | (Ti4+Fe2+)Ti4+3O9 |
4.CB.40 | Kamiokite | Fe2Mo3O8 |
4.CB.40 | Nolanite | V3+8Fe3+2O14(OH)2 |
4.CB.40 | Rinmanite | Zn2Sb2Mg2Fe4O14(OH)2 |
4.CB.40 | Iseite | Mn2Mo3O8 |
4.CB.40 | Majindeite | Mg2Mo3O8 |
4.CB.45 | Claudetite | As2O3 |
4.CB.45 | Stibioclaudetite | AsSbO3 |
4.CB.50 | Arsenolite | As2O3 |
4.CB.50 | Senarmontite | Sb2O3 |
4.CB.60 | Bismite | Bi2O3 |
4.CB.65 | Sphaerobismoite | Bi2O3 |
4.CB.70 | Sillénite | Bi12SiO20 |
4.CB.75 | Kyzylkumite | V3+Ti2O5(OH) |
4.CB.80 | Tietaiyangite | Fe3+4Fe2+TiO9 |
4.CB.85 | Liuite | FeTiO3 |
4.CB.90 | Luogufengite | Fe2O3 |
4.CB.95 | Wangdaodeite | FeTiO3 |
Other Information
Thermal Behaviour:
Heated in a closed tube, it fuses and partially sublimates. Before the blowpipe, on charcoal, it fuses easily and gives a white coating.
Notes:
Soluble in HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Valentinite
mindat.org URL:
https://www.mindat.org/min-4135.html
Please feel free to link to this page.
Please feel free to link to this page.
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External Links:
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References for Valentinite
Reference List:
Klaproth, M. H. (1802) Chemische Untersuchung des Weiß-Spießglanzerzes. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 3. Rottmann, Berlin. p.183-186.
Ungemach, Henri (1912) Sur la valentinite. Bulletin de Minéralogie, 35 (6) 539-552 doi:10.3406/bulmi.1912.3534
Localities for Valentinite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Algeria | |
| Jean-Pierre Barral specimen |
| BARRAL (2013) |
Bernard et al. (2004) | |
Australia | |
| Dieter Mylius collection |
| Gilligan et al. (1992) |
| www.mindat.org (2015) |
| D.McLaughlin 1988. Secondary Minerals ... +1 other reference |
| TVM Specimen |
| Ralph Bottrill collection |
| WILKINSON et al. (ed.) |
| F.Bussat 1980 |
Bussat et al. (1980) | |
| I.M. Threadgold (1958) |
| en.wikipedia.org (2016) |
Simpson (1952) | |
| Simpson (1948) |
| Simpson (1948) |
Austria | |
| Kolitsch et al. (2010) |
C.Auer (2016) | |
| C.Auer (2013) |
Blaß et al. (2002) | |
| H.Meixner (1974) |
H. Meixner: Carinthia II 158./78.:96-101 (1968) | |
| W. Paar (1980) +1 other reference |
Puttner (1987) | |
| Pichler (2009) |
Pichler (2009) | |
Niedermayr et al. (1995) | |
Pichler (2009) | |
| Niedermayr et al. (1995) |
| Niedermayr et al. (1995) |
Pichler (2009) | |
| Pichler (2009) |
| Niedermayr et al. (1995) |
| Niedermayr et al. (1995) |
| Niedermayr et al. (1995) |
| Groß (1983) |
Christian Auer collection | |
| Kolitsch et al. (2010) |
| Taucher (1999) |
| 50 +2 other references |
| 50. +1 other reference |
| Lapis 19 (7/8) |
| Putz et al. (2007) |
| Schachinger et al. (2017) |
| Arlt et al. (1994) |
Lapis 19 (7/8) | |
Bolivia | |
| Wilson (2001) |
| [MinRec 6:134 |
Kempff et al. (La Paz, 2009) | |
Wilson (2001) | |
| Wilson (2001) +1 other reference |
Gordon (1924) | |
| Salomon Rivas & Federico Ahlfeld (1998) |
| Kempff et al. (La Paz, 2009) |
| Mineralogical Record (2001) |
| Alfredo Petrov and Jaroslav Hyrsl ... |
| Wilson (1997) +1 other reference |
Spencer et al. (1907) | |
| Econ Geol (1997) +1 other reference |
| Smith et al. (2001) |
Petrov (n.d.) | |
Brazil | |
| USGS Professional Paper 341B |
Canada | |
| BC Minfile data +1 other reference |
| Wilson (1991) |
| Sabina (2003) |
| Lake et al. (2006) |
| Grantham (1985) |
| Sabina (1964) +1 other reference |
| an example of gudmundite-native ... +3 other references |
Chile | |
| Sernageomin +1 other reference |
China | |
| Zhen Meng et al. (2007) |
| Guozhong Chen et al. (2013) |
| Guangxi Zhao (2007) |
| Genwen Chen et al. (2008) |
| Chunlin Yang (1993) |
| Peixi Li (1993) |
| Ottens (2006) +1 other reference |
| Wang Binghua |
| Yongke Chen et al. (2004) |
| Zhiwei Bao (2001) |
| Yu Chen et al. (1984) +2 other references |
| Yonghong Zhu et al. (2012) |
| Lin Yang et al. (2010) |
| Jihua Li et al. (2012) |
| Hanzhi Sun and Lei Lei (1988) +1 other reference |
| Zhifang Zeng and Hesheng Liu (2003) |
| Jianyan Li (1989) +2 other references |
| Guangmo Liu and Houming Jian (1983) +3 other references |
| Pengcheng Liu et al. (2008) +1 other reference |
| Jianhong Zheng et al. (2009) |
| Behling et al. (2002) |
| Xiubao Huang and Quanshi Zuo (2001) |
| Leiming Xu et al. (1993) |
| Huiqin Zuo et al. (1991) |
| Lizi Chen et al. (2011) |
Zhang Fuxin et al. (1999) +3 other references | |
Fuxin Zhang and Jianqin Ma (1999) | |
| Gu et al. (2002) |
| Su Sun (1993) |
| Likuan Zhu et al. (2012) +2 other references |
| Hong Wang et al. (2003) +1 other reference |
| Yi Yang et al. (2006) |
Czech Republic | |
| |
Brabec (2002) | |
| RÜSENBERG et al. (1996) |
| [Bull.N.M.Praha 2002 |
| [Bull.N.M.Praha 2002 |
[Bull.N.M.Praha 2002 | |
| Fojt +8 other references |
| Pauliš et al. (2019) |
Veselovský (2019) | |
| Sejkora J et al. (2020) |
| Velebil +5 other references |
Ecuador | |
| an NI 43-101 Technical Report prepared ... +1 other reference |
Finland | |
| Sandström et al. (2009) |
| Geological Survey of Finland website |
France | |
| J.-J. Périchaud: Les Minéraux d'Auvergne et al. (1985) |
| |
| Queneau (n.d.) |
| R. Pierrot |
| |
Robin Fialip | |
| R. Pierrot |
| |
| J.J. Périchaud (Massif Central Français) |
J.J. Périchaud (Massif Central Français) | |
J.J. Périchaud (Massif Central Français) | |
| Queneau (n.d.) |
C. Vialaron : La mine d'antimoine de Daü et al. (1999) | |
| Queneau (n.d.) |
| |
Queneau (n.d.) | |
| |
| |
| Henwood (1871) +1 other reference |
| Personally collected by Matthias Diot ... |
| T. Brunsperger collection |
| Queneau (n.d.) |
| Germain C. et al. (1990) |
| M. Bocianowski collection +1 other reference |
| Pierre Le Roch photo & collection |
| Pillard F. et al. (1985) |
| Wittern (1997) |
| FLUCK et al. (1992) |
| Cassian (?) |
| Une ancienne mine d'Antimoine dans le Limousin aurifère ( Georges Hyvert ) +1 other reference |
| Queneau (n.d.) |
| Thiery et al. (2020) |
| Queneau (n.d.) |
| Y. Moëlo |
| BONNET Frederic collection |
| Inventaire Minéralogique de la France Numéro 14 ( Lozère ) |
| Robert Pecorini collection; EDX ... |
| Baret (1905) |
| |
| Mantienne (1974) +1 other reference |
| Jean-Luc Portes Collection |
| Self collected S. Maury |
Germany | |
| Walenta (1992) |
Meinrad Kempf Collection | |
Walenta (1992) | |
| Walenta (1992) |
| Walenta (1992) +1 other reference |
Walenta (1992) | |
| Walenta (1992) |
| Weiß (1990) |
| |
| |
| Weiß (1990) |
| Meier (1995) |
| |
| Weiß (1990) |
Lapis (6) | |
Blaß et al. (1993) | |
| Schnorrer- Köhler et al. (1987) +1 other reference |
| Weiss: "Mineralienfundstellen et al. (Munich) |
| Blaß et al. (1993) +1 other reference |
| Henrich (2009) |
| Hucko et al. (2009) |
| Beyer (1978) |
| Weiss: "Mineralienfundstellen et al. (Munich) |
| Weiß (1990) |
| Weiß (1990) |
| Weiß (1990) |
| Weiß (1990) |
Weiß (1990) | |
| Lapis 2001 (6) |
| Lapis (3) |
| Schnorrer et al. (1993) |
| Wittern (2001) |
| Gröbner et al. (2011) |
Gröbner et al. (2011) | |
| Klaproth (1802) |
| Tröger (2012) |
| 43-47 +3 other references |
Greece | |
| Fritz Schreiber collection |
Hanke (1998) | |
| Kolitsch et al. (2014) |
| Kanellopoulos et al. (2024) |
| Tzamos +9 other references |
Greenland | |
| Petersen (2001) |
| Karup-Møller et al. (1974) +1 other reference |
Hungary | |
| Szakáll: Minerals of Rudabánya |
| Koch: Minerals of Hungary |
| |
MAMIT | |
Isle of Man | |
| [J.Russell Soc 1998:35] |
Italy | |
| Pelloux (1927) +1 other reference |
| dbami.amiminerals.it (n.d.) |
| AA. VV. |
| AA. VV. |
| Bedognè et al. (2006) |
| Piccoli et al. (2007) |
Piccoli et al. (2007) | |
| AA. VV. |
| Luigi Chiappino data |
| Pelloux (1904) +3 other references |
| Lovisato (1894) +2 other references |
| Del Caldo et al. (1973) +1 other reference |
| Brizzi et al. (1994) |
Stara P. (1996) | |
Stara et al. (1996) | |
AA. VV. | |
| Corsi (1896) +3 other references |
| D'Achiardi (1896) +4 other references |
| Raman Spectroscopy by Ivano Rochetti |
| Brizzi G. et al. (Casal di Pari-GR) |
Brizzi G. (1985) +1 other reference | |
| M.E. Ciriotti (Alessandro Soccidi, 2006, pers. comm.) |
D'Achiardi (1872-73) +1 other reference | |
| Meli (2000) |
C. Lemanski (6791CL) | |
| Bazzoni C. et al. (2011) +1 other reference |
Bazzoni C. et al. (2011) | |
| Bazzoni et al. (2001) |
| Sitta et al. (1981) |
| Innocenti F. et al. (Semproniano, Grosseto) |
| Benvenuti M. et al. (1992/93) |
| Biagioni et al. (2015) |
| Biagioni et al. (2009) |
| Nannoni R. et al. (PI) +1 other reference |
| Min.Rec.: 15:35 +3 other references |
Japan | |
| Minakawa (1982) |
| Field collected by Dr Hidemichi Hori +1 other reference |
| Yamada (2004) |
| University of Tokyo collection |
| Yamada (2004) |
Petrov (n.d.) | |
University of Tokyo collection +1 other reference | |
Kyrgyzstan | |
| Kolesar et al. (1993) +1 other reference |
Kolesar et al. (1993) | |
| Evseev (1995) |
| Il'yasova +2 other references |
Luxembourg | |
| 43-45 +5 other references |
Mexico | |
| Panczner (1987) |
Panczner (1987) | |
| Loranth |
| Rocks & Min.: 56:247. |
| Panczner (1987) |
Panczner (1987) | |
Panczner (1987) | |
Panczner (1987) | |
| Panczner (1987) |
| Panczner (1987) |
| Panczner (1987) |
| Panczner (1987) |
| Panczner (1987) |
Panczner (1987) | |
| Pancnzer (1987) |
| Panczner (1987) |
| Panczner (1987) |
| Richard Gunter specimen +1 other reference |
Mozambique | |
| Behier (1957) |
New Zealand | |
| Collection of Rod Martin |
| Collection of Rod Martin |
| Watson (1974) |
| R.Martin personal collection |
| Collection of RJ Martin |
North Macedonia | |
| Rieck (1993) +1 other reference |
| Mudrinic et al. (1997) |
| Đorđević et al. (2017) +1 other reference |
Norway | |
| |
Portugal | |
| Bello |
| Pedro Alves analytical data. |
| |
| |
| Pedro Alves collection and analytical ... |
Romania | |
| www.minerals-of-the-carpathians |
| Szakáll: Minerals of Carpathian Reg. |
Gabor Koller specimens | |
Damian +6 other references | |
Marias Francisc | |
Damian +6 other references | |
| Clain et al. (2006) |
Russia | |
| Silyanov et al. (2021) |
| Volkov et al. (2013) |
| webmineral.ru (n.d.) |
| Grant et al. (2001) |
| Goryachev et al. (2011) |
| Gamyanin et al. (2014) |
Serbia | |
Slobodan A. Radosavljević et al. (2013) | |
| Slobodan A. Radosavljević +4 other references |
Slovakia | |
| Koděra (1986) |
| Koděra (1986) |
| Čík Š. et al. (2020) |
Koděra (1986) | |
| Koděra (1986) |
| Ferenc Š. |
| Števko et al. (2009) |
| Ďuďa (1993) |
| Sejkora J. et al. (2007) |
| Pavel.M. Kartashov (n.d.) +2 other references |
Ozdín D. | |
Laco Turecky collection | |
Števko M. et al. (2021) | |
| Koděra (1986) |
Pauliš P. | |
Martin Števko-unpublished | |
| Koděra (1986) |
| Števko M. (2022) |
| Ozdín D. et al. (in Slovak) +1 other reference |
Števko M. (2022) | |
| Koděra |
| Koděra (1986) |
| Duda et. all. |
Koděra (1986) | |
| Duda |
| Chovan et al. (1995) |
Slovenia | |
| Janez Zavašnik collection +1 other reference |
South Africa | |
| Cairncross et al. (1995) |
| Econ Geol (1997) |
Spain | |
| Valladares et al. (2021) |
| Calvo (2009) |
| Calvo (2008) |
| Calvo (2008) |
| Calvo (2008) |
| Calvo (2009) |
| Eduardo Alonso Herrero et al. Guia ... |
Lacasa (1934) | |
| |
| |
| Jiménez Martínez |
| Calvo (2009) |
Sweden | |
| Holtstam et al. (1999) +1 other reference |
Switzerland | |
| Romani (2000) +1 other reference |
Bedognè et al. (2006) | |
| Stalder et al. (1998) |
Schmutz et al. (1986) | |
Schmutz et al. (1986) | |
| Meisser N. et al. (2020) |
Stalder et al. (1998) | |
Schmutz et al. (1986) | |
Thailand | |
| Dill et al. (2008) |
Turkey | |
| Aral (1989) |
Aral (1989) | |
| Arik (2012) |
UK | |
| S. Rust collection. Ex Mike Rothwell ID ... |
| Golley et al. (1995) |
| Tindle (2008) |
| Steve Rust collection |
Golley et al. (1995) | |
| Golley et al. (1995) |
| Kingsbury (1957) +1 other reference |
| Golley et al. (1995) |
Golley et al. (1995) | |
| Norman Wilson collection |
| |
| Day (1999) |
| Day (1999) |
| Williams (1973) +1 other reference |
| Rust (2022) |
| Williams (1973) |
USA | |
| Rocks & Minerals 71:2 pp134-137 |
| Pearcy et al. (1993) |
| Van Nostrand Reinholt Press: 127 +2 other references |
| Van Nostrand Reinholt Press: 185. +2 other references |
| Stolburg (1984) |
| Stolburg (1984) |
| Van Nostrand Reinholt Press: 185. +1 other reference |
| Mining and Scientific Press (1915) +2 other references |
| - (2005) |
| Murdoch (1941) +1 other reference |
| Behre et al. (1921) +1 other reference |
| Van Nostrand Reinholt Press: 185. +2 other references |
| Cooper et al. (1989) |
| Rogers (1912) +1 other reference |
Palache et al. (1951) | |
| Cooper et al. (1989) |
| Van Nostrand Reinholt Press: 185. +3 other references |
Goldsmith (1873) +1 other reference | |
| Ream (1995) |
| Ream (1995) |
| Rocks & Min. 70:262 |
| Anderson (1991) |
| Castor et al. (2004) |
| Castor et al. (2004) |
| NBMG Bull 83 Geology and Mineral ... |
| Castor et al. (2004) |
| USGS Open-File Report 76-56 |
Castor et al. (2004) | |
| Castor et al. (2004) |
Castor et al. (2004) | |
| Castor et al. (2004) |
| NBMG Bull 58 Geology and Mineral ... +1 other reference |
NBMG Bull 58 Geology and Mineral ... +1 other reference | |
NBMG Bull 58 Geology and Mineral ... +1 other reference | |
| Castor et al. (2004) |
| Castor et al. (2004) |
Castor et al. (2004) | |
| NBMG Bull 99B Geology and Mineral ... |
| NBMG Bull 99B Geology and Mineral ... |
| USGS Bull 723 +1 other reference |
Ferguson (1924) +1 other reference | |
| Field collected by Daniel Evanich ... |
| Castor et al. (2004) |
| Wagner |
| K. Starnes |
| K. Starnes |
| Bullock (1981) |
| Thorne (n.d.) |
| Thorne (n.d.) |
| Bullock (1981) |
| Cannon (1975) |
| Tom Loomis |
| Derkey et al. (1990, November) +1 other reference |
Vietnam | |
| Shunso Ishihara and Pham Tich Xuan (2013) |
| Nevolko et al. (2019) |
Nevolko et al. (2019) | |
Nevolko et al. (2019) |
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Nador N'Bails Mine, Djebel Nador, Hammam N'Bails District, Guelma Province, Algeria